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Arévalo-Martínez, Damian L; Ma, Xiao; Sun, Mingshuang; Bange, Hermann Werner (2019): Nitrous Oxide Measurements SO243. PANGAEA,, Supplement to: Ji, Q; Altabet, Mark A; Bange, Hermann Werner; Graco, Michelle; Ma, Xiao; Arévalo-Martínez, Damian L; Grundle, Damian (2019): Investigating the effect of El Niño on nitrous oxide distribution in the eastern tropical South Pacific. Biogeosciences, 16(9), 2079-2093,

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The open ocean is a major source of nitrous oxide (N2O), an atmospheric trace gas attributable to global warming and ozone depletion. Intense sea-to-air N2O fluxes occur in major oceanic upwelling regions such as the eastern tropical South Pacific (ETSP). The ETSP is influenced by the El Niño–Southern Oscillation that leads to inter-annual variations in physical, chemical, and biological properties in the water column. In October 2015, a strong El Niño event was developing in the ETSP; we conduct field observations to investigate (1) the N2O production pathways and associated biogeochemical properties and (2) the effects of El Niño on water column N2O distributions and fluxes using data from previous non-El Niño years. Analysis of N2O natural abundance isotopomers suggested that nitrification and partial denitrification (nitrate and nitrite reduction to N2O) were occurring in the near-surface waters; indicating that both pathways contributed to N2O effluxes. Higher-than-normal sea surface temperatures were associated with a deepening of the oxycline and the oxygen minimum layer. Within the shelf region, surface N2O supersaturation was nearly an order of magnitude lower than that of non-El Niño years. Therefore, a significant reduction of N2O efflux (75 %–95 %) in the ETSP occurred during the 2015 El Niño. At both offshore and coastal stations, the N2O concentration profiles during El Niño showed moderate N2O concentration gradients, and the peak N2O concentrations occurred at deeper depths during El Niño years; this was likely the result of suppressed upwelling retaining N2O in subsurface waters. At multiple stations, water-column inventories of N2O within the top 1000 m were up to 160 % higher than those measured in non-El Niño years, indicating that subsurface N2O during El Niño could be a reservoir for intense N2O effluxes when normal upwelling is resumed after El Niño.
Median Latitude: -10.903094 * Median Longitude: -79.145850 * South-bound Latitude: -16.075000 * West-bound Longitude: -85.500000 * North-bound Latitude: 1.000000 * East-bound Longitude: -75.274000
Date/Time Start: 2015-10-07T00:47:11 * Date/Time End: 2015-10-20T01:05:30
Minimum DEPTH, water: 4.38 m * Maximum DEPTH, water: 1202.23 m
SO243_1-1 (CTD-001) * Latitude: -0.999830 * Longitude: -85.500320 * Date/Time: 2015-10-07T00:39:00 * Elevation: -2319.0 m * Campaign: SO243 (ASTRA-OMZ) * Basis: Sonne_2 * Method/Device: CTD/Rosette (CTD-RO)
SO243_1-3 (CTD-002) * Latitude: 1.000070 * Longitude: -85.500050 * Date/Time: 2015-10-07T02:51:00 * Elevation: -2534.0 m * Campaign: SO243 (ASTRA-OMZ) * Basis: Sonne_2 * Method/Device: CTD/Rosette (CTD-RO) * Comment: max depth/on ground
SO243_2-3 (CTD-003) * Latitude: -0.000050 * Longitude: -85.500020 * Date/Time: 2015-10-07T19:58:00 * Elevation: -3433.0 m * Campaign: SO243 (ASTRA-OMZ) * Basis: Sonne_2 * Method/Device: CTD/Rosette (CTD-RO) * Comment: max depth/on ground
-Bedford 258319: Use carefully, problems during headspace analysis.
- Bedford 258389: Use carefully, problems during headspace analysis.
- Bedford 258425: Potential contamination with lab air.
- Station 4 has no bedford numbers. Data was divided in 3 casts identified as 42, 43 and 44 (i.e. station+cast number).
- Station 18 data was divided in 3 casts identified as 181, 183 and 184 (i.e. station+cast number).
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventArévalo-Martínez, Damian L
2Station labelStationArévalo-Martínez, Damian L
3Cast numberCastArévalo-Martínez, Damian L
4Bottle numberBottleArévalo-Martínez, Damian L
5Sample code/labelSample labelArévalo-Martínez, Damian L
6DATE/TIMEDate/TimeArévalo-Martínez, Damian LGeocode
7LATITUDELatitudeArévalo-Martínez, Damian LGeocode
8LONGITUDELongitudeArévalo-Martínez, Damian LGeocode
9DEPTH, waterDepth watermArévalo-Martínez, Damian LGeocode
10Temperature, waterTemp°CArévalo-Martínez, Damian LCTD, SEA-BIRD SBE 911plus
11SalinitySalArévalo-Martínez, Damian LCTD, SEA-BIRD SBE 911plus
12OxygenO2µmol/kgArévalo-Martínez, Damian L
13FluorescenceFluorescencearbitrary unitsArévalo-Martínez, Damian L
14Density, potentialDens potkg/m3Arévalo-Martínez, Damian L
15Density, sigma, in situSigma in situkg/m3Arévalo-Martínez, Damian LCalculated
16Nitrous oxide, dissolvedN2Onmol/lArévalo-Martínez, Damian LGas chromatograph with an electron capture detector (GC-ECD)
17Nitrous oxide, standard deviationN2O std dev±Arévalo-Martínez, Damian LCalculatednmol/l
18Error, relativeError r%Arévalo-Martínez, Damian LCalculated
19Nitrous oxideN2Onmol/kgArévalo-Martínez, Damian LGas chromatograph with an electron capture detector (GC-ECD)
20Nitrous oxide, standard deviationN2O std dev±Arévalo-Martínez, Damian LCalculatednmol/kg
21Error, relativeError r%Arévalo-Martínez, Damian LCalculated
22FlagFlagArévalo-Martínez, Damian LCalculated
5423 data points

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