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Behrens, Melanie K; Pahnke, Katharina; Cravatte, Sophie; Marin, Frédéric; Jeandel, Catherine (2020): Dissolved rare earth element distributions and physical oceanographic observations in the tropical Western Pacific during L'Atalante cruise CASSIOPEE [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.913672

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Abstract:
We present spatially highly resolved distributions of dissolved seawater REE concentrations ([REE]) along three transects in the zonal (extra-)equatorial current system and the Solomon Strait of the Tropical Western Pacific. Seawater samples were collected using Niskin bottles and filtered through AcroPak500 filter cartridges (0.8/0.45 μm pore size) directly from the Niskin bottles or in the onboard laboratory of R/V L'Atalante cruise CASSIOPEE (GEOTRACES compliant data GPc05) in July-August 2015. We use seawater [REE] in combination with direct physical oceanographic observations to characterize the geochemical composition, origin and pathways of the complex surface and upper layer currents of the Tropical Western Pacific and to quantify the input fluxes of REEs in our study area.
Keyword(s):
GEOTRACES; Rare earth elements; zonal current system
Supplement to:
Behrens, Melanie K; Pahnke, Katharina; Cravatte, Sophie; Marin, Frédéric; Jeandel, Catherine (2020): Rare earth element input and transport in the near-surface zonal current system of the Tropical Western Pacific. Earth and Planetary Science Letters, 549, 116496, https://doi.org/10.1016/J.EPSL.2020.116496
Further details:
Coverage:
Median Latitude: -3.584753 * Median Longitude: 158.481031 * South-bound Latitude: -6.332800 * West-bound Longitude: 152.494500 * North-bound Latitude: -0.999300 * East-bound Longitude: 165.003200
Date/Time Start: 2015-07-27T04:27:00 * Date/Time End: 2015-08-12T16:01:00
Minimum Elevation: -4445.0 m * Maximum Elevation: -1479.0 m
Event(s):
CASSIOPEE_14  * Latitude: -6.333000 * Longitude: 165.000667 * Date/Time: 2015-07-27T06:04:54 * Elevation: -3710.0 m * Campaign: CASSIOPEE (GPc05) * Basis: L Atalante * Method/Device: CTD/Rosette (CTD-RO)
CASSIOPEE_19  * Latitude: -4.666000 * Longitude: 164.998700 * Date/Time: 2015-07-28T08:57:00 * Elevation: -2641.0 m * Campaign: CASSIOPEE (GPc05) * Basis: L Atalante * Method/Device: CTD/Rosette (CTD-RO)
CASSIOPEE_24  * Latitude: -3.000500 * Longitude: 165.001833 * Date/Time: 2015-07-29T12:57:10 * Elevation: -4100.0 m * Campaign: CASSIOPEE (GPc05) * Basis: L Atalante * Method/Device: CTD/Rosette (CTD-RO)
Comment:
Seawater REEs were purified and pre-concentrated using the automated seaFAST-pico system in offline mode (Elemental Scientific Inc., Nebraska, USA) and measured by isotope dilution (ID) inductively coupled plasma-mass spectrometry (ICP-MS) following the method described in Behrens et al. (2016). Seawater volumes of ~11-55 mL (pH = 2) per sample were spiked with a multi-element spike and passed together with a buffer solution (pH = 6) and MilliQ water through the seaFAST column containing a REE-complexing resin (Nobias PA-1) that allows to wash out the seawater matrix. Total procedural onboard blanks of (onboard) MilliQ water and lab blanks were processed through the seaFAST column and subsequently spiked with a diluted multi-element REE isotope spike for quantification.
