Citation:

j.envres.2015.05.018

Name: Brominated flame retardants and dechloranes in North Sea sediments in 2012/2013
Published: 2015
License: https://creativecommons.org/licenses/by/3.0/

Always quote citation above when using data! You can download the citation in several formats below.

RIS Citation BibTeX Citation Text Citation Facebook TwitterShow Map Google Earth

Abstract:

53 brominated and chlorinated flame retardants were investigated in sediment samples from the German rivers Elbe and Weser, the German Bight, Jadebusen, East Frisian Coast as well as the UK East coast. The aim of the presented study was to investigate the prevalence of different halogenated flame retardant groups as contaminants in North Sea sediments, identify determining factors for the distribution and levels as well as to identify area specific fingerprints that could help identify sources.

In order to do that a fast and effective ASE extraction method with an on-line clean-up was developed as well as a GC-EI-MSMS and LC-ESI-MSMS method to analyse PBDEs, MeOBDEs, alternate BFRs, Dechloranes as well as TBBPA and HBCDD. A fingerprinting method was adopted to identify representative area-specific patterns based on detection frequency as well as concentrations of individual compounds. Concentrations in general were low, with<1 ng/g dw for most compounds. Exceptions were the comparably high concentrations of BDE-209 with up to 7 ng/g dw in selected samples and TBBPA in UK samples with 2.7±1.5 ng/g dw. Apart from BDE-209 and TBBPA, alternate BFRs and Dechloranes were predominant in all analysed samples, displaying the increasing relevance of these compounds as environmental contaminants.

Project(s):

Helmholtz-Zentrum Geesthacht, Institute of Coastal Research (HZG)

Coverage:

Median Latitude: 53.600650 * Median Longitude: 6.272355 * South-bound Latitude: 50.858460 * West-bound Longitude: -0.601705 * North-bound Latitude: 55.288510 * East-bound Longitude: 9.940000

Date/Time Start: 2012-08-06T00:00:00 * Date/Time End: 2013-07-01T00:00:00

Minimum DEPTH, sediment/rock: 0 m * Maximum DEPTH, sediment/rock: 0 m

Event(s):

CEnd06/13_N1 * Latitude: 55.288510 * Longitude: -0.601705 * Date/Time: 2013-06-29T00:00:00 * Elevation: -82.0 m * Location: Northern United King Coast * Campaign: (CSEMP) * Basis: Cefas Endeavour * Method/Device: Grab (GRAB)

CEnd06/13_N2 * Latitude: 55.117480 * Longitude: 0.513960 * Date/Time: 2013-06-29T00:00:00 * Elevation: -83.0 m * Location: Northern United King Coast * Campaign: (CSEMP) * Basis: Cefas Endeavour * Method/Device: Grab (GRAB)

CEnd06/13_N3 * Latitude: 53.333350 * Longitude: 0.583342 * Date/Time: 2013-06-22T00:00:00 * Elevation: -28.0 m * Location: Northern United King Coast * Campaign: (CSEMP) * Basis: Cefas Endeavour * Method/Device: Grab (GRAB)

Comment:

Gas chromatography - Mass spectrometry (GC-MS): ASE_cleanup_GC-NCI-MS, GC-EI-MS/MS, validated analytical method, use of internal mass-labelled standards (isotope dilution method), blank controls; LODs and LOQs are averaged over the individual analytical batches. As the fingerprint approach was used for data evaluation, results between LOD and LOQ are given as the calculated values.

