PANGAEA_905430 A database for carbonyl sulfide (OCS) and carbon disulfide (CS2) in seawater and marine boundary layer Lennartz, Sinikka T; Marandino, Christa A; von Hobe, Marc; Andreae, Meinrat O; Aranami, Kazushi; Atlas, Elliot L; Berkelhammer, Max; Bingemer, Heinz G; Booge, Dennis; Cutter, Gregory A; Cortes, Pau; Kremser, Stefanie; Law, Cliff S; Marriner, Andrew; Simo, Rafel; Quack, Birgit; Uher, Günther; Xie, Huixiang; Xu, Xiaobin A database for carbonyl sulfide (OCS) and carbon disulfide (CS2) in seawater and marine boundary layer 2019-09-02 PANGAEA Dataset Supplement to: Lennartz, Sinikka T; Marandino, Christa A; von Hobe, Marc; Andreae, Meinrat O; Aranami, Kazushi; Atlas, Elliot L; Berkelhammer, Max; Bingemer, Heinz G; Booge, Dennis; Cutter, Gregory A; Cortes, Pau; Kremser, Stefanie; Law, Cliff S; Marriner, Andrew; Simo, Rafel; Quack, Birgit; Uher, Günther; Xie, Huixiang; Xu, Xiaobin (2020): Marine carbonyl sulfide (OCS) and carbon disulfide (CS2): a compilation of measurements in seawater and the marine boundary layer. Earth System Science Data, 12(1), 591-609, https://doi.org/10.5194/essd-12-591-2020 https://doi.pangaea.de/10.1594/PANGAEA.905430 Investigator Sinikka T Lennartz slennartz@geomar.de Earth Science File content File name File format File size Uniform resource locator/link to file geoscientificInformation air-sea exchange carbon disulfide carbonyl sulfide OCS_CS2_db trace gas 1982-01-01 2019-12-31 Complete -73.1 60.5 -180.0 180.0 unrestricted CC-BY-4.0: Creative Commons Attribution 4.0 International English PANGAEA Data Publisher for Earth & Environmental Science https://www.pangaea.de/ Data Center Contact Michael Diepenbroek info@pangaea.de

Leobener Str.

Bremen Bremen 28359 Germany online 30 data points text/tab-separated-values A database for carbonyl sulfide (OCS) and carbon disulfide (CS2) in seawater and marine boundary layer (xlsx file, 4444 kB) [dataset]. https://store.pangaea.de/Publications/LennartzS-etal_2019/Lennartzetal_OCSCS2_pangaea_v1_1.xlsx Aranami, Kazushi; Tsunogai, Shizuo (2004): Seasonal and regional comparison of oceanic and atmospheric dimethylsulfide in the northern North Pacific: Dilution effects on its concentration during winter. Journal of Geophysical Research, 109(D12), https://doi.org/10.1029/2003JD004288 Belviso, Sauveur; Mihalopoulos, Nikolaos; Nguyen, Ba Cuong (1967): The supersaturation of carbonyl sulfide (OCS) in rain waters. Atmospheric Environment, 21(6), 1363-1367, https://doi.org/10.1016/0004-6981(67)90083-2 Berkelhammer, Max; Steen-Larsen, Hans Christian; Cosgrove, A; Peters, Andrew J; Johnson, R; Hayden, M; Montzka, S A (2016): Radiation and atmospheric circulation controls on carbonyl sulfide concentrations in the marine boundary layer. Journal of Geophysical Research: Atmospheres, 121(21), 13,113-13,128, https://doi.org/10.1002/2016JD025437 Cutter, Gregory A; Cutter, Lynda S; Filippino, Katherine C (2004): Sources and cycling of carbonyl sulfide in the Sargasso Sea. Limnology and Oceanography, 49(2), 555-565, https://doi.org/10.4319/lo.2004.49.2.0555 Cutter, Gregory A; Radford-Knoery, J (1993): Carbonyl sulfide in two estuaries and shelf waters of the western North Atlantic Ocean. Marine Chemistry, 43(1-4), 225-233, https://doi.org/10.1016/0304-4203(93)90228-G de Gouw, Joost A; Warneke, C; Montzka, S A; Holloway, J S; Parrish, D D; Fehsenfeld, F C; Atlas, E L; Weber, Rodney J; Flocke, F M (2009): Carbonyl sulfide as an inverse tracer for biogenic organic carbon in gas and aerosol phases. Geophysical Research Letters, 36(5), https://doi.org/10.1029/2008GL036910 Ferek, Ronald J; Andreae, Meinrat O (1983): The supersaturation of carbonyl sulfide in surface waters of the Pacific Ocean off Peru. Geophysical Research Letters, 10(5), 393-396, https://doi.org/10.1029/GL010i005p00393 