Calvert, Stephen E; Price, N B (1977): Chemical and mineralogical data on manganese nodules and associated sediment from the Pacific Ocean [dataset publication series]. PANGAEA, https://doi.org/10.1594/PANGAEA.861295,

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Supplement to: Calvert, SE; Price, NB (1977): Geochemical variation in ferromanganese nodules and associated sediments from the Pacific Ocean. Marine Chemistry, 5(1), 43-74, https://doi.org/10.1016/0304-4203(77)90014-7

The major and minor element compositions of a suite of abyssal sea-floor ferromanganese nodules and associated sediments from the eastern central Pacific have been used to examine inter-element relationships and the mineralogy of the nodules, the relationship between the composition of nodules, and their associated sediments and regional variations in composition with respect to likely modes for formation of such deposits. Apart from Mn and Fe, significant proportions of the total Ti, Ca, Mg, K, Ba, Sr, Th and Y and almost all the P, As, Ce, Co, Cu, Mo, Ni, Pb, Zn and Zr are present in the oxide fractions of the nodules. The Mg, Ba, Cu, Mo, Ni and Zn contents are significantly correlated with the total Fe content. Nodules from the northeastern tropical Pacific have Mn/Fe ratios highter than those in the oxide fractions of their associated sediments, todorokite as the principal Mn phase and relatively high concns of minor elements associated with Mn. Nodules from the south central Pacific have Mn/Fe ratios similar to those in the oxide fractions of the associated sediments, {delta}-MnO Sub(2) as the only Mn-phase, and relatively high concns of minor elements associated with Fe. There appears to be a smooth gradation in composition in the tropical Pacific between these 2 end members. The retional compositional variation is interpreted as a reflection of different sources of metals for, and different growth mechanisms of, sea-floor nodules. The oxide precipitate from sea water consists of {delta}-MnO Sub(2), has a relatively low Mn/Fe ratio and minor element contents related to the total Fe and Mn({delta}-MnO Sub(2)) content. The oxide precipitate forming in areas of very low sedimentation as a result of diagenetic remobilisation in the surface sediment consists of todorokite, and has a high Mn/Fe ratio and enhanced metal content in the Mn-(todorokite) phase. Available information on the morphology and compositional variation of individual nodules from the tropical Pacific corroborates these contrasting metal sources and suggests that they can be resolved on the scale of an individual oxide concretion.

From 1983 until 1989 NOAA-NCEI compiled the NOAA-MMS Marine Minerals Geochemical Database from journal articles, technical reports and unpublished sources from other institutions. At the time it was the most extended data compilation on ferromanganese deposits world wide. Initially published in a proprietary format incompatible with present day standards it was jointly decided by AWI and NOAA to transcribe this legacy data into PANGAEA. This transfer is augmented by a careful checking of the original sources when available and the encoding of ancillary information (sample description, method of analysis...) not present in the NOAA-MMS database.