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Method/Device	Comment
1	Event label	Event		Sühring, Roxana
2	Station label	Station		Sühring, Roxana
3	Campaign of event	Campaign		Sühring, Roxana
4	Latitude of event	Latitude		Sühring, Roxana
5	Longitude of event	Longitude		Sühring, Roxana
6	Elevation of event	Elevation	m	Sühring, Roxana
7	Date/Time of event	Date/Time		Sühring, Roxana
8	DEPTH, sediment/rock	Depth sed	m	Sühring, Roxana		Geocode
9	2,2',4,4'-tetrabromodiphenyl ether	BDE47	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 15 pg/g, limit of quantification: 50 pg/g
10	2,2',3,4,4'-pentabromodiphenyl ether	BDE85	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight
11	2,2',4,4',5-pentabromodiphenyl ether	BDE99	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 29 pg/g, limit of quantification: 56 pg/g
12	2,2',4,4',6-pentabromodiphenyl ether	BDE100	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 124 pg/g, limit of quantification: 413 pg/g
13	2,2',4,4',5,6'-hexabromodiphenyl ether	BDE154	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 3 pg/g, limit of quantification: 9 pg/g
14	Decabromodiphenyl ether	BDE209	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 5028 pg/g, limit of quantification: 6134 pg/g
15	Tetrabromophtalic anhydride	TBP-AE	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 59 pg/g, limit of quantification: 196 pg/g
16	2-bromoallyl 2,4,6-tribromophenyl ether	BATE	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 44 pg/g, limit of quantification: 133 pg/g
17	2,3-dibromopropyl-2,4,6-tribromophenyl ether	TBP-DBPE	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 69 pg/g, limit of quantification: 217 pg/g
18	2-ethyl-1-hexyl 2,3,4,5-tetrabromobenzoate	EH-TBB	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 11 pg/g, limit of quantification: 35 pg/g
19	Hexabromobenzene	HBB	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 6 pg/g, limit of quantification: 19 pg/g
20	Pentabromoethylbenzene	PBEB	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 1 pg/g, limit of quantification: 3 pg/g
21	2,4,6-Tribromoanisole	TBA	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 7.8 pg/g, limit of quantification: 26 pg/g
22	Dibromoaldrin	DBALD	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 20 pg/g, limit of quantification: 56 pg/g
23	Dechlorane 602	DDC-DBF	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 6.3 pg/g, limit of quantification: 21 pg/g
24	anti-Dechlorane Plus	antiDP	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 30 pg/g, limit of quantification: 33 pg/g
25	syn-Dechlorane Plus	synDP	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 20 pg/g, limit of quantification: 25 pg/g
26	1,2,3,4,7,7-Hexachloro-5-phenyl-2-norbornene	HCPN	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 250 pg/g, limit of quantification: 700 pg/g
27	Tetrabromobisphenol A	TBBPA	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 83 pg/g, limit of quantification: 185 pg/g
28	alpha-hexabromocyclododecane	a-HBCDD	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 57 pg/g, limit of quantification: 171 pg/g
29	beta-hexabromocyclododecane	b-HBCDD	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 29 pg/g, limit of quantification: 77 pg/g
30	Gamma-hexabromocyclododecane	Gamma-HBCDD	pg/g	Sühring, Roxana	Gas chromatography - Mass spectrometry (GC-MS)	in total sediment, per dry weight, limit of detection: 70 pg/g, limit of quantification: 175 pg/g
31	Carbon, organic, total	TOC	%	Sühring, Roxana	Temperature-dependent differentiation of total carbon (DIN19539)	in total sediment
32	Water content, wet mass	Water wm	%	Sühring, Roxana	Difference weighting of wet and dry sediment mass	in total sediment

License:

Creative Commons Attribution 3.0 Unported (CC-BY-3.0)

Size:

1650 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 Event	2 Station	3 Campaign	4 Latitude	5 Longitude	6 Elevation [m]	7 Date/Time	9 BDE47 [pg/g]	10 BDE85 [pg/g]	11 BDE99 [pg/g]	12 BDE100 [pg/g]	13 BDE154 [pg/g]	14 BDE209 [pg/g]	15 TBP-AE [pg/g]	16 BATE [pg/g]	17 TBP-DBPE [pg/g]	18 EH-TBB [pg/g]	19 HBB [pg/g]	20 PBEB [pg/g]	21 TBA [pg/g]	22 DBALD [pg/g]	23 DDC-DBF [pg/g]	24 antiDP [pg/g]	25 synDP [pg/g]	26 HCPN [pg/g]	27 TBBPA [pg/g]	28 a-HBCDD [pg/g]	29 b-HBCDD [pg/g]	30 Gamma-HBCDD [pg/g]	31 TOC [%]	32 Water wm [%]
CEnd06/13_N1	Northern UK Coast 1	CEnd06/13	55.2885	-0.6017	-82	2013-06-29	0	0	0	0	183	0	0	0	99	0	0	260	0	0	0	0	165	0	2573	0	0	0	0.17	24
CEnd06/13_N2	Northern UK Coast 2	CEnd06/13	55.1175	0.5140	-83	2013-06-29	0	0	0	0	0	0	0	0	0	0	0	222	0	159	0	0	130	0	2238	0	0	0	0.17	24
CEnd06/13_N3	Northern UK Coast 3	CEnd06/13	53.3334	0.5833	-28	2013-06-22	290	0	300	500	141	0	0	0	0	0	0	56	0	489	0	611	109	0	1774	112	0	202	0.89	37
CEnd06/13_N4	Northern UK Coast 4	CEnd06/13	54.8744	0.6205	-88	2013-06-23	184	0	326	0	0	0	0	0	131	0	0	159	0	0	0	74	16	7901	5006	184	0	0	0.57	34
CEnd06/13_N5	Northern UK Coast 5	CEnd06/13	50.8622	0.8533	-28	2013-06-23	0	0	63	0	74	0	0	0	25	0	0	68	0	46	0	65	81	610	6324	77	0	0	0.38	34
CEnd06/13_N6	Northern UK Coast 6	CEnd06/13	50.9740	1.0262	-17	2013-06-21	177	0	158	771	0	0	0	0	123	1049	0	0	0	81	0	258	211	1272	2200	0	0	0	0.16	21
CEnd06/13_N7	Northern UK Coast 7	CEnd06/13	52.1929	1.7179	-31	2013-06-23	0	0	69	0	0	0	0	0	56	0	0	0	0	0	0	92	96	1940	2530	0	0	0	0.33	30
CEnd06/13_N8	Northern UK Coast 8	CEnd06/13	52.6845	2.3082	-50	2013-06-23	0	0	0	0	0	0	0	0	0	0	0	354	0	0	0	190	235	0	0	0	0	0	0.30	23
CEnd06/13_N9	Northern UK Coast 9	CEnd06/13	54.0980	2.4309	-75	2013-06-24	0	0	0	1093	315	0	0	0	0	1074	0	258	0	0	0	219	295	0	2247	0	0	0	0.18	23
CEnd06/13_N10	Northern UK Coast 10	CEnd06/13	54.1322	2.4482	-66	2013-06-26	206	0	100	1004	228	0	0	0	0	1182	0	0	0	0	0	79	117	0	0	1438	86	228	0.23	24
CEnd06/13_N11	Northern UK Coast 11	CEnd06/13	50.8585	0.8500	-28	2013-06-24	50	0	92	0	0	0	0	0	61	0	0	227	0	0	0	210	226	1063	2712	0	0	0	0.29	25
CEnd06/13_N12	Northern UK Coast 12	CEnd06/13	50.9700	1.0371	-25	2013-06-28	0	0	0	0	0	4253	0	0	0	508	0	58	0	0	0	52	36	0	648	56	0	0	0.77	47
