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Pasquier, Virgil; Revillon, Sidonie; Leroux, Estelle; Molliex, Stéphane; Moccochain, Ludovic; Rabineau, Marina (2019): Depth, estimated age, and associated geochemical information from sediment core PRGL 1-4 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.902768, Supplement to: Pasquier, Virgil; Revillon, Sidonie; Leroux, Estelle; Molliex, Stéphane; Mocochain, L; Rabineau, Marina (2019): Quantifying Biogenic Versus Detrital Carbonates on Marine Shelf: An Isotopic Approach. Frontiers in Earth Science, 7, https://doi.org/10.3389/feart.2019.00164

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Abstract:
The terrigenous sedimentary budget of passive margin records variations in past sedimentary fluxes, and thus can be used to infer past variations of Earth surface deformation processes, or climate change. Accurate estimates of sediment fluxes over various times scale and space-scale are therefore crucial. Traditionally, offshore sediment sequence volumes take into account only siliciclastic accumulation, the carbonate fraction being considered only as in-situ production (i.e. CaCO3). Here we propose a new geochemical methodology to decipher and quantify the amount of detrital carbonates in comparison to in-situ produced biogenic carbonates. This isotopic approach enables taking into account the export of detrital carbonates, and investigating its effect on sediment budgets. This study, located in the Gulf of Lion, is based on a 300 m long sediment borehole located near the shelf break and covering the last 500 000 years (i.e. 5 glacial-interglacial periods). 86Sr/87Sr isotopic data (0.70809 to 0.70858) are significantly less radiogenic than modern seawater (i.e. 0.7092) and show fluctuations in agreement with stratigraphic and climatic variations. These results suggest an unsuspected high export of detrital carbonates from the catchment area during both glacial (between 55 to 85% of the sedimentary carbonate fraction) and interglacial (between 30 to 50%) conditions. Thus, not only do detrital carbonate fluxes need to be factored into sediment flux calculations, these results suggest that detrital carbonate components could potentially have a strong influence on carbonate 86Sr/87Sr ratios when not obtained from microdrilled biogenic carbonates, such as the entirety of the Precambrian Sr chemostratigraphic record.
Keyword(s):
86Sr/87Sr carbonate; Detrital carbonate export; Glacial – Interglacial; Source to sink; Strontium isotope stratigraphy
Funding:
Fifth Framework Programme (FP5), grant/award no. EVR1-CT-2002-40024: Profiles across Mediterranean Sedimentary Systems
Coverage:
Latitude: 42.690000 * Longitude: 3.838000
Minimum DEPTH, sediment/rock: 72.10 m * Maximum DEPTH, sediment/rock: 110.05 m
Event(s):
PRGL_1-4  * Latitude: 42.690000 * Longitude: 3.838000 * Elevation: -298.0 m * Location: Golf of Lion * Campaign: PROMESS1 * Basis: Bavenit * Method/Device: Core drilling (CDRILL)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Event labelEventPasquier, Virgil
Sample materialSamp matPasquier, Virgil
DEPTH, sediment/rockDepth sedmPasquier, VirgilGeocode – in mbsf
AGEAgeka BPPasquier, VirgilGeocode
Strontium-87/Strontium-86 ratio87Sr/86SrPasquier, VirgilLaser ablation multicollector - ICP-MS (LA-MC-ICP-MS)
Calcium carbonateCaCO3%Pasquier, VirgilLaser ablation multicollector - ICP-MS (LA-MC-ICP-MS)
StrontiumSrmg/kgPasquier, VirgilLaser ablation multicollector - ICP-MS (LA-MC-ICP-MS)
CalciumCamg/kgPasquier, VirgilLaser ablation multicollector - ICP-MS (LA-MC-ICP-MS)
MagnesiumMgmg/kgPasquier, VirgilLaser ablation multicollector - ICP-MS (LA-MC-ICP-MS)
10 AluminiumAlmg/kgPasquier, VirgilLaser ablation multicollector - ICP-MS (LA-MC-ICP-MS)
11 BariumBamg/kgPasquier, VirgilLaser ablation multicollector - ICP-MS (LA-MC-ICP-MS)
12 PotassiumKmg/kgPasquier, VirgilLaser ablation multicollector - ICP-MS (LA-MC-ICP-MS)
13 SodiumNamg/kgPasquier, VirgilLaser ablation multicollector - ICP-MS (LA-MC-ICP-MS)
Size:
224 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Event

Samp mat

Depth sed [m]

Age [ka BP]

87Sr/86Sr

CaCO3 [%]

Sr [mg/kg]

Ca [mg/kg]

Mg [mg/kg]
10 
Al [mg/kg]
11 
Ba [mg/kg]
12 
K [mg/kg]
13 
Na [mg/kg]
PRGL_1-4 Bulk72.10123.830.7085841.121621054994297641403130412225764
PRGL_1-4Bulk74.07132.130.7083841.3216085462635075106598273021503
PRGL_1-4Bulk81.68137.660.7082339.422781049403471911277110374934852
PRGL_1-4Bulk85.53140.440.7081042.4192285409529529101580252823028
PRGL_1-4Bulk88.49142.590.7080935.324471098259326932196158555737810
PRGL_1-4Bulk91.13144.500.7081135.828131226483384683298206512039827
PRGL_1-4Bulk93.25146.050.7082336.827591059182439781686128378331137
PRGL_1-4Bulk95.12147.030.7082433.231861226532516572523155585244310
PRGL_1-4Bulk100.30149.210.7082631.627281071100479094488206606052921
PRGL_1-4Bulk104.88151.490.7082532.92806993573432792290181514038386
PRGL_1-4Bulk105.21151.960.7082431.029151086069488383037194534439857
PRGL_1-4Bulk110.05158.810.7083129.530211172656539292997218629549967
Dura nee river0.7078732.839614352983266163085
Drome river0.7074340.325510244665647142159
Aude river0.7080922.531339207527881882848253
Herault river0.7085512.0586360745341552640141
Fier river0.7076921.24442531471449104942129
Arve river0.7079722.480331060920781371258168
Aygues river0.7074127.4295207734111188232364
Ardeche river0.707652.06231315006823299269842366798417132
Gard river0.708412.617553328970178248987819389212168
Agly river0.707985.8114410528163255612331114451859
Pure calcite72.100.70921
Pure calcite88.500.70919