Dissolved REE concentrations were analyzed using a Thermo Finnigan Element 2 ICP-MS coupled to an autosampler (CETAC ASX-100) and a desolvation introduction system (CETAC Aridus 2) (Behrens et al., 2016). Average instrumental blanks of 2% HNO3 were subtracted for each sample. The accuracy was checked with replicates of the GEOTRACES seawater standard SAFe 3000 m and average [REE] agreed within the 2 RSD confidence interval of the published intercomparison study (Behrens et al., 2016). The external error (≤2.3% for all REEs, except for Ce with 8.2%, 1 RSD) is derived from independently processed seawater replicates from a sample from station 50 at 1001 m water depth (sample 50-2-8, n = 4). If the internal error of a sample was higher than this external error, the internal error is reported. Average total procedural onboard (n = 8) and lab blanks (n = 14) were ≤1.9% for all REEs, except for Ce (4.9%, n = 20, and 28%, n = 2) of the average sample concentration.
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Event labelEventBehrens, Melanie K
ProjectProjectBehrens, Melanie K
CampaignCampaignBehrens, Melanie KExpedition
Station labelStationBehrens, Melanie K
Sample IDSample IDBehrens, Melanie K
Cast numberCastBehrens, Melanie KDevice: CTD, Cast number
DATE/TIMEDate/TimeBehrens, Melanie KGeocode – UTC
LATITUDELatitudeBehrens, Melanie KGeocode
LONGITUDELongitudeBehrens, Melanie KGeocode
10 ELEVATIONElevationm a.s.l.Behrens, Melanie KGeocode
11 Bottle numberBottleBehrens, Melanie K
12 DEPTH, waterDepth watermBehrens, Melanie KGeocode
13 SalinitySalBehrens, Melanie K
14 Temperature, water, potentialTpot°CBehrens, Melanie K
15 Density, potentialDens potkg/m3Behrens, Melanie K
16 Neutral densitygamma nkg/m3Behrens, Melanie K
17 OxygenO2µmol/kgBehrens, Melanie K
18 Lanthanum, dissolvedLa disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
19 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2La 1 RSD (see comment)
20 Cerium, dissolvedCe disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
21 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2Ce 1 RSD (see comment)
22 Praseodymium, dissolvedPr disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
23 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2Pr 1 RSD (see comment)
24 Neodymium, dissolvedNd disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
25 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2Nd 1 RSD (see comment)
26 Samarium, dissolvedSm disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
27 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2Sm 1 RSD (see comment)
28 Europium, dissolvedEu disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
29 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2Eu 1 RSD (see comment)
30 Gadolinium, dissolvedGd disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
31 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2Gd 1 RSD (see comment)
32 Terbium, dissolvedTb disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
33 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2Tb 1 RSD (see comment)
34 Dysprosium, dissolvedDy disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
35 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2Dy 1 RSD (see comment)
36 Holmium, dissolvedHo disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
37 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2Ho 1 RSD (see comment)
38 Erbium, dissolvedEr disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
39 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2Er 1 RSD (see comment)
40 Thulium, dissolvedTm disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
41 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2Tm 1 RSD (see comment)
42 Ytterbium, dissolvedYb disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
43 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2Yb 1 RSD (see comment)
44 Lutetium, dissolvedLu disspmol/kgBehrens, Melanie KICP-MS, Thermo Finnigan, Element 2
45 Standard deviation, relativeStd dev r%Behrens, Melanie KICP-MS, Thermo Finnigan, Element 2Lu 1 RSD (see comment)
Size:
1404 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Event

