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Chang, Alice S; Pichevin, Laetitia; Pedersen, Thomas F; Gray, Victoria; Ganeshram, Raja S (2015): (Table S1) Geochemistry for sediment core MD02-2515 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.841827, Supplement to: Chang, AS et al. (2015): New insights into productivity and redox-controlled trace element (Ag, Cd, Re, Mo) accumulation in a 55-kyr long sediment record from Guaymas Basin, Gulf of California. Paleoceanography, 30(2), 77-94, https://doi.org/10.1002/2014PA002681

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Abstract:
A high-resolution, 55-kyr long record of chalcophile and redox-sensitive trace element accumulation (Ag, Cd, Re, Mo) from MD02-2515, western Guaymas Basin, is investigated in conjunction with patterns in stratigraphy and productivity. High opal concentrations (~58 wt. %), representing increased diatom production, coincide with laminated sediments, and dilute the concentrations of organic carbon (Corg) and metals. A similarity between opal and normalized Corg, Ag and Cd concentrations suggests delivery to the sediments by diatom export production, while patterns in normalized Re and Mo accumulation suggest a different emplacement mechanism. Although Mo enrichment in organic-rich, laminated sediments typically represents anoxic conditions at other locations, Mo (and Re) in Guaymas Basin is enriched in nonlaminated and bioturbated sediments that are representative of oxygenated conditions. Adsorption onto Fe- and/or Mn-oxyhydroxide surfaces during oxygenation inadequately explains both the Re and Mo enrichments. Thus, recently published mechanisms invoking direct Re and Mo removal from the water column and bioturbation-assisted irrigation of Re into the sediments are used to explain the counterintuitive observations in Guaymas Basin. The MD02-2515 stratigraphic and proxy records are also different from other records in the northeast Pacific in that there is little correspondence with Greenland Dansgaard-Oeschger interstadials. There is some correlation with Heinrich events, suggesting that ventilation of intermediate waters and/or reduced productivity may be important in controlling stratigraphy and trace element accumulation. The results question whether MD02-2515 records can be compared to northeast Pacific open-margin records, especially before 17 kyr BP.
Further details:
Cheshire, Heather; Thurow, Juergen W (2013): High-resolution migration history of the Subtropical High/Trade Wind system of the northeastern Pacific during the last ~55 years: Implications for glacial atmospheric reorganization. Paleoceanography, 28(2), 319-333, https://doi.org/10.1002/palo.20031
Coverage:
Latitude: 27.483500 * Longitude: -112.074300
Date/Time Start: 2002-06-13T04:53:00 * Date/Time End: 2002-06-13T04:53:00
Minimum DEPTH, sediment/rock: 0.035 m * Maximum DEPTH, sediment/rock: 74.465 m
Event(s):
MD02-2515 (MD022515) * Latitude: 27.483500 * Longitude: -112.074300 * Date/Time: 2002-06-13T04:53:00 * Elevation: -881.0 m * Recovery: 74.49 m * Location: Guaymas Basin * Campaign: MD126 (IMAGES VIII - MONA) * Basis: Marion Dufresne (1995) * Method/Device: Calypso Corer (CALYPSO)
Comment:
Age is based on calibrated and interpolated radiocarbon ages. PI of age and corrected depth is Laetitia Pichevin (laetitia.pichevin@ed.ac.uk).
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
DEPTH, sediment/rockDepth sedmGeocode
Depth, correctedDepth corrmPichevin, LaetitiaCalculatedvoid corrected
AGEAgeka BPGeocode
Sedimentation rateSRcm/kaPichevin, LaetitiaCalculated
Nitrogen, totalTN%Pichevin, LaetitiaMeasured
Carbon, organic, totalTOC%Pichevin, LaetitiaMeasured
δ15N, bulk sedimentδ15N bulk‰ airPichevin, LaetitiaMeasured
δ13C, organic carbonδ13C Corg‰ PDBPichevin, LaetitiaMeasured
Opal, biogenic silicabSiO2%Pichevin, LaetitiaCalculated
10 SilverAgmg/kgChang, Alice SMeasured
11 CadmiumCdmg/kgChang, Alice SMeasured
12 RheniumReµg/kgChang, Alice SMeasured
13 MolybdenumMomg/kgChang, Alice SMeasured
14 Carbon, organic, totalTOC%Chang, Alice SCalculatedopal-free
15 SilverAgmg/kgChang, Alice SCalculatedopal-free
16 CadmiumCdmg/kgChang, Alice SCalculatedopal-free
17 RheniumReµg/kgChang, Alice SCalculatedopal-free
18 MolybdenumMomg/kgChang, Alice SCalculatedopal-free
19 AluminiumAl%Chang, Alice SCalculatedcalculated from oxide concentrations from Cheshire and Thurow (2013)
20 IronFe%Chang, Alice SCalculatedcalculated from oxide concentrations from Cheshire and Thurow (2013)
21 ManganeseMn%Chang, Alice SCalculatedcalculated from oxide concentrations from Cheshire and Thurow (2013)
22 Iron/Aluminium ratioFe/AlChang, Alice SCalculated
23 Manganese/Aluminium ratioMn/AlChang, Alice SCalculated
24 Carbon, organic/Aluminium ratioC org/AlChang, Alice SCalculateddetermined using OC sample data closest in age to Al sample data
25 Silver/Aluminium ratioAg/AlChang, Alice SCalculateddetermined using trace element sample data closest in age to Al sample data
26 Cadmium/Aluminium ratioCd/AlChang, Alice SCalculateddetermined using trace element sample data closest in age to Al sample data
27 Rhenium/Aluminium ratioRe/AlChang, Alice SCalculateddetermined using trace element sample data closest in age to Al sample data
28 Molybdenum/Aluminium ratioMo/AlChang, Alice SCalculateddetermined using trace element sample data closest in age to Al sample data
Size:
15516 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Depth sed [m]