Ferek, Ronald J; Andreae, Meinrat O (1984): Photochemical production of carbonyl sulphide in marine surface waters. Nature, 307(5947), 148-150, https://doi.org/10.1038/307148a0 Inomata, Yayoi; Hayashi, Masahiko; Osada, Kazuo; Iwasaka, Yasunobu (2006): Spatial distributions of volatile sulfur compounds in surface seawater and overlying atmosphere in the northwestern Pacific Ocean, eastern Indian Ocean, and Southern Ocean. Global Biogeochemical Cycles, 20(2), n/a-n/a, https://doi.org/10.1029/2005GB002518 Inomata, Yayoi; Matsunaga, Katsuji; Murai, Yasuhiro; Osada, Kazuo; Iwasaka, Yasunobu (1999): Simultaneous measurement of volatile sulfur compounds using ascorbic acid for oxidant removal and gas chromatography–flame photometric detection. Journal of Chromatography A, 864(1), 111-119, https://doi.org/10.1016/S0021-9673(99)00963-2 Johnson, James E (1985): Role of the oceans in the atmospheric cycle of carbonyl sulfide [dissertation]. National Center for Atmospheric Research, Boulder, CO, USA Johnson, James E; Harrison, Halstead (1986): Carbonyl sulfide concentrations in the surface waters and above the Pacific Ocean. Journal of Geophysical Research: Atmospheres, 91(D7), 7883-7888, https://doi.org/10.1029/JD091iD07p07883 Kettle, A J; Rhee, T S; von Hobe, Marc; Poulton, A; Aiken, James; Andreae, Meinrat O (2001): Assessing the flux of different volatile sulfur gases from the ocean to the atmosphere. Journal of Geophysical Research: Atmospheres, 106(D11), 12193-12209, https://doi.org/10.1029/2000JD900630 Kim, Ki-Hyun; Andreae, Meinrat O (1987): Carbon disulfide in seawater and the marine atmosphere over the North Atlantic. Journal of Geophysical Research, 92(D12), 14733, https://doi.org/10.1029/JD092iD12p14733 Kim, Ki-Hyun; Andreae, Meinrat O (1992): Carbon disulfide in the estuarine, coastal, and oceanic environments. Marine Chemistry, 40(3-4), 179-197, https://doi.org/10.1016/0304-4203(92)90022-3 Lennartz, Sinikka T; Marandino, Christa A; von Hobe, Marc; Cortes, Pau; Quack, Birgit; Simo, Rafel; Booge, Dennis; Pozzer, Andrea; Steinhoff, Tobias; Arévalo-Martínez, Damian L; Kloss, Corinna; Bracher, Astrid; Röttgers, Rüdiger; Atlas, Elliot L; Krüger, Kirstin (2017): Direct oceanic emissions unlikely to account for the missing source of atmospheric carbonyl sulfide. Atmospheric Chemistry and Physics, 17(1), 385-402, https://doi.org/10.5194/acp-17-385-2017 Mihalopoulos, Nikolaos; Nguyen, Ba Cuong; Putaud, Jean-Philippe; Belviso, Sauveur (1992): The oceanic source of carbonyl sulfide (COS). Atmospheric Environment, 26(8), 1383-1394, https://doi.org/10.1016/0960-1686(92)90123-3 Mihalopoulos, Nikolaos; Putaud, Jean-Philippe; Nguyen, Ba Cuong; Belviso, Sauveur (1991): Annual variation of atmospheric carbonyl sulfide in the marine atmosphere in the Southern Indian Ocean. Journal of Atmospheric Chemistry, 13(1), 73-82, https://doi.org/10.1007/BF00048101 Moore, Robert M; Webb, M (1996): The relationship between methyl bromide and chlorophyll α in high latitude ocean waters. Geophysical Research Letters, 23(21), 2951-2954, https://doi.org/10.1029/96GL02772 Radford-Knȩry, Joël; Cutter, Gregory A (1994): Biogeochemistry of dissolved hydrogen sulfide species and carbonyl sulfide in the western North Atlantic Ocean. Geochimica et Cosmochimica Acta, 58(24), 5421-5431, https://doi.org/10.1016/0016-7037(94)90239-9 Staubes, R; Georgii, H-W; Bürgermeister, S (1990): Biogenic Sulfur Compounds in Seawater and the Marine Atmosphere. In: Restelli, G.; Angeletti, G. (eds.), Physico-Chemical Behaviour of Atmospheric Pollutants, Springer Netherlands, Dordrecht, 686-692, https://doi.org/10.1007/978-94-009-0567-2_104 Staubes, R; Georgii, H-W; Ockelmann, G (1989): Flux of COS, DMS and CS2 from various soils in Germany. Tellus