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Zeppenfeld, Sebastian; van Pinxteren, Manuela; Herrmann, Hartmut (2020): Free neutral monosaccharides and combined monosaccharides in seawater and related saline matrices [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.910575

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Abstract:
Bulk seawater, surface microlayer, ice core and brine samples from the Arctic, the North and Tropical Atlantic and Raunefjorden were investigated on their sugar concentrations. Free neutral monosaccharides (DFCHO) and combined monosaccharides/polysaccharides (CCHO) were determined using high performance anionic exchange chromatography with pulsed amperometric detection (HPAEC-PAD) and electro-dialysis for prior desalination.
Keyword(s):
amino sugars; arabinose; brine; combined monosaccharides; free monosaccharides; fructose; fucose; galactose; glucose; HPAEC-PAD; Ice core; mannose; polysaccharides; rhamnose; sea surface microlayer; seawater; uronic acids; xylose
Supplement to:
Zeppenfeld, Sebastian; van Pinxteren, Manuela; Engel, Anja; Herrmann, Hartmut (2020): A protocol for quantifying mono- and polysaccharides in seawater and related saline matrices by electro-dialysis (ED) - combined with HPAEC-PAD. Ocean Science, 16(4), 817-830, https://doi.org/10.5194/os-16-817-2020
Project(s):
Funding:
German Research Foundation (DFG), grant/award no. 268020496: TRR 172: ArctiC Amplification: Climate Relevant Atmospheric and SurfaCe Processes, and Feedback Mechanisms
Coverage:
Median Latitude: 59.096222 * Median Longitude: 3.993950 * South-bound Latitude: 16.935000 * West-bound Longitude: -24.915000 * North-bound Latitude: 81.824000 * East-bound Longitude: 26.882700
Date/Time Start: 2011-05-16T00:00:00 * Date/Time End: 2017-07-14T00:00:00
Minimum DEPTH, water: 0.00 m * Maximum DEPTH, water: 2.00 m
Event(s):
CapeVerde-WS_2011  * Latitude: 16.935000 * Longitude: -24.915000 * Date/Time: 2011-11-13T00:00:00 * Location: Cape Verde * Method/Device: Water sample (WS)
PS79/324-WS  * Latitude: 33.300000 * Longitude: -13.500000 * Date/Time: 2012-05-07T00:00:00 * Location: North Atlantic * Campaign: ANT-XXVIII/5 (PS79) * Basis: Polarstern * Method/Device: Water sample (WS)
PS106_30-ICEM  * Latitude: 81.824000 * Longitude: 11.571000 * Date/Time: 2017-06-12T00:00:00 * Location: Arctic Ocean * Campaign: PS106/1 (ARK-XXXI/1.1,PASCAL) * Basis: Polarstern * Method/Device: Ice measurement (ICEM)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Event labelEventZeppenfeld, Sebastian
Latitude of eventLatitudeZeppenfeld, Sebastian
Longitude of eventLongitudeZeppenfeld, Sebastian
Sample code/labelSample labelZeppenfeld, Sebastian
Area/localityAreaZeppenfeld, Sebastian
DATE/TIMEDate/TimeZeppenfeld, SebastianGeocode
CampaignCampaignZeppenfeld, Sebastian
DEPTH, waterDepth watermZeppenfeld, SebastianGeocode – #0 = SML
Depth, top/minDepth topmZeppenfeld, Sebastian
10 Depth, bottom/maxDepth botmZeppenfeld, Sebastian
11 Carbohydrates, dissolved combinedDCCHOnmol/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)
12 FucoseFuc%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)dissolved, combined, mol%
13 RhamnoseRha%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)dissolved, combined, mol%
14 GalactosamineGalN%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)dissolved, combined, mol%
15 ArabinoseAra%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)dissolved, combined, mol%
16 GlucosamineGlcN%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)dissolved, combined, mol%
17 GalactoseGal%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)dissolved, combined, mol%
18 GlucoseGlc%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)dissolved, combined, mol%
19 Mannose/XyloseMan/Xyl%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)dissolved, combined, mol%
20 Galacturonic acidGalA%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)dissolved, combined, mol%
21 Glucuronic acidGlcA%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)dissolved, combined, mol%
22 Carbohydrates, dissolved, neutral freeDFCHOnmol/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)
23 FucoseFuc%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)free, dissolved, mol%
24 RhamnoseRha%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)free, dissolved, mol%
25 ArabinoseAra%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)free, dissolved, mol%
26 GalactoseGal%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)free, dissolved, mol%
27 GlucoseGlc%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)free, dissolved, mol%
28 Mannose/XyloseMan/Xyl%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)free, dissolved, mol%
29 FructoseFru%Zeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)free, dissolved, mol%
Size:
204 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Event