Depth corr [m]
(void corrected, Calculated)

Age [ka BP]

SR [cm/ka]
(Calculated)

TN [%]
(Measured)

TOC [%]
(Measured)

δ15N bulk [‰ air]
(Measured)

δ13C Corg [‰ PDB]
(Measured)

bSiO2 [%]
(Calculated)
10 
Ag [mg/kg]
(Measured)
11 
Cd [mg/kg]
(Measured)
12 
Re [µg/kg]
(Measured)
13 
Mo [mg/kg]
(Measured)
14 
TOC [%]
(opal-free, Calculated)
15 
Ag [mg/kg]
(opal-free, Calculated)
16 
Cd [mg/kg]
(opal-free, Calculated)
17 
Re [µg/kg]
(opal-free, Calculated)
18 
Mo [mg/kg]
(opal-free, Calculated)
19 
Al [%]
(calculated from oxide concent...)
20 
Fe [%]
(calculated from oxide concent...)
21 
Mn [%]
(calculated from oxide concent...)
22 
Fe/Al
(Calculated)
23 
Mn/Al
(Calculated)
24 
C org/Al
(determined using OC sample da...)
25 
Ag/Al
(determined using trace elemen...)
26 
Cd/Al
(determined using trace elemen...)
27 
Re/Al
(determined using trace elemen...)
28 
Mo/Al
(determined using trace elemen...)
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0.0801.8806.8161660.232.559.1-20.147.90.3371.2714.56.44.90.6482.427.812.2
0.1201.9206.8411660.262.7510.4-19.935.24.2
0.1701.9706.8711660.272.8210.1-19.832.30.3161.3616.77.04.20.4662.024.710.3
0.2202.0206.9011660.333.2510.4-20.230.44.7
0.2442.0446.9151663.871.630.00770.422.00E-3
0.2702.0706.9311660.252.8310.3-20.138.80.3961.3817.57.74.60.6472.228.612.67.30E-11.02E-53.60E-54.50E-72.00E-4
0.3202.1206.9611660.232.519.9-19.936.74.0
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0.4202.2207.0221660.272.9110.4-20.328.24.1
0.4702.2707.0521660.333.1910.3-20.131.70.4111.5019.98.94.70.6022.229.113.0
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0.6202.4207.1421660.243.029.5-20.134.54.6
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0.9702.7707.3541660.272.8910.2-20.325.00.3001.3516.15.73.90.4001.821.57.6
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1.4683.2687.6541660.232.6010.8-20.534.30.2581.4315.24.94.00.3922.223.17.4
1.5153.3157.6831660.282.9310.3-20.431.44.3
1.5653.3657.7131660.323.4210.8-20.231.70.3851.8621.77.05.00.5642.731.810.3
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1.6653.4657.7731660.293.1410.4-20.242.00.2812.0917.47.85.40.4843.630.013.4
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1.8153.6157.8641660.252.869.5-20.836.84.5
1.8653.6657.8941660.302.9210.9-20.637.00.2671.3217.95.74.60.4242.128.59.1
1.9153.7157.9241660.283.0210.2-20.638.84.9
1.9653.7657.9551660.282.9710.4-20.836.00.2941.6017.86.84.60.4592.527.810.6
2.0153.8157.9851660.303.0510.4-20.839.75.1
2.0653.8658.0151660.282.8710.1-20.930.60.3541.2715.05.34.10.5101.821.67.7
2.1153.9158.0451660.272.8110.3-20.431.84.1
