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Mejía, Luz María; Mendez-Vicente, Ana; Abrevaya, Lorena; Lawrence, Kira T; Ladlow, Caroline; Bolton, Clara T; Cacho, Isabel; Stoll, Heather M (2017): epsilon-p and pCO2 estimations for ODP Hole 138-846B [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.881943, In supplement to: Mejía, LM et al. (2017): A diatom record of CO 2 decline since the late Miocene. Earth and Planetary Science Letters, 479, 18-33, https://doi.org/10.1016/j.epsl.2017.08.034

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Related to:
Herbert, Timothy D; Lawrence, Kira T; Tzanova, Alexandrina; Peterson, Laura C; Caballero-Gill, Rocio P; Kelly, Christopher S (2016): Late Miocene global cooling and the rise of modern ecosystems. Nature Geoscience, 9(11), 843-847, https://doi.org/10.1038/ngeo2813
Lawrence, Kira T; Liu, Zhonghui; Herbert, Timothy D (2006): Evolution of the Eastern Tropical Pacific Through Plio-Pleistocene Glaciation. Science, 312(5770), 79-83, https://doi.org/10.1126/science.1120395
Project(s):
Coverage:
Latitude: -3.094930 * Longitude: -90.817960
Date/Time Start: 1991-05-21T17:00:00 * Date/Time End: 1991-05-24T06:08:00
Minimum Elevation: -3295.8 m * Maximum Elevation: -3295.8 m
Event(s):
138-846B * Latitude: -3.094930 * Longitude: -90.817960 * Date/Time Start: 1991-05-21T17:00:00 * Date/Time End: 1991-05-24T06:08:00 * Elevation: -3295.8 m * Penetration: 422.4 m * Recovery: 373.44 m * Location: South Pacific Ocean * Campaign: Leg138 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 45 cores; 422.4 m cored; 0 m drilled; 88.4 % recovery
Comment:
In the publication Mejía et al. (2017), for the calculation of diatom epsilon-p and pCO2 at 0.82 and 3.99 Ma we used the Uk'37 SST from the study of Lawrence et al. (2006), which used the Prahl et al. (1988) calibration. For the rest of the record, epsilon p and pCO2 data were calculated using the Uk'37 SST record calibrated using Müller et al. (1998) from the study of Herbert et al. (2016) and adapted to our age model (Shackleton et al., 1995).
For all samples, including those at 0.82 and 3.99 Ma, the epsilon p and pCO2 data shown here are calculated using the Uk'37 SST calibration of Müller et al. (1998) from the study of Herbert et al. (2016), adapted to our age model (Shackleton et al., 1995). Changing the calibration used for the first two samples from Prahl et al. (1988) to Müller et al. (1998) (SST values taken from Herbert et al., (2016)), results in pCO2 estimates of up to 5.1 ppm higher than that reported in Mejía et al. (2017).
The use of the Müller et al. (1998) calibration for the Uk'37 SST of the youngest sample would entail insignificant changes in the b* required to obtain a pCO2 of 229 ppmv (from 97, pCO2 of 233 ppmv to 95.5, pCO2 of 229 ppmv). This is not propagated through the remaining calculations because the reproducibility of the ice core pCO2 records is within this range of pCO2 variation (±3 ppmv).
Data of the post 5 Ma alkenone concentrations were taken from the study of Lawrence et al. (2006). Data of Pre 5 Ma alkenone concentrations shown here are adapted to the age model of our diatom samples (Shackleton et al., 1995). The full record can be found in spreadsheet "Pre 5Ma alkenone and SST record".
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
AGEAgeka BPMejía, Luz MaríaGeocode
Diatoms, pennales purityPennales purity%Mejía, Luz María
Diatoms, biomass as carbonDiatom C%Mejía, Luz Maríapennales
δ13C, diatom-bound organic matterδ13C DB‰ PDBMejía, Luz Maríapennales
Isotopic fractionation, during photosynthisεpMejía, Luz María
Neogloboquadrina sp., δ13CNeogloboquadrina sp. δ13C‰ PDBMejía, Luz María
Neogloboquadrina sp., δ18ONeogloboquadrina sp. δ18O‰ PDBMejía, Luz María
Globigerinoides sacculifer, δ13CG. sacculifer δ13C‰ PDBMejía, Luz María
Globigerinoides sacculifer, δ18OG. sacculifer δ18O‰ PDBMejía, Luz María
10 Coccoliths, Sr/Ca ratioCocco Sr/Cammol/molMejía, Luz María
11 AlkenoneAlkenonenmol/gMejía, Luz María
12 Sea surface temperature, annual meanSST (1-12)°CMejía, Luz MaríaCalculated from UK'37 (Müller et al, 1998)Herbert et al. (2016)
13 CoefficientCoeffMejía, Luz Maríab* constant
14 CoefficientCoeffMejía, Luz Maríab* opal content
15 CoefficientCoeffMejía, Luz Maríab* Alkenone concentration
16 CoefficientCoeffMejía, Luz Maríab* Sr/Ca cocco
17 Carbon dioxide, partial pressurepCO2ppmvMejía, Luz Maríab* constant; diffusive model
18 Carbon dioxide, partial pressurepCO2ppmvMejía, Luz Maríab* opal content; diffusive model
19 Carbon dioxide, partial pressurepCO2ppmvMejía, Luz Maríab* alkenone concentration; diffusive model
20 Carbon dioxide, partial pressurepCO2ppmvMejía, Luz Maríab* Sr/Ca cocco; diffusive model
21 Carbon dioxide, partial pressurepCO2ppmvMejía, Luz Maríaµ = 1.7 d-1; HCO3- uptake
22 Carbon dioxide, partial pressurepCO2ppmvMejía, Luz Maríaµ = 1 d-1; HCO3- uptake
23 Carbon dioxide, partial pressurepCO2ppmvMejía, Luz Maríaµ = 0.5 d-1; HCO3- uptake
24 Carbon dioxide, partial pressurepCO2ppmvMejía, Luz Maríaµ = 0.5-0.85 d-1; HCO3- uptake
25 CommentCommentMejía, Luz María
Size:
159 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Age [ka BP]