CEnd06/13_N13	Northern UK Coast 13	CEnd06/13	52.1945	1.6813	-23	2013-06-30	0	0	0	76	73	0	0	0	5	0	0	73	0	23	0	120	114	0	521	0	0	0	0.48	40
CEnd06/13_N14	Northern UK Coast 14	CEnd06/13	52.1898	1.6929	-23	2013-06-27	139	0	153	520	128	0	0	0	0	0	0	130	0	0	0	162	135	0	1141	72	0	0	0.58	36
CEnd06/13_N15	Northern UK Coast 15	CEnd06/13	52.2237	1.7216	-28	2013-06-27	0	0	0	654	195	0	0	0	82	0	0	87	0	0	0	103	127	0	1484	0	0	0	0.27	24
CEnd06/13_N16	Northern UK Coast 16	CEnd06/13	52.7341	2.3352	-23	2013-06-21	0	0	0	0	0	0	0	0	132	0	0	311	0	0	0	0	14	0	4170	92	0	0	0.31	29
CEnd06/13_N17	Northern UK Coast 17	CEnd06/13	53.2200	8.4800		2013-06-20	0	0	96	0	0	0	0	0	0	1348	0	86	0	50	0	167	82	0	3083	0	0	0	0.28	27
CEnd06/13_S1	Southern UK Coast 1	CEnd06/13	53.1700	8.6000		2013-06-28	0	0	0	0	0	3989	0	0	0	1308	0	143	0	0	0	66	112	0	391	102	0	0	0.56	38
CEnd06/13_S2	Southern UK Coast 2	CEnd06/13	53.5200	8.1700		2013-06-28	0	0	77	0	0	0	0	0	44	701	0	0	0	0	0	0	0	1343	1178	467	0	431	0.30	28
CEnd06/13_S3	Southern UK Coast 3	CEnd06/13	53.5200	8.1900		2013-06-27	103	0	97	1315	321	0	0	0	0	0	0	162	0	110	0	121	154	0	0	0	0	0	0.46	38
CEnd06/13_S4	Southern UK Coast 4	CEnd06/13	53.5600	9.7000		2013-07-01	0	0	0	0	0	7211	0	0	0	0	0	0	0	80	0	0	0	0	1413	1474	0	208	0.41	40
CEnd06/13_S5	Southern UK Coast 5	CEnd06/13	53.5800	9.6000		2013-06-27	0	0	0	0	0	0	0	0	0	970	0	194	0	0	0	89	135	0	296	0	0	0	0.08	18
CEnd06/13_S6	Southern UK Coast 6	CEnd06/13	53.7195	7.9234		2013-06-27	0	0	0	0	0	0	0	0	0	0	0	532	0	0	144	241	918	0	0	0	0	0	0.05	15
East-Frisian_1	East Frisian 1	NLWKN	53.4280	7.1835		2012-08-13	0	0	8	0	0	0	0	0	20	0	0	0	18	11	137	20	13	254	44	44	16	398	0.35	33
East-Frisian_2	East Frisian 2	NLWKN	53.6088	8.2725		2012-08-13	0	0	0	0	0	0	0	0	50	0	0	48	0	0	40	59	12	376	0	33	0	177	0.46	38
East-Frisian_3	East Frisian 3	NLWKN	53.6956	7.2393		2012-08-06	2	0	4	3	0	0	0	0	1	0	6	0	26	2	32	20	17	0	0	0	0	99	0.23	28
East-Frisian_4	East Frisian 4	NLWKN	53.5965	6.7731		2012-09-12	0	0	0	3	0	0	0	0	0	0	0	0	9	0	43	22	22	403	0	30	0	129	0.35	30
East-Frisian_5	East Frisian 5	NLWKN	53.5563	7.1007		2012-08-08	7	0	26	0	0	0	0	49	20	0	7	0	6	0	30	19	14	428	13	0	0	25	0.27	31
East-Frisian_6	East Frisian 6	NLWKN	53.7665	8.5275		2012-08-15	0	25	0	0	0	0	0	0	0	0	0	0	22	28	49	13	11	0	0	0	0	99	0.45	41
