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Henkel, Susann; Kasten, Sabine; Hartmann, Jan; Silva Busso, A; Staubwasser, Michael (2018): Pore water geochemistry of sediment core Potter_Cove_STA13 [dataset]. Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research, Bremerhaven, PANGAEA, https://doi.org/10.1594/PANGAEA.890304, In supplement to: Henkel, S et al. (2018): Iron cycling and stable Fe isotope fractionation in Antarctic shelf sediments, King George Island. Geochimica et Cosmochimica Acta, https://doi.org/10.1016/j.gca.2018.06.042

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Further details:
Lohan, Maeve C; Aguilar-Islas, Ana M; Franks, Robert P; Bruland, Kenneth W (2005): Determination of iron and copper in seawater at pH 1.7 with a new commercially available chelating resin, NTA Superflow. Analytica Chimica Acta, 530(1), 121-129, https://doi.org/10.1016/j.aca.2004.09.005
Sarazin, Gérard; Michard, Gil; Prevot, François (1999): A rapid and accurate spectroscopic method for alkalinity measurements in sea water samples. Water Research, 33(1), 290-294, https://doi.org/10.1016/S0043-1354(98)00168-7
Schoenberg, Ronny; von Blanckenburg, Friedhelm (2005): An assessment of the accuracy of stable Fe isotope ratio measurements on samples with organic and inorganic matrices by high-resolution multicollector ICP-MS. International Journal of Mass Spectrometry, 242(2-3), 257-272, https://doi.org/10.1016/j.ijms.2004.11.025
Seeberg-Elverfeldt, Jens; Schlüter, Michael; Feseker, Tomas; Kölling, Martin (2005): Rhizon sampling of pore waters near the sediment/water interface of aquatic systems. Limnology and Oceanography: Methods, 3, 361-371, https://doi.org/10.4319/lom.2005.3.361
Stookey, Lawrence L (1970): Ferrozine - A new spectrophotometric reagent for iron. Analytical Chemistry, 42, 779-781, https://doi.org/10.1021/ac60289a016
Funding:
German Research Foundation (DFG), grant/award no. 5472008: Priority Programme 1158 Antarctic Research with Comparable Investigations in Arctic Sea Ice Areas
Coverage:
Latitude: -62.225290 * Longitude: -58.640380
Date/Time Start: 2013-02-19T00:00:00 * Date/Time End: 2013-02-19T00:00:00
Minimum DEPTH, sediment/rock: -0.01 m * Maximum DEPTH, sediment/rock: 0.40 m
Event(s):
Potter_Cove_STA13 * Latitude: -62.225290 * Longitude: -58.640380 * Date/Time: 2013-02-19T00:00:00 * Elevation: -18.0 m * Location: Potter Cove, King George Island, Antarctic Peninsula * Method/Device: Gravity corer, UWITEC (GCUWI) * Comment: Elevation error ±1.5 m (tidal range)
Comment:
Methods:
Sampling:
• Rhizon technique (Seeberg-Elverfeldt et al. 2005)
SO42-:
• Ion chromatography (Metrohm IC Net 2.3)
Fe2+:
• Ferrozine method (Stookey 1970)
NH4+:
• spectrophotometrically using a Multiskan microplate reader
Alkalinity:
• Spectrophotometrically after Sarazin et al. (1999) using a Multiskan microplate reader
δ56Fe(pw):
• Removal of salt matrix by column chromatography (NTA Superflow columns, Qiagen) (Lohan et al. 2005)
• Column separation using the Dowex 1X8 resin
• Isotope analysis on a ThermoFinnigan Neptune Multicollector-ICP-MS (ESI Apex-Q desolvator, standard-sample bracketing method with IRMM-014) (Schoenberg and von Blanckenburg 2005)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
CoreCoreHenkel, Susann
DEPTH, sediment/rockDepth sedmHenkel, SusannGeocode
Sulfate[SO4]2-mmol/lHenkel, SusannIon chromatography (Metrohm IC Net 2.3)
Iron 2+Fe2+µmol/lHenkel, SusannIron, colorimetric, Ferrozine (Stookey, 1970)
Alkalinity, totalATmmol(eq)/lHenkel, SusannSpectrophotometry (Sarazin et al., 1999), Multiskan microplate reader
Ammonium[NH4]+µmol/lHenkel, SusannSpectrophotometry (Sarazin et al., 1999), Multiskan microplate reader
CommentCommentHenkel, Susann
Size:
106 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Core

Depth sed [m]

[SO4]2- [mmol/l]

Fe2+ [µmol/l]

AT [mmol(eq)/l]

[NH4]+ [µmol/l]

Comment
B-0.0125.321.12.3210.9bottom water
B0.0124.54157.33.5595.3
B0.0225.08114.03.63122.8
B0.0324.2099.04.2388.0
B0.0423.6180.66.42177.9
B0.0522.8959.17.30192.0
B0.0622.4643.47.82190.4
B0.0721.61102.38.30205.9
B0.0821.0044.98.82206.5
B0.0920.3756.38.86208.6
B0.1019.5665.19.08232.2
B0.1318.9467.19.39235.1
B0.1617.8594.09.51225.0
B0.1916.7868.29.48232.4
B0.2215.9544.19.14222.1
B0.2514.7838.69.27217.7
B0.2814.4539.29.13220.5
B0.3114.0741.48.64210.4
B0.3413.5553.68.30218.8
B0.3712.9378.37.47200.9
B0.4012.2576.67.20217.9