Pennales purity [%]

Diatom C [%]
(pennales)

δ13C DB [‰ PDB]
(pennales)

εp []

Neogloboquadrina sp. δ13C [‰ PDB]

Neogloboquadrina sp. δ18O [‰ PDB]

G. sacculifer δ13C [‰ PDB]

G. sacculifer δ18O [‰ PDB]
10 
Cocco Sr/Ca [mmol/mol]
11 
Alkenone [nmol/g]
12 
SST (1-12) [°C]
(Herbert et al. (2016))
13 
Coeff
(b* constant)
14 
Coeff
(b* opal content)
15 
Coeff
(b* Alkenone concentration)
16 
Coeff
(b* Sr/Ca cocco)
17 
pCO2 [ppmv]
(b* constant; diffusive model)
18 
pCO2 [ppmv]
(b* opal content; diffusive model)
19 
pCO2 [ppmv]
(b* alkenone concentration; di...)
20 
pCO2 [ppmv]
(b* Sr/Ca cocco; diffusive model)
21 
pCO2 [ppmv]
(µ = 1.7 d-1; HCO3- uptake)
22 
pCO2 [ppmv]
(µ = 1 d-1; HCO3- uptake)
23 
pCO2 [ppmv]
(µ = 0.5 d-1; HCO3- uptake)
24 
pCO2 [ppmv]
(µ = 0.5-0.85 d-1; HCO3- uptake)
25 
Comment
820650.06-20.4911.191.131.192.386.1122.6297979797233232233233229229229229
3990930.08-20.0210.410.470.231.25-0.552.214.5626.02971038385241255207210192198216210
5810850.04-21.5811.740.12-0.781.19-1.432.324.6526.5797888492268244233255312303279257
7660810.05-22.5714.031.18-1.101.88-1.492.399.1228.339711112398339388430342689564424547
8860530.10-24.4915.460.591.59-1.592.728.6428.69971071191223934354824931081807512733corrected d13C for pennate impurites, d13C Neogloboquadrina denote calculated values using measured d13C values from Globigerinoides sacculifer and assuming a similar foraminifer gradient compared to adjacent samples
10850810.08-23.9215.491.20-1.372.32-1.772.708.2128.73971141151203944644694891082807513775
12890330.04-19.9111.761.612.61-1.932.541.1128.74976653109283192155317270131299211corrected d13C for pennate impurites, d13C Neogloboquadrina denote calculated values using measured d13C values from Globigerinoides sacculifer and assuming a similar foraminifer gradient compared to adjacent samples