Series B-Chemical and Physical Meteorology, 41(3), 305-313, https://doi.org/10.3402/tellusb.v41i3.15084 Uher, Günther (1994): Photochemische produktion von carbonylsulfid im oberflächenwasser der ozeane: Prozeßstudien und ein empirisches modell [dissertation]. Universität Mainz, 147 pp Ulshofer, Veit; Flock, Otmar; Uher, Günther; Andreae, Meinrat O (1996): Photochemical production and air-sea exchange of carbonyl sulfide in the eastern Mediterranean Sea. Marine Chemistry, 53(1-2), 25-39, https://doi.org/10.1016/0304-4203(96)00010-2 Ulshofer, Veit; Uher, Günther; Andreae, Meinrat O (1995): Evidence for a winter sink of atmospheric carbonyl sulfide in the northeast Atlantic Ocean. Geophysical Research Letters, 22(19), 2601-2604, https://doi.org/10.1029/95GL02656 von Hobe, Marc; Cutter, Gregory A; Kettle, A J; Andreae, Meinrat O (2001): Dark production: A significant source of oceanic COS. Journal of Geophysical Research: Oceans, 106(C12), 31217-31226, https://doi.org/10.1029/2000JC000567 von Hobe, Marc; Kenntner, Thomas; Helleis, Frank H; Sandoval-Soto, Lisseth; Andreae, Meinrat O (2000): Cryogenic trapping of carbonyl sulfide without using expendable cryogens. Analytical Chemistry, 72(21), 5513-5515, https://doi.org/10.1021/ac000585f von Hobe, Marc; Kettle, Anthony James; Andreae, Meinrat O (1999): Carbonyl sulphide in and over seawater: summer data from the northeast Atlantic Ocean. Atmospheric Environment, 33(21), 3503-3514, https://doi.org/10.1016/S1352-2310(98)00236-2 von Hobe, Marc; Kuhn, Uwe; Van Diest, Heidi; Sandoval-Soto, Lisseth; Kenntner, Thomas; Helleis, Frank H; Yonemura, Seiichiro; Andreae, Meinrat O; Kesselmeier, Jürgen (2008): Automated in situ analysis of volatile sulfur gases using a Sulfur Gas Analyser (SUGAR) based on cryogenic trapping and gas-chromatographic separation. International Journal of Environmental Analytical Chemistry, 88(5), 303-315, https://doi.org/10.1080/03067310701642081 Xie, Huixiang; Moore, Robert M (1999): Carbon disulfide in the North Atlantic and Pacific oceans. Journal of Geophysical Research: Oceans, 104(C3), 5393-5402, https://doi.org/10.1029/1998JC900074 Xu, X; Bingemer, Heinz G; Georgii, H-W; Schmidt, U; Bartell, U (2001): Measurements of carbonyl sulfide (COS) in surface seawater and marine air, and estimates of the air-sea flux from observations during two Atlantic cruises. Journal of Geophysical Research: Atmospheres, 106(D4), 3491-3502, https://doi.org/10.1029/2000JD900571 Xu, Xiaobin (2001): Investigations into the tropospheric cycle of COS : atmospheric distribution, air-sea and air-vegetation exchanges [dissertation]. Fachbereich Geowissenschaften, Johann-Wolfgang University Frankfurt Main, 174 pp

The database includes measurements of the trace gases carbonyl sulfide (OCS) and carbon disulfide (CS2) in seawater (in picomol per liter) and the marine boundary layer (parts per trillion, ppt). It consists of individual datasets compiled from published original data, digitalization from publications (pdf documents) and unpublished data. Only shipborne measurements or measurements from time series stations with a dominant marine signal are included. The database contains mainly surface ocean measurements, but few available profiles down to >1000 m are included as well. Temporal resolution ranges from 12 minutes to hourly or monthly intervals. The database includes the following metadata (if available): latitude, longitude, depth, time of sampling, meteorological and physical parameters, main reference, method, contributor(s). The database is intended to facilitate model evaluation and the identification of global patterns. Data in excel and txt-files are identical. ** For all details see the full metadata description at "https://doi.pangaea.de/10.1594/PANGAEA.905430"!

