Murray, Natalie A; Muratli, Jesse M; Hartwell, Anne M; Manners, Hayley R; Megowan, Meghan; Goñi, Nicolas; Palmer, Martin R; McManus, James (2016): Geochemistry of solid and dissolved phases of IODP EXP340 holes [dataset publication series]. PANGAEA, https://doi.org/10.1594/PANGAEA.882320,

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Supplement to: Murray, NA et al. (2016): Data report: dissolved minor element compositions, sediment major and minor element concentrations, and reactive iron and manganese data from the Lesser Antilles volcanic arc region, IODP Expedition 340 Sites U1394, U1395, U1396, U1399, and U1400. In: Le Friant, A; Ishizuka, O; Stroncik, N.A and the Expedition 340 Scientists (eds.) Proceedings of the IODP, Integrated Ocean Drilling Program (Integrated Ocean Drilling Program Management International, Inc.), 340, https://doi.org/10.2204/iodp.proc.340.207.2016

We measured dithionite-extractable iron and manganese along with a variety of bulk sedimentary solid and dissolved phases to constrain diagenetic reactions occurring within the sediment package of Grenada Basin, which is within the Lesser Antilles volcanic arc region. Core material was obtained during Integrated Ocean Drilling Program Expedition 340. For this report we focus primarily on five sites; three sites are located in the northern portion of the study area off the island of Montserrat (Sites U1394-U1396), and two sites are located farther south off the island of Martinique (Sites U1399 and U1400). Sediments throughout this region include tephra-rich volcanic sands, hemipelagic mud sequences, and carbonate-rich sequences, with widely variable proportions over short (centimeter scale) depth intervals. Regardless of the main sediment type, organic carbon contents are low with average values of 0.19 ± 0.1 wt% at Site U1394, 0.13 ± 0.08 wt% at Site U1395, 0.13 ± 0.06 wt% at Site U1396, 0.28 ± 0.08 wt% at Site U1399, and 0.23 ± 0.15 wt% at Site U1400. Carbonate contents are more variable, ranging between 0 and ~80 wt%, in cores from Sites U1394-U1396 and between 1 and 40 wt% at both Sites U1399 and U1400. These variations in carbonate content likely reflect variable dilution with volcanogenic sediment. Pore fluids reflect a range of diagenetic conditions from oxidizing (sulfate rich) to sulfate-reducing conditions. Reactive major elements (Ca and Mg) as well as a number of minor elements show a range of diagenetic behaviors from reactions likely related to carbonate dissolution or precipitation to exchange reactions between pore fluids and the volcanic-rich sedimentary substrate and clay formation. However, significant site-to-site variability is seen in the diagenetic behavior of these elements. Solid-phase reactive Fe ranges from 0.18 to 0.75 wt% at the northern sites and 0.4 to 1.5 wt% at the southern sites, whereas reactive Mn ranges from 0 to 0.1 wt% in the north and 0 to 0.3 wt% in the south.