LP20130527_Stat_20	Jade/Weser 1	LP20130527	53.7024	7.7127		2013-05-29	370	0	462	77	0	2427	0	0	167	0	6	0	30	209	143	240	72	0	281	1799	321	2109	4.87	61
LP20130527_Stat_21	Jade/Weser 2	LP20130527	53.6956	7.2393		2013-05-29	2	0	28	7	0	0	0	27	136	0	10	0	5	47	198	49	21	174	0	49	0	53	0.26	18
LP20130527_Stat_14	Jade/Weser 3	LP20130527	53.4300	8.4900		2013-05-29	0	0	0	0	0	0	0	0	37	0	6	0	0	0	279	20	20	0	198	0	0	0	0.26	18
Jade-Weser_4	Jade/Weser 4	NLWKN	53.5537	8.4884		2012-08-14	1	0	45	0	0	0	0	0	107	0	0	55	18	31	74	148	23	886	0	0	0	175	0.61	34
LP20130527_Stat_13	Jade/Weser 5	LP20130527	53.5300	8.5700		2013-05-29	0	0	0	0	0	0	0	0	45	0	10	0	0	0	38	34	31	607	0	0	0	29	0.13	20
LP20130527_Stat_12	Jade/Weser 6	LP20130527	53.6700	8.3700		2013-05-29	0	0	0	0	0	0	0	0	22	0	6	0	0	0	25	31	15	0	0	0	0	0	0.04	22
LP20130527_Stat_9	Jade/Weser 7	LP20130527	53.6800	8.0800		2013-05-28	0	0	6	0	0	0	0	0	0	0	0	0	0	0	8	1	2	176	0	0	0	0	0.11	18
LP20130527_Stat_18	Jade/Weser 8	LP20130527	53.5965	6.7731		2013-05-28	20	0	41	0	0	0	0	61	0	0	0	0	0	49	85	16	8	0	0	0	0	0	0.47	36
LP20130527_Stat_19	Jade/Weser 9	LP20130527	53.5563	7.1007		2013-05-28	0	0	13	0	0	0	0	0	0	0	0	0	0	93	124	7	3	0	142	119	51	222	0.46	34
LP20130527_Stat_10	Jade/Weser 10	LP20130527	53.4900	8.1900		2013-05-28	0	0	0	0	0	0	0	0	0	35	0	0	0	0	0	5	0	0	48	96	14	186	0.49	34
Jade-Weser_11	Jade/Weser 11	NLWKN	53.4280	7.1835		2012-08-14	0	0	15	0	0	0	138	0	75	0	0	0	359	0	96	12	9	0	34	0	0	117	0.65	37
Jade-Weser_12	Jade/Weser 12	NLWKN	53.6088	8.2725		2012-08-15	0	0	0	0	0	0	0	0	12	0	0	35	0	0	89	46	27	0	180	0	0	278	1.00	41
HE391/01-4	North Sea 1	HE391	53.8160	7.4932	-11	2012-10-30	0	0	0	0	0	0	0	0	0	31	2	0	0	0	4	0	2	0	0	0	0	0	0.01	10
HE391/03-4	North Sea 2	HE391	53.7103	6.6153	-14	2012-10-31	0	0	14	24	0	0	0	31	0	0	5	0	0	0	9	0	1	0	0	0	0	0	0.01	11
HE391/06-4	North Sea 3	HE391	54.2248	6.3572	-33	2012-10-31	0	0	0	0	0	0	0	0	0	0	0	0	0	0	10	6	2	0	0	0	0	0	0.05	17
HE391/12-4	North Sea 4	HE391	54.6802	8.1178	-11	2012-11-01	0	0	11	0	0	0	0	0	0	0	0	0	0	0	5	0	0	227	59	0	0	0	0.03	15
HE391/13-7	North Sea 5	HE391	54.2210	8.2513	-12	2012-11-02	0	14	0	0	0	0	0	0	0	0	0	0	0	0	10	7	4	0	146	0	0	0	0.08	15
HE391/15-3	North Sea 6	HE391	54.2223	7.5065	-36	2012-11-04	0	0	0	0	0	0	0	0	0	55	3	0	0	0	11	12	11	0	0	0	0	0	0.14	18
