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Goursaud, Sentia; Masson-Delmotte, Valerie; Favier, Vincent; Preunkert, Suzanne; Legrand, Michel R; Minster, Bénédicte (2018): The TA192A water stable isotope and chemical firn core records , Adélie Land, Antarctica [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.896623, Supplement to: Goursaud, Sentia; Masson-Delmotte, Valerie; Favier, Vincent; Preunkert, Suzanne; Legrand, Michel; Minster, Bénédicte; Werner, Martin (2019): Challenges associated with the climatic interpretation of water stable isotope records from a highly resolved firn core from Adélie Land, coastal Antarctica. The Cryosphere, 13(4), 1297-1324, https://doi.org/10.5194/tc-13-1297-2019

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Abstract:
A new 21.3m firn core was drilled in 2015 at a coastal Antarctic high accumulation site in Adélie Land (66.78°S; 139.56°E, 602ma.s.l.). The core was dated by annual layers counting based on non-sea-salt sulfate and methanesulfonate summer peaks, refined by a comparison between the reconstructed surface mass balance (hereafter, SMB) and the closest available stake data. The mean reconstructed SMB of 75.2 ± 15.0cmw.e. y−1 is consistent with local stake data, and remarkably high for coastal East Antarctica. The resulting inter-annual and sub-annual variations in isotopic records (δ18O and deuterium excess, hereafter d-excess) are explored for 1998–2014 and are systematically compared with a couple of climatic time series: an updated database of Antarctic surface snow isotopic composition, SMB stake data, meteorological observations from Dumont d'Urville station, sea-ice concentration based on passive microwave satellite data, precipitation outputs of atmospheric reanalyses, climate and water stable isotope outputs from the atmospheric general circulation model ECHAM5-wiso, as well as air mass origins diagnosed using 5-days back-trajectories.
The mean isotopic values (−19.3 ± 3.1‰ for δ18O and 5.4 ± 2.2‰ for d-excess) are consistent with other coastal Antarctic values. No significant isotope-temperature relationship can be evidenced at any timescale, ruling out a simple interpretation of in terms of local temperature. An observed asymmetry in the δ18O seasonal cycle may be explained by the precipitation of air masses coming from Indian and Pacific/West Antarctic Ice Sheet sectors in autumn and winter times, recorded in the d-excess signal showing outstanding values in austral spring versus autumn. Significant positive trends are observed in the annual d-excess record and local sea-ice extent (135°E–145°E) over the period 1998–2014.
However, processes studies focusing on resulting isotopic compositions and particularly the d-excess-δ18O relationship, evidenced as a potential fingerprint of moisture origins, as well as the collection of more isotopic measurements in Adélie Land are needed for an accurate interpretation of our signals.
Related to:
Jourdain, Bruno; Legrand, Michel (2002): Year-round records of bulk and size-segregated aerosol composition and HCl and HNO₃ levels in the Dumont d'Urville (coastal Antarctica) atmosphere: Implications for sea-salt aerosol fractionation in the winter and summer. Journal of Geophysical Research, 107(D22), 4645, https://doi.org/10.1029/2002JD002471
Coverage:
Latitude: -66.780000 * Longitude: 139.560000
Minimum DEPTH, ice/snow: 0.0002 m * Maximum DEPTH, ice/snow: 0.1321 m
Event(s):
TA192A__Adelie_Land * Latitude: -66.780000 * Longitude: 139.560000 * Elevation: 602.0 m * Location: Antarctic * Method/Device: Core (CORE)
Comment:
The TA192A core is a 21.3 m firn core drilled in 2015 at a coastal Antarctic high accumulation site in Adélie Land (66.78 °S; 139.56 °E, 602 m a.s.l.). Chemical elements, i.e. sulfate and methane sulfonic acid , as well as water stable isotope (δ18O and deutérium excess) were analysed at a 4 cm snow equivalent resolution. Non-sea-salt summer and winter sulfate were computed based on Jourdain et Legrand (2002). Records are given in function of firn core depth (in cm w.e.), and time.
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
NumberNoGoursaud, SentiaNumber of sampling
DEPTH, ice/snowDepth ice/snowmGoursaud, SentiaGeocode – In meters water equivalent (w.e)
AgeAgea AD/CEGoursaud, Sentia
SodiumNamg/kgGoursaud, Sentia
Original valueOrig valGoursaud, SentiaMethane sulfonic acid (ppb)
Methane sulfonic acidMSAµg/kgGoursaud, Sentia
Sulfate[SO4]2-mg/kgGoursaud, SentiaNon-sea-salt summer sulfate
Sulfate[SO4]2-mg/kgGoursaud, SentiaNon-sea-salt winter sulfate
δ18Oδ18OGoursaud, Sentia
10 Deuterium excessd xsGoursaud, Sentia
Size:
4772 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


No
(Number of sampling)

Depth ice/snow [m]
(In meters water equivalent (w.e))

Age [a AD/CE]

Na [mg/kg]

Orig val
(Methane sulfonic acid (ppb))

MSA [µg/kg]