https://doi.org/10.1002/2016JD025437 Radiation and atmospheric circulation controls on carbonyl sulfide concentrations in the marine boundary layer https://doi.org/10.1007/978-94-009-0567-2_104 Biogenic Sulfur Compounds in Seawater and the Marine Atmosphere https://doi.org/10.1007/BF00048101 Annual variation of atmospheric carbonyl sulfide in the marine atmosphere in the Southern Indian Ocean https://doi.org/10.1016/0004-6981(67)90083-2 The supersaturation of carbonyl sulfide (OCS) in rain waters https://doi.org/10.1016/0016-7037(94)90239-9 Biogeochemistry of dissolved hydrogen sulfide species and carbonyl sulfide in the western North Atlantic Ocean https://doi.org/10.1016/0304-4203(92)90022-3 Carbon disulfide in the estuarine, coastal, and oceanic environments https://doi.org/10.1016/0304-4203(93)90228-G Carbonyl sulfide in two estuaries and shelf waters of the western North Atlantic Ocean https://doi.org/10.1016/0304-4203(96)00010-2 Photochemical production and air-sea exchange of carbonyl sulfide in the eastern Mediterranean Sea https://doi.org/10.1016/0960-1686(92)90123-3 The oceanic source of carbonyl sulfide (COS) https://doi.org/10.1016/S0021-9673(99)00963-2 Simultaneous measurement of volatile sulfur compounds using ascorbic acid for oxidant removal and gas chromatography–flame photometric detection https://doi.org/10.1016/S1352-2310(98)00236-2 Carbonyl sulphide in and over seawater: summer data from the northeast Atlantic Ocean https://doi.org/10.1021/ac000585f Cryogenic trapping of carbonyl sulfide without using expendable cryogens https://doi.org/10.1029/1998JC900074 Carbon disulfide in the North Atlantic and Pacific oceans https://doi.org/10.1029/2000JC000567 Dark production: A significant source of oceanic COS https://doi.org/10.1029/2000JD900571 Measurements of carbonyl sulfide (COS) in surface seawater and marine air, and estimates of the air-sea flux from observations during two Atlantic cruises https://doi.org/10.1029/2000JD900630 Assessing the flux of different volatile sulfur gases from the ocean to the atmosphere https://doi.org/10.1029/2003JD004288 Seasonal and regional comparison of oceanic and atmospheric dimethylsulfide in the northern North Pacific: Dilution effects on its concentration during winter https://doi.org/10.1029/2005GB002518 Spatial distributions of volatile sulfur compounds in surface seawater and overlying atmosphere in the northwestern Pacific Ocean, eastern Indian Ocean, and Southern Ocean https://doi.org/10.1029/2008GL036910 Carbonyl sulfide as an inverse tracer for biogenic organic carbon in gas and aerosol phases https://doi.org/10.1029/95GL02656 Evidence for a winter sink of atmospheric carbonyl sulfide in the northeast Atlantic Ocean https://doi.org/10.1029/96GL02772 The relationship between methyl bromide and chlorophyll α in high latitude ocean waters https://doi.org/10.1029/GL010i005p00393 The supersaturation of carbonyl sulfide in surface waters of the Pacific Ocean off Peru https://doi.org/10.1029/JD091iD07p07883 Carbonyl sulfide concentrations in the surface waters and above the Pacific Ocean https://doi.org/10.1029/JD092iD12p14733 Carbon disulfide in seawater and the marine atmosphere over the North Atlantic https://doi.org/10.1038/307148a0 Photochemical production of carbonyl sulphide in marine surface waters https://doi.org/10.1080/03067310701642081 Automated in situ analysis of volatile sulfur gases using a Sulfur Gas Analyser (SUGAR) based on cryogenic trapping and gas-chromatographic separation https://doi.org/10.3402/tellusb.v41i3.15084 Flux of COS, DMS and CS2 from various soils in Germany https://doi.org/10.4319/lo.2004.49.2.0555 Sources and cycling of carbonyl sulfide in the Sargasso Sea https://doi.org/10.5194/acp-17-385-2017 Direct oceanic emissions unlikely to account for the missing source of atmospheric carbonyl sulfide https://doi.org/10.5194/essd-12-591-2020 Marine carbonyl sulfide (OCS) and carbon disulfide (CS2): a compilation of measurements in seawater and the marine boundary layer https://store.pangaea.de/Publications/LennartzS-etal_2019/Lennartzetal_OCSCS2_pangaea_v1_1.xlsx A database for carbonyl sulfide (OCS) and carbon disulfide (CS2) in seawater and marine boundary layer (xlsx file, 4444 kB) DIF 9.4 2019-09-02 2026-04-30