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Foster, Gavin L; Sexton, Philip F (2014): Summary of boron isotope and Mg/Ca data [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.839680, Supplement to: Foster, GL; Sexton, PF (2014): Enhanced carbon dioxide outgassing from the eastern equatorial Atlantic during the last glacial. Geology, 42(11), 1003-1006, https://doi.org/10.1130/G35806.1

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Abstract:
Biological productivity and carbon export in the equatorial Atlantic are thought to have been dramatically higher during the last glacial period than during the Holocene. Here we reconstruct the pH and CO2 content of surface waters from the eastern equatorial Atlantic Ocean over the past ~30 k.y. using the boron isotope composition of Globigerinoides ruber (a mixed-layer-dwelling planktic foraminifera). Our new record, combined with previously published data, indicates that during the last glacial, in contrast to today, a strong west to east gradient existed in the extent of air:sea equilibrium with respect to pCO2 (DeltapCO2), with the eastern equatorial Atlantic acting as a significant source of CO2 (+100 µatm) while the western Atlantic remained close to equilibrium (+25 µatm). This pattern suggests that a fivefold increase in the upwelling rate of deeper waters drove increased Atlantic productivity and large-scale regional cooling during the last glacial, but the higher than modern DeltapCO2 in the east indicates that export production did not keep up with enhanced upwelling of nutrients. However, the downstream decline of DeltapCO2 provides evidence that the unused nutrients from the east were eventually used for biologic carbon export, thereby effectively negating the impact of changes in upwelling on atmospheric CO2 levels. Our findings indicate that the equatorial Atlantic exerted a minimal role in contributing to lower glacial-age atmospheric CO2.
Coverage:
Median Latitude: 4.970222 * Median Longitude: -44.263099 * South-bound Latitude: -1.665000 * West-bound Longitude: -78.739300 * North-bound Latitude: 12.744000 * East-bound Longitude: -12.428330
Date/Time Start: 1989-02-25T00:00:00 * Date/Time End: 1996-01-14T23:15:00
Minimum DEPTH, sediment/rock: 0.05 m * Maximum DEPTH, sediment/rock: 1.67 m
Event(s):
165-999A  * Latitude: 12.744000 * Longitude: -78.739300 * Date/Time Start: 1996-01-10T19:30:00 * Date/Time End: 1996-01-14T23:15:00 * Elevation: -2828.0 m * Penetration: 566.1 m * Recovery: 534.83 m * Location: Caribbean Sea * Campaign: Leg165 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 61 core; 566.1 m cored; 0 m drilled; 94.5 % recovery
GeoB1105-4  * Latitude: -1.665000 * Longitude: -12.428330 * Date/Time: 1989-02-25T00:00:00 * Elevation: -3225.0 m * Penetration: 17 m * Recovery: 15.22 m * Location: Equatorial Atlantic * Campaign: M9/4 * Basis: Meteor (1986) * Method/Device: Gravity corer (Kiel type) (SL) * Comment: cc: Karbonatschlamm, tonig
GeoB1523-1  * Latitude: 3.831667 * Longitude: -41.621667 * Date/Time: 1991-05-17T00:00:00 * Elevation: -3292.0 m * Recovery: 6.65 m * Location: Amazon Fan * Campaign: M16/2 * Basis: Meteor (1986) * Method/Device: Gravity corer (Kiel type) (SL)
Size:
423 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Event

Depth sed [m]

Age [ka BP]

δ11B [‰ SRM]
(MC-ICP-MS Thermo-Finnigan Nep...)

δ11B std dev [±]

G. ruber Mg/Ca [mmol/mol]
(ICP-MS, Thermo Fisher Scienti...)

SST (1-12) [°C]
(Calculated from Mg/Ca ratios ...)

pCO2(aq) [µatm]
(seawater)

pCO2(aq) [µatm]
(seawater, 2.5%)
10 
pCO2(aq) [µatm]
(seawater, 14%)
11 
pCO2(aq) [µatm]
(seawater, 86%)
12 
pCO2(aq) [µatm]
(seawater, 97.5%)
GeoB1105-4 0.369.220.340.253.8125.6300273285319331
GeoB1105-40.4611.420.650.254.0326.2270251256285290
GeoB1105-40.5513.320.580.253.7725.5277257262289300
GeoB1105-40.6514.620.720.253.5424.8256229244273278
GeoB1105-40.7515.720.540.253.2623.9266238254281292
GeoB1105-40.8016.420.130.252.8622.4302277287316324
GeoB1105-40.8918.020.120.252.6621.6295273280310330
GeoB1105-40.9519.120.210.252.8122.2290261272309334
GeoB1105-41.0520.420.220.252.7522.0284262271300316
GeoB1105-41.1521.519.860.252.6921.7330301310348367
GeoB1105-41.2423.020.160.252.8822.5296263282314328
GeoB1105-41.3724.820.350.252.9422.7281249266295309
GeoB1105-41.4726.820.700.252.9522.8238218225252269
GeoB1105-41.5728.820.140.252.9622.8303270286319331
GeoB1105-41.5728.820.590.253.0123.0254225239269275
GeoB1105-41.6730.820.730.253.0323.1244218230258268
GeoB1523-1 0.053.120.780.254.6527.8273251259285299
GeoB1523-10.106.020.720.254.4727.4277253265294300
GeoB1523-10.158.520.970.254.5627.6252234239265279
GeoB1523-10.2010.520.730.254.2926.9273245258287300
GeoB1523-10.2512.621.290.254.1426.5217197203228234
GeoB1523-10.3014.621.130.254.0226.2229210218239258
GeoB1523-10.3516.621.330.253.5624.9201183191210221
GeoB1523-10.4018.221.370.253.6825.2203181191214219
GeoB1523-10.4519.121.150.253.5324.8216197205226234
GeoB1523-10.5520.921.140.253.8125.6222206212232242
GeoB1523-10.6523.920.990.253.6925.3235217222246254
GeoB1523-10.7527.421.170.253.6925.2219200208229240
GeoB1523-10.8530.920.670.253.5824.9265242249279294
165-999A 0.053.920.670.254.8028.2288268273303310
165-999A0.114.620.780.254.9128.4278249261295309
165-999A0.155.020.590.254.7628.1299268283319332
165-999A0.317.820.820.254.8128.2275249260292300
165-999A0.317.820.720.254.8128.2279254265294310
165-999A0.399.520.680.254.5427.6279250263295303
165-999A0.4310.320.930.254.5127.5256230240269282
165-999A0.4811.720.720.254.3327.0271247258283296
165-999A0.5714.020.980.254.4827.4251229237264270
165-999A0.6115.121.020.254.4827.4244224231259268
165-999A0.6115.121.150.254.4827.4233213224242248
165-999A0.7117.321.040.254.2026.7237217224248262
165-999A0.8219.221.750.254.0326.2183168174191200
165-999A0.9321.121.200.253.9025.9220206209230240
165-999A1.0222.521.260.254.2126.7220203207231239
165-999A1.1324.821.510.254.0926.4199182192208223
165-999A1.2026.321.620.254.0426.3191173181201209
165-999A1.2026.321.690.254.0426.3185170175195205