[SO4]2- [mg/kg]
(Non-sea-salt summer sulfate)

[SO4]2- [mg/kg]
(Non-sea-salt winter sulfate)

δ18O []
10 
d xs []
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5290.13121997.363636627.251.800.001806.0474.33-17.3111.17
5280.13091997.454545479.971.670.00167-28.5841.24-17.139.64
5270.13061997.545455395.771.240.00124-5.7928.88-17.387.80
5260.13031997.636364307.102.540.00254-7.7030.27-17.866.68
5250.13001997.727273325.764.570.00457-4.6333.27-18.156.32
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4660.11371999.74193559.122.070.002078.6014.59-19.283.85
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610.01242013.65217499.280.890.00089-0.6811.24-18.316.98
600.01212013.69565296.641.030.0010321.4433.03-18.666.76
590.01192013.73913044.260.170.0001731.5836.89-18.507.03
580.01172013.78260943.440.260.0002613.0118.22-16.628.34
570.01142013.82608751.090.040.000047.2513.38-14.347.89
560.01122013.86956533.640.130.0001312.9316.97-12.818.46
550.01102013.91304318.192.490.0024937.7339.91-13.708.39
540.01082013.95652213.7417.830.01783129.74131.39-16.068.95
530.01052014.00000012.659.430.00943125.20126.71-17.639.47
520.01032014.02272714.146.090.00609105.28106.98-17.799.80
510.01012014.04545510.039.170.0091753.5654.77-17.0210.76
500.00992014.0681829.784.780.0047850.8452.02-16.6110.20
490.00962014.0909098.835.350.0053546.1847.24-16.749.11
480.00942014.1136368.914.260.0042656.3657.43-16.848.45
470.00922014.1363649.235.010.0050158.2759.37-17.078.07
460.00902014.15909138.879.810.0098153.7558.42-17.546.47
450.00882014.18181810.918.570.0085763.1764.48-16.507.91
440.00862014.20454515.718.840.0088454.7956.68-16.827.49
430.00842014.22727315.949.850.0098556.2058.11-17.097.05
420.00822014.25000016.019.620.0096256.3258.24-17.517.27
410.00802014.27272716.686.700.0067052.8654.87-18.766.80
400.00782014.29545535.265.610.0056130.7134.94-21.016.27
390.00762014.31818223.687.730.0077330.8633.70-23.355.64
380.00742014.34090924.295.060.0050618.2321.15-24.604.03
370.00722014.36363621.314.490.0044919.7222.28-23.563.77
360.00692014.38636477.574.640.0046426.5135.82-19.665.51
350.00672014.409091176.755.090.0050920.4841.69-15.458.12
340.00652014.43181886.523.920.0039220.9031.28-14.304.65
330.00622014.45454584.553.000.0030019.0229.17-15.115.16
320.00602014.47727370.602.770.0027717.4525.93-16.425.67
310.00582014.50000039.351.070.0010713.4218.15-17.765.80
300.00562014.522727162.951.300.0013023.5543.10-17.946.96
290.00542014.545455783.194.020.0040276.22170.20-16.688.70
280.00522014.568182412.272.870.0028737.3886.85-16.549.47
270.00502014.590909314.281.480.0014812.4750.18
260.00482014.613636312.532.220.0022212.5450.05-18.607.63
250.00462014.636364302.371.640.0016416.0352.31-19.217.30
240.00432014.659091174.182.090.0020912.0932.99-20.056.52
230.00412014.681818180.602.110.00211-15.056.62-25.101.19
220.00392014.704545165.651.920.00192-7.1312.75
210.00372014.727273110.741.310.00131-2.7910.50-23.303.62
200.00352014.75000024.890.560.000568.0111.00
190.00342014.77272724.480.230.000238.4011.34-21.763.96
180.00322014.79545543.870.290.0002912.0017.27-22.993.56
170.00302014.81818257.330.480.0004815.5822.46-25.270.53
160.00292014.84090935.420.240.0002413.8818.13-26.59-0.63
150.00272014.86363645.870.280.0002814.3719.87-26.68-0.67
140.00252014.88636445.160.360.0003613.4218.84-26.29-0.30
130.00232014.90909147.160.990.0009915.9121.57-24.930.13
120.00222014.93181836.295.340.0053445.6149.96-22.371.84
110.00202014.95454515.9018.760.0187686.0387.94-20.090.74
100.00172014.97727361.5520.650.02065125.45132.84
90.00152015.00000077.8628.920.02892124.21133.55-17.073.98
80.00142015.12500064.9616.560.01656110.99118.79-16.743.90
70.00122015.25000053.9313.980.01398119.45125.92-16.702.28
60.00102015.37500036.4511.570.0115796.33100.71-15.812.04
50.00082015.50000020.4619.240.0192453.0755.53-14.591.85
40.00062015.62500019.6615.910.0159146.5148.87-13.880.98
30.00062015.75000019.6615.910.0159146.5148.87-13.500.98
20.00042015.87500018.6110.530.0105327.9230.15-13.480.85
10.00022016.00000018.658.820.0088229.4631.69-12.761.45