2.1653.9658.0751660.282.9310.1-20.534.30.2591.3917.35.44.50.3942.126.38.2
2.2154.0158.1061660.303.0710.0-20.524.44.1
2.2404.0408.1211664.361.990.01550.463.56E-3
2.2654.0658.1361660.282.839.6-20.742.40.2931.5417.57.04.90.5102.730.312.26.50E-16.70E-63.50E-54.00E-71.60E-4
2.3154.1158.1661660.272.889.5-19.941.04.9
2.3654.1658.1961660.242.548.4-21.036.40.2691.3616.86.24.00.4232.126.49.7
2.4154.2158.2261660.232.668.0-20.835.44.1
2.4154.2158.2261660.292.7010.2-20.3
2.4654.2658.2571130.232.648.0-20.638.10.2441.3718.46.24.30.3952.229.810.1
2.5154.3158.3011130.232.458.6-21.039.54.1
2.5654.3658.3451130.252.679.2-20.634.20.3341.5814.96.64.10.5082.422.710.0
2.5984.3988.3741130.222.589.1-21.030.13.7
2.6254.4258.3981130.292.989.7-20.837.80.3882.0121.27.14.80.6233.234.011.4
2.6654.4658.4341130.212.469.1-21.1
2.7154.5158.4781130.272.768.7-20.842.80.2921.5517.05.94.80.5102.729.810.48.10E-64.30E-54.70E-71.60E-4
2.7404.5408.5001133.611.530.00770.422.15E-3
2.7654.5658.5231130.252.689.4-20.843.54.77.40E-1
2.8154.6158.5671130.313.0910.0-19.938.80.3641.8017.46.35.00.5952.928.510.4
2.8154.6158.5671130.343.0810.9-19.7
2.8654.6658.6111130.232.538.6-20.742.14.4
2.9154.7158.6561130.303.139.1-20.534.70.3901.9516.57.94.80.5973.025.312.1
2.9684.7688.7021130.242.478.9-20.729.53.5
3.0154.8108.7401130.272.7010.2-20.240.10.3242.4313.36.04.50.5414.122.19.9
3.0154.8108.7401130.282.7010.5-19.9
3.0654.8608.7841130.252.659.9-20.244.44.8
3.1284.9238.8401130.313.0410.0-20.433.20.3751.8723.89.44.50.5612.835.714.1
3.1654.9608.8731130.272.849.6-20.437.34.5
3.2185.0138.9191130.313.1710.1-20.040.10.3852.8816.914.15.30.6434.828.223.57.60E-19.20E-66.90E-54.10E-73.40E-4
3.2185.0138.9191130.333.1910.6-19.7
3.2405.0358.9391134.181.840.01550.443.71E-3
3.2655.0608.9611130.303.109.6-20.034.94.8
3.3155.1109.0061130.303.009.3-20.328.90.3352.1517.85.54.20.4713.025.17.7
3.3655.1609.0501130.292.938.4-20.237.54.7
3.4205.1959.0811130.293.039.1-20.041.50.3341.5717.76.55.20.5722.730.311.1
3.4805.2439.1241130.302.769.0-20.339.74.6
3.5235.2869.1611130.292.809.0-20.324.30.3031.2016.34.53.70.4001.621.56.0
3.5555.3189.1901130.252.528.9-20.330.93.7
3.5555.3189.1901130.282.489.9-20.0
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3.7555.4089.2701134.441.780.01550.403.49E-3
3.7655.4189.2791130.292.768.7-20.234.14.26.20E-1
3.8155.4689.3231130.292.648.8-20.238.00.3021.1616.06.24.30.4871.925.810.1
3.8655.5189.3681130.312.889.2-20.134.84.4
3.9155.5689.4121130.312.688.8-20.229.30.3782.3120.76.63.80.5353.329.39.3
3.9655.6189.4561130.282.698.6-20.228.03.7
4.0155.6689.5011130.282.918.7-20.230.50.3291.3018.25.84.20.4731.926.18.4
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