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Therre, Steffen; Fohlmeister, Jens; Fleitmann, Dominik; Matter, Albert; Burns, Stephen J; Arps, Jennifer; Schröder-Ritzrau, Andrea; Friedrich, Ronny; Frank, Norbert (2019): Uranium and Thorium in stalagmite M1-5 from Moomi Cave, Socotra Island [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.906002, In: Therre, S et al. (2019): U-series and radiocarbon dating results of stalagmite M1-5 from Moomi Cave, Socotra Island [dataset publication series]. PANGAEA, https://doi.org/10.1594/PANGAEA.906003

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Abstract:
In this study, the dead carbon fraction (DCF) variations in stalagmite M1-5 from Socotra Island in the western Arabian Sea were investigated through a new set of high-precision U-series and radiocarbon (14C) dates. The data reveal an extreme case of very high and also climate dependent DCF values. For M1-5 an average DCF of 56.2 ± 3.4 % is observed between 27 and 18 kyr BP. Such high DCF values indicate a high influence of aged soil organic matter (SOM) and nearly completely closed system carbonate dissolution conditions. Towards the end of the last glacial period decreasing Mg/Ca ratios suggest an increase in precipitation which caused a marked change in the soil carbon cycling as indicated by sharply decreasing DCF. This is in contrast to the relation of soil infiltration and reservoir age observed in stalagmites from temperate zones. For Socotra Island, which is influenced by the East African-Indian monsoon, we propose that more humid conditions and enhanced net-infiltration after the LGM led to denser vegetation and thus lowered the DCF by increased 14CO2 input into the soil zone. The onset of the Younger Dryas (YD) is represented in the record by the end of DCF decrease with a sudden change to much higher and extremely variable reservoir ages. Our study highlights the dramatic variability of soil carbon cycling processes and vegetation feedback on Socotra Island manifested in stalagmite reservoir ages on both long-term trends and sub-centennial timescales, thus providing evidence for climate influence on stalagmite radiocarbon. This is of particular importance for studies focussing on 14C calibration and atmospheric reconstruction through stalagmites which relies on largely climate independent soil carbon cycling above the cave.
Keyword(s):
Dead Carbon Fraction; radiocarbon; Socotra; speleothem; U-series
Supplement to:
Therre, Steffen; Fohlmeister, Jens; Fleitmann, Dominik; Matter, Albert; Burns, Stephen J; Arps, Jennifer; Schröder-Ritzrau, Andrea; Friedrich, Ronny; Frank, Norbert (2020): Climate-induced speleothem radiocarbon variability on Socotra Island from the Last Glacial Maximum to the Younger Dryas. Climate of the Past, 16(1), 409-421, https://doi.org/10.5194/cp-16-409-2020
Coverage:
Latitude: 12.544444 * Longitude: 54.316667
Minimum DISTANCE: 7.8 cm * Maximum DISTANCE: 222.4 cm
Event(s):
Moomi_Cave_M1-5 (Moomi_Cave_2002) * Latitude: 12.544444 * Longitude: 54.316667 * Elevation: 400.0 m * Location: Socotra Island, Arabian Sea * Method/Device: Speleothem sample (SPS) * Comment: Sample year: 2002
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Laboratory code/labelLab labelTherre, SteffenHD lab nr.
DISTANCEDistancecmTherre, SteffenGeocode – Distance from top
Uranium-238238Ung/gTherre, Steffenppb
Uranium-238, standard deviation238U std dev±Therre, Steffen
Thorium-232232Thpg/gTherre, Steffenppt
Thorium-232, standard deviation232Th std dev±Therre, Steffen
Thorium-230/Thorium-232 activity ratio(230Th/232Th)Therre, Steffen
Thorium-230/Thorium-232 activity ratio, standard deviation(230Th/232Th) std dev±Therre, Steffen
δ234 Uraniumδ234UTherre, Steffenmeas
10 δ234 Uranium, standard deviationδ234U std dev±Therre, Steffenmeas; 2σ
11 AGEAgeka BPTherre, SteffenGeocode – corrected; before 1950
12 Age, standard deviationAge std dev±Therre, Steffencorrected; 2σ
13 δ234 Uraniumδ234UTherre, Steffeninit
14 δ234 Uranium, standard deviationδ234U std dev±Therre, Steffeninit; 2σ
Size:
740 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Lab label
(HD lab nr.)

Distance [cm]
(Distance from top)

238U [ng/g]
(ppb)

238U std dev [±]
(2σ)

232Th [pg/g]
(ppt)

232Th std dev [±]
(2σ)

(230Th/232Th)

(230Th/232Th) std dev [±]
(2σ)

δ234U []
(meas)
10 
δ234U std dev [±]
(meas; 2σ)
11 
Age [ka BP]
(corrected; before 1950)
12 
Age std dev [±]
(corrected; 2σ)
13 
δ234U []
(init)
14 
δ234U std dev [±]
(init; 2σ)
78277.8940.9380.038-61.240.6510.8900.034-63.150.67
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724110.9700.5002.900555.00011.0001900.0040.00-63.202.1011.1130.081-65.202.20
780111.8922.6270.074693.2005.800392.704.40-55.560.3711.7320.095-57.430.38
780212.81442.8600.150251.6001.0001721.409.60-47.670.9111.8830.049-49.300.94
7242a13.71107.1006.600456.1009.6003939.0087.00-48.802.6011.8400.120-50.502.70
7242b13.71112.5003.100456.0009.3003939.0081.00-47.101.2011.7580.058-48.701.20
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7243b17.21691.4004.3001758.00036.0001577.0032.00-43.801.2011.8850.057-45.301.20
724420.41243.2004.300134.5002.80015110.00320.00-48.501.6011.9490.070-50.201.70
724523.31515.0004.400488.0009.9005160.00110.00-41.601.2012.0430.060-43.001.20
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8155166.52339.8690.0832208.2006.400481.102.20-105.570.7119.9490.080-111.690.75
7817170.22085.6700.1005517.00012.000188.190.61-91.780.4421.4050.072-97.500.47
8156170.72330.2840.0791850.3005.300582.902.50-105.830.6520.3660.075-112.100.69
8157174.92240.6300.087387.5001.1002665.0012.00-125.270.6420.8240.084-132.860.68
7818178.71732.0070.0671892.8003.500452.001.30-104.680.3621.6230.058-111.280.38
7819186.32377.3540.085658.9001.7001803.306.60-107.780.2522.0580.065-114.710.27
8158186.32050.2110.087567.2001.3001792.306.10-109.440.7022.1350.065-116.510.75
8159189.92004.6090.09113696.00037.00074.060.34-102.590.5922.2700.140-109.250.63
7820193.02308.2400.110864.9001.6001483.104.10-72.370.3023.7580.055-77.400.32
7821199.41517.2820.0641124.1002.300770.502.10-74.650.4224.5300.054-80.010.45
7822207.42019.7570.0931322.1002.300896.902.40-77.250.2825.3960.059-83.000.30
7823215.01871.4030.0714551.3007.100246.600.60-82.280.3226.1370.073-88.590.35
7824222.41856.1950.08621042.00036.00055.500.10-76.730.3927.1100.200-82.840.42