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Wolschke, Hendrik; Sühring, Roxana; Mi, Wenying; Möller, Axel; Xie, Zhiyong; Ebinghaus, Ralf (2016): Organophosphorus flame retardants and plasticizer in air samples at the German coast in 2011/2012 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.876576, Supplement to: Wolschke, H et al. (2016): Atmospheric occurrence and fate of organophosphorus flame retardants and plasticizer at the German coast. Atmospheric Environment, 137, 1-5, https://doi.org/10.1016/j.atmosenv.2016.04.028

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Abstract:
This study reports the occurrence and distribution of organophosphor esters (OPEs), used as flame retardants and plasticizer, in the marine atmosphere of the German Coast. From August 2011 to October 2012, 58 high volume air samples (gas/particle phase separately) were collected at the German North Sea coast town Büsum. With the use of a GC-MS/MS System for instrumental analysis, detection limits for OPEs in air samples could be significantly improved compared to the previously used single GC-MS method. The concentration (gas + particle phase) of total OPEs was on average 5 pg/m3, with eight of the nine investigated compounds detectable in over 50% of the samples. A focus of this investigation concerned the partioning of OPEs between the particle and the gas phase. The observed partitioning of OPEs in this study was distinguished from previous studies. While previous studies reported OPEs exclusively in the particle phase, a significant part of the sum OPE concentration (55%) was detected in the gas phase. The contribution of the gas phase even reached up to as high as 88% for individual compounds such as tri-iso-butyl phosphate.
Project(s):
Helmholtz-Zentrum Geesthacht, Institute of Coastal Research (HZG)
Coverage:
Latitude: 54.130000 * Longitude: 8.880000
Date/Time Start: 2011-09-07T08:38:00 * Date/Time End: 2012-10-02T09:12:00
Minimum HEIGHT above ground: 1.5 m * Maximum HEIGHT above ground: 1.5 m
Event(s):
Buesum * Latitude: 54.130000 * Longitude: 8.880000 * Date/Time Start: 2011-09-07T08:38:00 * Date/Time End: 2012-10-10T12:45:00 * Location: Buesum, Germany * Method/Device: High volume air sampler (HVAIR)
Comment:
Solid-Phase extraction, measurement by GC-MSMS (Wolschke et al. 2016).
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1 HEIGHT above groundHeightmWolschke, HendrikGeocode
2 DATE/TIMEDate/TimeWolschke, HendrikGeocode
3 Date/time endDate/time endWolschke, Hendrik
4 Sample volumeSamp volm3Wolschke, Hendrik
5 Average temperatureT avg°CWolschke, Hendrik
6 Triisobutyl phosphateTiBPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)vapor phase
7 Tributyl phosphateTBPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)vapor phase
8 Tris(2-chloroethyl)phosphateTCEPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)vapor phase
9 Tris(1-chloro-2-propyl)phosphateTCPPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)vapor phase
10 Tris(1,3-dichloro-2-propyl)phosphateTDCPPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)vapor phase
11 Triphenyl phosphateTPhPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)vapor phase
12 Tris(2-butoxyethyl)phosphateTBEPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)vapor phase
13 Tris(2-ethylhexyl)phosphateTEHPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)vapor phase
