Hawkes, Jeffrey A; Rossel, Pamela E; Stubbins, Aron; Butterfield, David A; Connelly, Douglas P; Achterberg, Eric Pieter; Koschinsky, Andrea; Chavagnac, Valerie; Hansen, Christian T; Bach, Wolfgang; Dittmar, Thorsten (2015): Deep-Ocean dissolved organic matter in hydrothermal vents [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.867501, Supplement to: Hawkes, JA et al. (2015): Efficient removal of recalcitrant deep-ocean dissolved organic matter during hydrothermal circulation. Nature Geoscience, 8(11), 856-860, https://doi.org/10.1038/ngeo2543
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Published: 2015 (exact date unknown) • DOI registered: 2016-12-01
Abstract:
Oceanic dissolved organic carbon (DOC) is an important carbon pool, similar in magnitude to atmospheric CO2, but the fate of its oldest forms is not well understood (Dittmar and Stubbins, 2014; Hansell, 2013, doi:10.1146/annurev-marine-120710-100757). Hot hydrothermal circulation may facilitate the degradation of otherwise un-reactive dissolved organic matter, playing an important role in the long-term global carbon cycle. The oldest, most recalcitrant forms of DOC, which make up most of oceanic DOC, can be recovered by solid-phase extraction. Here we present measurements of solid-phase extractable DOC from samples collected between 2009 and 2013 at seven vent sites in the Atlantic, Pacific and Southern oceans, along with magnesium concentrations, a conservative tracer of water circulation through hydrothermal systems. We find that magnesium and solid-phase extractable DOC concentrations are correlated, suggesting that solid-phase extractable DOC is almost entirely lost from solution through mineralization or deposition during circulation through hydrothermal vents with fluid temperatures of 212-401 °C. In laboratory experiments, where we heated samples to 380 °C for four days, we found a similar removal efficiency. We conclude that thermal degradation alone can account for the loss of solid-phase extractable DOC in natural hydrothermal systems, and that its maximum lifetime is constrained by the timescale of hydrothermal cycling, at about 40 million years (Elderfield and Schultz, 1996, doi:10.1146/annurev.earth.24.1.191).
Related to:
Coverage:
Median Latitude: 10.880999 * Median Longitude: -75.845948 * South-bound Latitude: -56.088930 * West-bound Longitude: 130.763330 * North-bound Latitude: 48.000000 * East-bound Longitude: -30.188980
Date/Time Start: 2001-07-21T00:13:00 * Date/Time End: 2011-07-31T05:22:00
Minimum Elevation: -3034.0 m * Maximum Elevation: -800.0 m
Event(s):
AMK47-Lost_City * Latitude: 30.125000 * Longitude: -42.117000 * Elevation: -800.0 m * Location: Lost City Hydrothermal Field, Mid-Atlantic Ridge * Campaign: AMK47 * Basis: Akademik Mstislav Keldysh * Method/Device: MIR deep-sea manned submersible (MIR)
J2-574 * Latitude: 47.900000 * Longitude: -129.000000 * Date/Time: 2001-07-21T00:13:00 * Elevation: -2192.0 m * Campaign: AT18-08 * Basis: Atlantis (1997) * Method/Device: Remote operated vehicle Jason II (ROVJ)
J2-575 * Latitude: 47.900000 * Longitude: -129.000000 * Date/Time: 2011-07-21T16:23:00 * Elevation: -2203.0 m * Campaign: AT18-08 * Basis: Atlantis (1997) * Method/Device: Remote operated vehicle Jason II (ROVJ)
Parameter(s):
# | Name | Short Name | Unit | Principal Investigator | Method/Device | Comment |
---|---|---|---|---|---|---|
1 | Event label | Event | Hawkes, Jeffrey A | |||
2 | Latitude of event | Latitude | Hawkes, Jeffrey A | |||
3 | Longitude of event | Longitude | Hawkes, Jeffrey A | |||
4 | Identification | ID | Hawkes, Jeffrey A | |||
5 | Ocean and sea region | OS region | Hawkes, Jeffrey A | |||
6 | Site | Site | Hawkes, Jeffrey A | vent | ||
7 | Name | Name | Hawkes, Jeffrey A | vent | ||
8 | Sampling date | Sampling date | Hawkes, Jeffrey A | year | ||
9 | Sample type | Samp type | Hawkes, Jeffrey A | |||
10 | Type | Type | Hawkes, Jeffrey A | flow | ||
11 | Lithology/composition/facies | Lithology | Hawkes, Jeffrey A | |||
12 | Description | Description | Hawkes, Jeffrey A | geochemistry | ||
13 | Magnesium | Mg | mmol/l | Hawkes, Jeffrey A | ||
14 | Carbon, organic, dissolved | DOC | µmol/l | Hawkes, Jeffrey A | ||
15 | Precision | Precis | Hawkes, Jeffrey A | DOC [µmol/l] | ||
16 | Solid phase extractable | SPE | µmol/l | Hawkes, Jeffrey A | ||
17 | Precision | Precis | Hawkes, Jeffrey A | SPE [µmol/l] | ||
18 | Sample volume | Samp vol | ml | Hawkes, Jeffrey A | ||
19 | Volume | Vol | ml | Hawkes, Jeffrey A | extracted | |
20 | Factor | Factor | Hawkes, Jeffrey A | Extract dilution factor for SPEDOC analysis | ||
21 | Carbon, organic, dissolved, extracted | DOC extr | µmol/l | Hawkes, Jeffrey A | SPEDOC in extract | |
22 | Error | Error | Hawkes, Jeffrey A | SPEDOC in extract | ||
23 | Carbon, organic, dissolved, extracted | DOC extr | µmol/l | Hawkes, Jeffrey A | Procedural SPEDOC extract blank | |
24 | Precision | Precis | Hawkes, Jeffrey A | Extract Blank precision | ||
25 | Error | Error | Hawkes, Jeffrey A | Extract blank error [µmol/l] | ||
26 | Carbon, organic, dissolved, extracted | DOC extr | µmol/l | Hawkes, Jeffrey A | SPEDOC extract blank subtracted | |
27 | Error | Error | Hawkes, Jeffrey A | Extract error [µmol/l] | ||
28 | Carbon, organic, dissolved, extracted | DOC extr | µmol/l | Hawkes, Jeffrey A | SPEDOC | |
29 | Error | Error | Hawkes, Jeffrey A | SPEDOC error | ||
30 | Percentage | Perc | % | Hawkes, Jeffrey A | ||
31 | Contamination | Contamination | Hawkes, Jeffrey A | |||
32 | Comment | Comment | Hawkes, Jeffrey A | Bulk DOC quality control | ||
33 | Comment 2 (continued) | Comm 2 | Hawkes, Jeffrey A | Reason for omission from paper |
License:
Creative Commons Attribution 3.0 Unported (CC-BY-3.0)
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4130 data points
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