Project

Campaign
(Expedition)

Station

Sample ID

Cast
(Device: CTD, Cast number)

Date/Time
(UTC)

Latitude

Longitude
10 
Elevation [m a.s.l.]
11 
Bottle
12 
Depth water [m]
13 
Sal
14 
Tpot [°C]
15 
Dens pot [kg/m3]
16 
gamma n [kg/m3]
17 
O2 [µmol/kg]
18 
La diss [pmol/kg]
19 
Std dev r [%]
(La 1 RSD (see comment))
20 
Ce diss [pmol/kg]
21 
Std dev r [%]
(Ce 1 RSD (see comment))
22 
Pr diss [pmol/kg]
23 
Std dev r [%]
(Pr 1 RSD (see comment))
24 
Nd diss [pmol/kg]
25 
Std dev r [%]
(Nd 1 RSD (see comment))
26 
Sm diss [pmol/kg]
27 
Std dev r [%]
(Sm 1 RSD (see comment))
28 
Eu diss [pmol/kg]
29 
Std dev r [%]
(Eu 1 RSD (see comment))
30 
Gd diss [pmol/kg]
31 
Std dev r [%]
(Gd 1 RSD (see comment))
32 
Tb diss [pmol/kg]
33 
Std dev r [%]
(Tb 1 RSD (see comment))
34 
Dy diss [pmol/kg]
35 
Std dev r [%]
(Dy 1 RSD (see comment))
36 
Ho diss [pmol/kg]
37 
Std dev r [%]
(Ho 1 RSD (see comment))
38 
Er diss [pmol/kg]
39 
Std dev r [%]
(Er 1 RSD (see comment))
40 
Tm diss [pmol/kg]
41 
Std dev r [%]
(Tm 1 RSD (see comment))
42 
Yb diss [pmol/kg]
43 
Std dev r [%]
(Yb 1 RSD (see comment))
44 
Lu diss [pmol/kg]
45 
Std dev r [%]
(Lu 1 RSD (see comment))
CASSIOPEE_14 GEOTRACES compliant data GPc05CASSIOPEE1414-1-7+812015-07-27T04:27-6.3328165.0002-37097+86.734.8829.8421.6921.711803.102.31.378.20.691.53.331.20.661.60.203.61.171.40.180.91.402.10.371.01.171.70.141.80.621.50.091.1
CASSIOPEE_14GEOTRACES compliant data GPc05CASSIOPEE1414-1-5+612015-07-27T04:27-6.3328165.0002-37095+629.034.8829.8521.6921.681803.092.31.388.20.702.03.301.80.652.40.201.31.192.60.182.51.422.40.360.71.193.50.131.90.652.50.091.1
CASSIOPEE_14GEOTRACES compliant data GPc05CASSIOPEE141-3+412015-07-27T04:27-6.3328165.0002-37093+494.035.5829.1122.4622.481653.922.91.538.20.803.33.723.50.743.40.231.31.274.10.211.01.631.80.461.61.541.10.201.81.072.30.162.0
CASSIOPEE_19 GEOTRACES compliant data GPc05CASSIOPEE191-7+812015-07-28T08:57-4.6660164.9987-26417+86.034.8229.8021.6621.671823.372.31.498.20.711.53.432.00.671.60.211.01.221.90.182.01.461.70.381.11.191.40.140.80.672.10.101.4
CASSIOPEE_19GEOTRACES compliant data GPc05CASSIOPEE191-5+612015-07-28T08:57-4.6660164.9987-26415+626.034.8229.8121.6521.671823.492.31.528.20.731.63.412.20.692.80.211.61.242.40.192.81.403.00.391.31.193.10.152.00.692.20.101.1
CASSIOPEE_19GEOTRACES compliant data GPc05CASSIOPEE191-3+412015-07-28T08:57-4.6660164.9987-26413+460.035.6229.7222.2922.301733.912.31.968.20.791.53.631.50.723.10.221.21.292.10.201.81.583.00.461.61.491.70.201.91.061.50.172.5
CASSIOPEE_24 GEOTRACES compliant data GPc05CASSIOPEE241-7+812015-07-29T11:52-3.0007165.0022-41307+86.034.6229.6921.5521.551803.842.32.388.20.941.94.421.30.991.60.310.81.652.60.251.41.961.90.492.21.640.80.201.21.102.10.171.1
CASSIOPEE_24GEOTRACES compliant data GPc05CASSIOPEE241-5+612015-07-29T11:52-3.0007165.0022-41305+626.034.6329.7121.5521.561803.962.32.318.20.981.54.481.21.023.10.321.91.732.30.261.81.942.30.521.91.601.10.211.51.082.50.171.1
CASSIOPEE_24GEOTRACES compliant data GPc05CASSIOPEE241-3+412015-07-29T11:52-3.0007165.0022-41303+471.035.0730.1221.7421.761833.212.31.268.20.712.83.331.20.681.60.211.21.212.00.190.91.501.20.411.41.380.80.171.30.861.50.131.1