14 Tricresyl phosphateTCPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)vapor phase
15 Triisobutyl phosphateTiBPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)particle phase
16 Tributyl phosphateTBPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)particle phase
17 Tris(2-chloroethyl)phosphateTCEPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)particle phase
18 Tris(1-chloro-2-propyl)phosphateTCPPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)particle phase
19 Tris(1,3-dichloro-2-propyl)phosphateTDCPPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)particle phase
20 Triphenyl phosphateTPhPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)particle phase
21 Tris(2-butoxyethyl)phosphateTBEPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)particle phase
22 Tris(2-ethylhexyl)phosphateTEHPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)particle phase
23 Tricresyl phosphateTCPpg/m3Wolschke, HendrikGas chromatography, coupled with tandem mass spectrometer (GC-MS/MS)particle phase
License:
Creative Commons Attribution 3.0 Unported (CC-BY-3.0)
Size:
1027 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 
Height [m]		2 
Date/Time		3 
Date/time end		4 
Samp vol [m3]		5 
T avg [°C]		6 
TiBP [pg/m3]
(vapor phase)		7 
TBP [pg/m3]
(vapor phase)		8 
TCEP [pg/m3]
(vapor phase)		9 
TCPP [pg/m3]
(vapor phase)		10 
TDCPP [pg/m3]
(vapor phase)		11 
TPhP [pg/m3]
(vapor phase)		12 
TBEP [pg/m3]
(vapor phase)		13 
TEHP [pg/m3]
(vapor phase)		14 
TCP [pg/m3]
(vapor phase)		15 
TiBP [pg/m3]
(particle phase)		16 
TBP [pg/m3]
(particle phase)		17 
TCEP [pg/m3]
(particle phase)		18 
TCPP [pg/m3]
(particle phase)		19 
TDCPP [pg/m3]
(particle phase)		20 
TPhP [pg/m3]
(particle phase)		21 
TBEP [pg/m3]
(particle phase)		22 
TEHP [pg/m3]
(particle phase)		23 
TCP [pg/m3]
(particle phase)
1.52011-09-07T08:382011-09-14T08:4011.35.44.513.40.91.60.00.71.20.00.00.00.00.00.00.00.60.0
1.52011-09-14T09:102011-09-21T09:00274013.96.12.31.84.20.10.40.00.30.03.63.00.04.30.41.20.07.61.4
1.52011-09-21T09:072011-09-28T10:12294814.410.45.54.48.90.41.90.00.70.30.00.30.01.01.71.61.96.23.4
1.52011-09-28T10:232011-10-05T09:27284616.221.813.011.939.11.54.60.00.90.70.00.30.02.71.92.14.723.29.6
1.52011-10-05T09:382011-10-12T10:30255912.14.51.81.64.10.30.50.00.20.01.30.62.63.00.20.20.01.60.0
1.52011-10-12T10:452011-10-19T10:2624959.011.83.21.74.50.31.80.01.21.20.00.00.00.00.21.10.012.23.2
1.52011-10-19T10:392011-10-26T11:0120387.99.13.11.22.90.21.10.01.50.51.10.80.02.01.47.73.112.08.6
1.52011-10-26T11:182011-11-01T09:20249110.223.311.23.313.90.42.00.00.80.00.40.62.31.62.14.29.147.412.7
1.52011-11-01T09:352011-11-09T12:2034079.617.18.82.512.20.42.00.01.50.41.40.30.01.41.55.55.331.710.8
1.52011-11-09T12:252011-11-16T09:1927203.34.94.11.210.10.41.00.00.00.00.50.83.46.21.410.24.014.316.3
1.52011-11-16T09:252011-11-22T10:0020343.431.374.02.618.91.03.10.00.70.02.24.10.03.72.18.58.031.918.8
1.52011-11-22T10:052011-11-30T09:0023496.415.618.13.412.22.26.33.93.03.53.11.90.01.60.32.60.011.44.4
1.52011-11-30T09:102011-12-06T09:2017556.29.18.73.46.61.02.42.31.81.70.00.50.01.50.00.00.02.30.0
1.52011-12-06T09:252011-12-13T10:5521364.34.72.03.42.60.40.50.00.40.00.00.40.00.00.01.20.01.81.6
1.52011-12-13T10:552011-12-20T10:3522704.37.53.73.43.80.91.42.02.90.80.70.01.21.30.00.60.01.40.2
