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Tzedakis, Polychronis C; Margari, Vasiliki; Skinner, Luke C; Menviel, Laurie; Capron, Emilie; Rhodes, Rachael H; Mleneck-Vautravers, Maryline J; Ezat, Mohamed M; Martrat, Belén; Grimalt, Joan O; Hodell, David A (2020): Stable isotopes of detrital carbonate from sediment core MD01-2444 on the Portuguese Margin, Marine Isotope Stage 3 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.919838, In: Tzedakis, PC et al. (2020): Palaeoceanographic, sediment and pollen data from sediment core MD01-2444 on the Portuguese Margin, Marine Isotope Stage 3 [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.919846

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Abstract:
Stable isotopes of detrital carbonate were measured on single grains taken from the peaks of HL4 (10.06 m) and HL5 (11.98 m) in MD01-2444. Detrital carbonate grains were picked from the >150 μm fraction and leached in a weak acid. Each detrital carbonate grain was ground and between 20 and 60 μg of powdered sample was loaded into Exetainer vials and sealed with silicone rubber septa using a screw cap. The samples were flushed with CP grade helium, then acidified with 104% orthophosphoric acid, left to react for 1 hour at 70 degrees Celsius and then analysed using a Thermo Gasbench preparation system attached to a Thermo Delta V mass spectrometer in continuous flow mode. Each run of samples was accompanied by 10 reference carbonates (Carrara Z) and 2 control samples (Fletton Clay). Carrara Z has been calibrated to VPDB using the international standard NBS19. The results are reported with reference to the international standard VPDB and the precision is better than ±0.08 per mil for d13C and ± 0.10 per mil for d18O. The record was generated by D.A. Hodell.
Keyword(s):
Heinrich Stadials; Interstadials; MIS 3; Portuguese Margin
Supplement to:
Margari, Vasiliki; Skinner, Luke C; Menviel, Laurie; Capron, Emilie; Rhodes, Rachael H; Mleneck-Vautravers, Maryline J; Ezat, Mohamed M; Martrat, Belén; Grimalt, Joan O; Hodell, David A; Tzedakis, Polychronis C (2020): Fast and slow components of interstadial warming in the North Atlantic during the last glacial. Communications Earth & Environment, 1(1), https://doi.org/10.1038/s43247-020-0006-x
Further details:
Buizert, Christo; Cuffey, Kurt M; Severinghaus, Jeffrey P; Baggenstos, Daniel; Fudge, Tyler J; Steig, Eric J; Markle, Bradley R; Winstrup, Mai; Rhodes, Rachael H; Brook, Edward J; Sowers, Todd A; Clow, Gary D; Cheng, Hai; Edwards, Ross L; Sigl, Michael; McConnell, Joseph R; Taylor, Kendrick C (2015): The WAIS Divide deep ice core WD2014 chronology - Part 1: Methane synchronization (68–31 ka BP) and the gas age–ice age difference. Climate of the Past, 11(2), 153-173, https://doi.org/10.5194/cp-11-153-2015
Coverage:
Latitude: 37.565000 * Longitude: -10.134000
Minimum DEPTH, sediment/rock: 10.06 m * Maximum DEPTH, sediment/rock: 11.98 m
Event(s):
MD01-2444 * Latitude: 37.565000 * Longitude: -10.134000 * Elevation: -2656.0 m * Campaign: MD123 (GEOSCIENCES, MARMARCORE) * Basis: Marion Dufresne (1995) * Method/Device: Calypso Corer (CALYPSO)
Size:
78 data points

Data

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Depth sed [m]

δ13C carb [‰ PDB]

δ18O carb [‰ PDB]

Sed layer
10.060.04-7.31HL4
10.060.33-6.13HL4
10.06-0.40-5.96HL4
10.06-0.73-5.87HL4
10.060.76-5.85HL4
10.061.20-7.02HL4
10.060.21-4.69HL4
10.061.56-7.77HL4
10.06-0.68-4.43HL4
10.060.38-3.98HL4
10.061.86-7.42HL4
10.060.26-5.26HL4
10.06-2.44-6.15HL4
10.06-2.10-9.36HL4
10.06-0.30-7.62HL4
10.060.40-4.29HL4
10.060.76-4.22HL4
10.060.75-5.12HL4
10.06-0.75-6.15HL4
10.06-0.11-6.21HL4
10.06-0.58-4.31HL4
10.060.12-4.53HL4
10.06-1.17-7.42HL4
11.98-1.19-5.62HL5
11.98-0.65-4.92HL5
11.98-0.42-3.13HL5