CASSIOPEE_29 GEOTRACES compliant data GPc05CASSIOPEE291-7+812015-07-30T19:54-1.3338165.0032-44557+89.034.3429.4821.4121.411815.672.34.128.21.511.56.802.11.651.60.501.42.581.40.400.93.002.60.701.62.331.40.301.61.872.20.291.4
CASSIOPEE_29GEOTRACES compliant data GPc05CASSIOPEE291-5+612015-07-30T19:54-1.3338165.0032-44555+625.034.3529.4921.4121.421815.902.34.208.21.531.56.902.41.641.80.511.52.591.70.401.43.001.50.710.72.370.80.301.21.811.50.291.7
CASSIOPEE_29GEOTRACES compliant data GPc05CASSIOPEE291-3+412015-07-30T19:54-1.3338165.0032-44553+489.034.8428.4122.1422.161694.013.12.408.20.961.74.563.81.002.80.320.81.684.70.273.42.054.10.543.31.794.50.242.61.363.00.223.1
CASSIOPEE_47 GEOTRACES compliant data GPc05CASSIOPEE472-15+1622015-08-06T03:54-1.4987157.5003-176615+164.434.2929.0521.5121.511825.262.33.778.21.351.96.342.81.452.10.453.92.253.40.362.42.701.80.652.52.161.30.282.21.651.50.261.7
CASSIOPEE_47GEOTRACES compliant data GPc05CASSIOPEE472-11+1222015-08-06T03:54-1.4987157.5003-176611+1225.034.4828.8621.7221.721825.022.43.358.21.282.25.963.11.402.00.431.72.231.40.351.82.581.60.631.22.051.40.271.61.591.80.261.9
CASSIOPEE_47GEOTRACES compliant data GPc05CASSIOPEE472-6+722015-08-06T03:54-1.4987157.5003-17666+760.034.9528.1222.3222.341793.972.32.488.21.022.24.692.21.042.90.332.11.842.70.272.72.092.80.541.91.752.70.230.81.313.40.221.5
CASSIOPEE_50 GEOTRACES compliant data GPc05CASSIOPEE501-7+812015-08-06T19:36-3.0012157.5003-17217+84.034.7129.1021.8121.821803.382.61.928.20.843.63.795.00.814.30.263.81.383.30.213.31.694.70.433.41.464.50.173.90.933.30.152.4
CASSIOPEE_50GEOTRACES compliant data GPc05CASSIOPEE501-5+612015-08-06T19:36-3.0012157.5003-17215+624.034.7629.1621.8321.831793.562.61.768.20.851.93.913.60.822.10.271.11.413.70.222.21.723.90.441.31.473.70.170.70.944.50.151.1
CASSIOPEE_50GEOTRACES compliant data GPc05CASSIOPEE501-3+412015-08-06T19:36-3.0012157.5003-17213+455.035.4229.1822.3222.321663.402.31.448.20.771.53.421.20.711.70.221.71.322.20.200.91.611.90.480.71.581.00.210.81.132.90.181.8
CASSIOPEE_54 GEOTRACES compliant data GPc05CASSIOPEE541-9+1012015-08-07T17:31-4.9988157.4995-14719+105.034.9728.8922.0822.081793.132.31.548.20.761.53.403.40.693.20.212.11.212.80.184.31.443.50.382.51.182.60.142.30.732.00.102.6
CASSIOPEE_54GEOTRACES compliant data GPc05CASSIOPEE541-7+812015-08-07T17:31-4.9988157.4995-14717+824.034.9728.9022.0822.081783.352.31.708.20.792.83.532.30.713.20.222.11.241.40.182.11.412.10.380.71.192.60.141.20.674.50.102.4
CASSIOPEE_54GEOTRACES compliant data GPc05CASSIOPEE541-5+612015-08-07T17:31-4.9988157.4995-14715+674.035.3728.3622.5522.551463.352.81.468.20.732.83.304.90.672.90.212.51.223.80.204.41.662.00.453.41.564.20.214.01.142.40.183.8
CASSIOPEE_57 GEOTRACES compliant data GPc05CASSIOPEE571-7+812015-08-08T10:23-6.1663156.8328-23967+86.035.0128.8622.1222.121803.322.31.338.20.711.53.241.40.662.60.201.21.211.70.181.11.421.50.391.41.232.20.152.90.752.40.111.3