LP20120815_Stat_5	North Sea 7	LP20120815	54.7300	8.2970	-35	2012-08-17	0	0	0	0	6	5053	0	0	58	151	19	0	0	0	472	387	233	0	0	0	0	0	0.16	16
HE391/18-3	North Sea 8	HE391	54.6813	6.3618	-36	2012-11-04	0	0	0	0	0	0	0	0	0	0	4	0	0	78	0	7	6	0	0	0	0	0	0.10	15
HE391/20-4	North Sea 9	HE391	55.1723	5.0315	-38	2012-11-05	1	0	0	0	0	0	0	0	37	0	10	0	650	0	13	37	10	0	0	0	0	0	0.08	15
HE391/22-4	North Sea 10	HE391	55.0145	6.3337	-40	2012-11-05	0	0	17	0	0	0	0	0	29	0	0	14	11	0	70	30	19	0	0	0	0	0	0.24	38
LP20120815_Stat_1	North Sea 11	LP20120815	54.0670	8.5990	-12	2012-08-15	0	0	0	0	0	0	0	0	0	0	3	0	0	0	0	2	2	0	0	0	0	0	0.02	18
LP20120815_Stat_2	North Sea 12	LP20120815	54.1270	8.7180	-12	2012-08-15	0	0	0	0	0	0	0	0	0	0	0	0	0	0	12	11	6	0	0	0	0	0	0.16	18
HE395/06-13	North Sea 13	HE395/1	54.0633	8.0165	-24	2013-03-06	0	0	17	0	0	0	0	0	29	0	0	14	11	0	70	30	19	0	0	0	0	0	0.45	41
HE395/10-5	North Sea 14	HE395/1	54.0933	7.3618	-34	2013-03-06	0	0	0	0	0	5092	0	0	0	0	10	0	0	0	0	6	7	0	0	0	0	0	0.10	24
HE395/17-6	North Sea 15	HE395/1	54.4367	7.4200	-25	2013-03-11	0	8	0	0	0	0	0	0	0	0	2	0	0	0	0	3	4	0	0	0	0	0	0.04	19
HE395/23-7	North Sea 16	HE395/1	54.4680	6.1952	-37	2013-03-12	0	0	33	0	0	0	0	0	0	0	0	509	199	0	0	8	14	0	0	0	0	0	0.09	24
HE395/25-5	North Sea 17	HE395/1	53.9883	6.2327	-28	2013-03-12	0	0	0	0	0	0	0	0	0	0	0	0	0	0	3	1	0	0	0	0	0	0	0.02	15
HE395/30-2	North Sea 18	HE395/1	53.9508	6.8093	-24	2013-03-13	0	0	12	0	0	0	0	0	0	0	5	0	0	0	0	0	0	0	0	0	0	0	0.04	18
LP20120815_Stat_6	Elbe river 1	LP20120815	53.9700	8.6925		2012-08-16	0	0	0	0	0	0	0	0	50	0	11	0	0	0	38	34	29	0	0	0	0	107	0.66	48
LP20120815_Stat_3	Elbe river 2	LP20120815	53.9150	8.7460		2012-08-16	0	0	0	0	0	0	0	0	0	0	0	0	0	0	0	0	4	0	0	0	0	0	0.01	19
LP20120815_Stat_4	Elbe river 3	LP20120815	53.8700	9.0040		2012-08-16	0	0	0	0	0	0	0	0	0	0	6	0	0	0	11	7	4	0	0	0	0	0	0.02	19
LP20130527_Stat_5	Elbe river 4	LP20130527	53.7500	9.4100		2013-05-27	0	0	0	0	0	0	0	0	9	0	3	0	0	0	6	4	1	0	0	0	0	0	0.36	27
LP20130527_Stat_16	Elbe river 5	LP20130527	53.7665	8.5275		2013-05-27	33	0	44	0	0	0	0	0	0	23	3	0	0	199	0	14	11	0	0	0	0	0	1.01	36
LP20130527_Stat_17	Elbe river 6	LP20130527	53.5537	8.4884		2013-05-27	0	0	0	0	0	0	0	53	70	0	0	0	0	0	65	50	29	163	0	57	9	403	0.14	20
LP20130527_Stat_3	Elbe river 7	LP20130527	53.5400	9.9400		2013-05-27	0	0	0	0	0	0	0	0	18	92	33	0	0	0	14	9	6	0	0	0	0	34	0.10	22