1.52011-12-20T10:352012-01-03T08:3541985.74.04.73.45.50.30.70.00.30.61.00.50.00.80.00.70.00.80.7
1.52012-01-24T10:552012-01-31T09:502370-1.111.35.63.42.70.00.60.00.30.02.72.22.36.41.014.15.319.914.0
1.52012-01-31T09:502012-02-07T10:032715-7.54.60.53.40.20.00.20.00.00.04.45.92.25.50.67.63.311.39.7
1.52012-02-07T10:052012-02-14T09:552453-3.43.80.83.41.40.10.80.00.50.60.60.00.00.00.11.40.01.92.3
1.52012-02-14T10:002012-02-21T10:0021552.44.33.63.44.90.61.13.40.60.90.70.00.00.20.00.20.00.00.0
1.52012-02-21T10:102012-02-28T10:0022314.66.25.23.48.41.23.12.80.61.70.00.00.01.40.00.30.01.70.2
1.52012-02-28T10:052012-03-06T10:1022195.05.32.63.48.90.21.00.00.40.72.72.70.04.00.56.32.04.510.2
1.52012-03-14T09:002012-03-20T09:4028286.77.57.73.47.70.51.00.02.00.60.00.91.54.61.62.62.411.43.5
1.52012-03-20T09:402012-03-27T09:0028986.63.84.33.44.40.00.20.00.00.01.01.71.23.90.20.70.01.41.1
1.52012-04-04T09:002012-04-11T09:0022214.71.93.63.42.00.10.60.00.00.00.90.80.00.30.10.90.02.11.1
1.52012-04-11T09:002012-04-18T10:1027556.73.30.73.41.10.00.10.00.00.02.93.02.56.40.41.40.03.91.1
1.52012-04-18T10:102012-04-25T10:1827608.87.43.03.43.20.30.72.31.10.02.13.20.82.00.31.84.412.12.7
1.52012-04-25T10:302012-05-03T08:50292011.93.61.93.43.90.10.62.01.20.00.00.01.81.80.21.02.117.91.1
1.52012-05-03T09:002012-05-10T10:0023509.86.33.53.44.50.50.72.71.30.00.00.40.02.10.20.62.316.30.5
1.52012-05-10T10:102012-05-16T10:00212811.03.21.43.43.00.20.42.75.00.01.00.70.01.60.00.40.020.80.1
1.52012-05-16T10:052012-05-24T08:20304914.75.12.63.46.90.21.40.02.80.00.00.00.00.10.50.76.155.81.6
1.52012-05-24T08:382012-05-30T10:00227217.13.92.33.412.40.10.70.00.60.00.00.00.01.50.50.63.146.51.6
1.52012-06-06T10:052012-06-13T10:00213413.86.43.33.49.20.91.05.03.60.60.00.00.01.60.00.00.013.70.8
1.52012-06-13T10:052012-06-20T10:05272514.12.51.13.44.00.20.41.80.70.00.70.50.03.70.10.31.96.50.4
1.52012-06-20T10:102012-06-27T08:32256815.06.73.13.46.30.10.20.00.50.02.30.71.43.20.20.50.08.10.6
1.52012-06-27T08:552012-07-05T09:30281117.49.63.33.46.80.70.71.93.40.00.00.00.01.10.30.61.58.50.9
1.52012-07-05T09:402012-07-10T19:20223018.04.62.93.47.40.40.82.01.90.00.40.30.01.50.00.00.03.40.0
1.52012-07-10T19:302012-07-18T08:50290715.64.12.23.46.70.20.40.00.30.00.60.50.92.40.20.40.02.30.4
1.52012-07-18T09:002012-07-25T08:20263916.66.81.83.46.50.10.40.00.20.00.00.30.02.20.30.51.62.20.4
1.52012-07-25T08:302012-08-01T09:30288817.73.81.93.411.20.30.60.00.50.01.10.90.01.70.43.01.55.70.6
1.52012-08-01T09:302012-08-15T17:45497117.33.02.53.413.10.60.70.00.30.00.00.00.00.00.40.20.82.10.6
1.52012-08-15T18:002012-08-22T09:08263320.39.25.23.411.10.41.50.01.00.00.00.50.00.80.60.41.87.11.6
1.52012-08-22T09:102012-08-29T09:00274617.212.34.63.413.90.21.20.00.40.00.40.81.02.80.61.62.05.92.8
1.52012-08-29T09:002012-09-05T09:00298016.66.12.53.46.70.20.60.00.20.00.60.61.04.50.40.70.01.40.4
1.52012-09-05T09:002012-09-12T08:30298116.87.22.73.410.70.20.50.00.20.00.40.40.01.60.30.50.01.60.8
1.52012-09-12T08:302012-09-18T14:00260614.65.21.93.45.60.30.40.00.30.00.50.70.93.60.50.60.01.00.3
1.52012-09-18T14:202012-09-25T14:30260611.84.52.13.43.80.70.70.00.40.00.61.00.01.40.30.90.01.61.0
1.52012-09-25T14:402012-10-02T08:35262012.58.44.93.46.00.80.91.80.60.00.00.60.01.10.51.10.03.51.6
1.52012-10-02T09:122012-10-10T12:45319711.44.62.43.43.70.50.30.00.40.00.80.80.83.30.70.40.01.50.5