CASSIOPEE_57GEOTRACES compliant data GPc05CASSIOPEE571-5+612015-08-08T10:23-6.1663156.8328-23965+610.035.0128.8622.1222.121793.452.31.308.20.713.73.311.50.662.60.211.21.162.00.182.41.440.90.380.71.271.80.152.10.721.50.112.1
CASSIOPEE_57GEOTRACES compliant data GPc05CASSIOPEE571-3+412015-08-08T10:23-6.1663156.8328-23963+445.035.0128.8722.1222.111802.942.31.378.20.711.53.262.20.641.60.212.11.161.70.181.61.442.20.373.31.221.50.142.60.715.30.111.3
CASSIOPEE_60 GEOTRACES compliant data GPc05CASSIOPEE601-21+2212015-08-09T16:17-5.1417154.3325-254421+228.035.0128.1122.4022.371803.542.32.458.20.881.53.902.30.861.60.271.41.431.40.231.31.741.40.460.71.491.60.191.30.971.70.151.9
CASSIOPEE_63 GEOTRACES compliant data GPc05CASSIOPEE631-7+812015-08-10T15:11-5.1417154.3325-28007+86.035.0328.3622.3022.311823.552.32.308.20.861.54.011.20.801.60.251.61.372.70.211.61.661.20.440.71.451.00.180.50.941.90.151.5
CASSIOPEE_63GEOTRACES compliant data GPc05CASSIOPEE631-5+612015-08-10T15:11-5.1417154.3325-28005+626.035.0328.3622.3022.301813.552.32.538.20.902.94.072.60.843.30.263.21.376.20.214.91.714.10.443.11.484.60.175.00.914.60.143.4
CASSIOPEE_63GEOTRACES compliant data GPc05CASSIOPEE631-3+412015-08-10T15:11-5.1417154.3325-28003+451.035.0527.7222.5222.531794.772.35.898.21.371.56.441.31.361.60.411.72.021.40.302.72.391.00.570.71.980.80.250.81.472.20.231.1
CASSIOPEE_66 GEOTRACES compliant data GPc05CASSIOPEE661-17+1812015-08-11T21:18-2.4983152.4945-221517+184.035.0528.4922.2722.281754.923.41.998.20.713.93.455.20.663.60.204.11.153.30.180.91.411.60.381.01.293.80.162.30.793.10.123.4
CASSIOPEE_66GEOTRACES compliant data GPc05CASSIOPEE661-15+1612015-08-11T21:18-2.4983152.4945-221515+1610.035.0528.5022.2722.271743.262.31.358.20.731.53.822.10.662.60.211.71.241.80.180.91.461.80.391.01.260.80.151.90.771.50.121.1
CASSIOPEE_66GEOTRACES compliant data GPc05CASSIOPEE661-9+1012015-08-11T21:18-2.4983152.4945-22159+1025.035.0528.5022.2722.271743.492.31.768.20.731.53.463.60.693.50.211.81.184.10.182.81.513.10.391.31.332.20.150.50.792.70.121.4
CASSIOPEE_66GEOTRACES compliant data GPc05CASSIOPEE661-7+812015-08-11T21:18-2.4983152.4945-22157+851.035.0528.5022.2722.281743.542.31.808.20.791.53.491.20.702.20.222.41.244.20.190.91.523.50.391.81.273.10.150.80.763.20.122.6
CASSIOPEE_66GEOTRACES compliant data GPc05CASSIOPEE661-1+212015-08-11T21:18-2.4983152.4945-22151+2100.035.3527.1022.9522.961414.882.32.498.20.881.53.832.20.771.60.251.21.351.40.211.51.741.80.492.61.622.30.223.41.242.10.211.1
CASSIOPEE_69 GEOTRACES compliant data GPc05CASSIOPEE691-7+812015-08-12T16:01-0.9993152.5010-42747+86.034.5028.6221.8121.821828.012.34.328.21.431.56.202.61.512.90.451.92.192.80.351.42.662.30.651.32.221.00.280.51.681.50.271.4
CASSIOPEE_69GEOTRACES compliant data GPc05CASSIOPEE691-5+612015-08-12T16:01-0.9993152.5010-42745+625.034.5028.6121.8221.821818.272.310.498.21.961.58.101.21.661.60.501.22.421.40.370.92.732.40.651.52.161.30.281.31.651.50.261.6
CASSIOPEE_69GEOTRACES compliant data GPc05CASSIOPEE691-3+412015-08-12T16:01-0.9993152.5010-42743+456.034.8628.4422.1522.151793.002.32.058.20.861.53.961.20.871.60.281.01.471.70.231.81.752.00.471.11.541.30.201.61.071.50.171.3