Latitude

Longitude

Sample label

Area

Date/Time

Campaign

Depth water [m]
(#0 = SML)

Depth top [m]
10 
Depth bot [m]
11 
DCCHO [nmol/l]
12 
Fuc [%]
(dissolved, combined, mol%)
13 
Rha [%]
(dissolved, combined, mol%)
14 
GalN [%]
(dissolved, combined, mol%)
15 
Ara [%]
(dissolved, combined, mol%)
16 
GlcN [%]
(dissolved, combined, mol%)
17 
Gal [%]
(dissolved, combined, mol%)
18 
Glc [%]
(dissolved, combined, mol%)
19 
Man/Xyl [%]
(dissolved, combined, mol%)
20 
GalA [%]
(dissolved, combined, mol%)
21 
GlcA [%]
(dissolved, combined, mol%)
22 
DFCHO [nmol/l]
23 
Fuc [%]
(free, dissolved, mol%)
24 
Rha [%]
(free, dissolved, mol%)
25 
Ara [%]
(free, dissolved, mol%)
26 
Gal [%]
(free, dissolved, mol%)
27 
Glc [%]
(free, dissolved, mol%)
28 
Man/Xyl [%]
(free, dissolved, mol%)
29 
Fru [%]
(free, dissolved, mol%)
CapeVerde-WS_2011 16.9350-24.9150Sea water 1Tropical Atlantic2011-11-13Cape Verde#0.00678.38637.00756.78772.85318.07493.728115.024020.110821.963311.75242.698215.12856.9699#0.00008.39767.818157.1105#0.000019.7039
CapeVerde-WS_201116.9350-24.9150Sea water 2Tropical Atlantic2011-11-13Cape Verde2.00286.34817.48008.30902.08196.75072.742912.173024.596524.088810.80520.972013.6338#0.0000#0.0000#0.0000#0.000051.7707#0.000048.2293
Raunefjorden_WS_2011 60.27405.1810Sea water 3Raunefjorden2011-05-16Raunefjorden2.00576.41699.92449.26373.07518.56075.559413.727319.771321.05217.40091.665211.3162#0.0000#0.00004.9987#0.000080.242014.7593#0.0000
PS79/324-WS 33.3000-13.5000Sea water 4North Atlantic2012-05-07ANT-XXVIII/5#0.00410.80625.58685.36171.74897.29672.961912.030431.088826.17415.66152.089113.6372#0.0000#0.00007.5996#0.000086.98955.4109#0.0000
PS106_83-WS 81.229018.7440Sea water 5Arctic Ocean2017-07-13PS106/21.001408.00741.55752.11990.82852.22541.29672.877883.69252.1091#0.00003.292534.7391#0.0000#0.00003.83813.195689.47703.4892#0.0000
PS106_ZODIAK_170714 81.015326.8827Sea water 6Arctic Ocean2017-07-14PS106/21.00261.28531.86513.96342.3293#0.00004.07637.010448.435310.437914.98266.899927.192133.6032#0.000019.61358.165016.330122.2881#0.0000
PS106_30-ICEM 81.824011.5710Ice Core 1Arctic Ocean2017-06-12PS106/100.8332.2616#0.00001.10001.67911.40451.37389.188153.792011.309110.076710.0767118.101814.95802.5790#0.00005.639850.37441.539524.9093
PS106_30-ICEM81.824011.5710Brine 1Arctic Ocean2017-06-12PS106/100.8420.59104.05544.05543.37642.53614.823411.481646.718113.4011#0.00009.552614.528429.35048.3858#0.000026.743823.005412.5147#0.0000
PS106_30-ICEM81.824011.5710Brine 2Arctic Ocean2017-06-12PS106/101.5636.85024.49573.34781.75201.46553.18557.844265.01949.8972#0.00002.992652.98035.74892.29961.25832.095485.16603.4318#0.0000