Citation:

2004PA001043

Name: Geochemistry of Eocene/Oligocene sediments of ODP Site 177-1090
Published: 2005
License: https://creativecommons.org/licenses/by/3.0/

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Abstract:

The Agulhas Ridge, off the tip of Africa between the Atlantic and Indian Oceans, is ideally located to capture the evolution of Paleogene-early Neogene circulation patterns associated with global cooling. Multiproxy records of productivity (biogenic barium (Baex), opal, CaCO3 mass accumulation rates (MARs)), nutrient and organic carbon burial (reactive phosphorus (Pr) MARs), and redox state of deep waters (U enrichment) from Ocean Drilling Program (ODP) Site 1090 reflect hydrographic shifts in this region between the middle Eocene and early Oligocene (~9–33 Ma). Several peaks in increased export productivity and burial of organic matter occurred within the late Eocene (~36.5, ~34, and ~33.7 Ma), which along with surface hydrologic conditions favoring opaline organisms over calcareous organisms could have aided in the draw down of pCO2 to a threshold level that facilitated large ice sheet development on Antarctica in the earliest Oligocene. Our multiproxy approach illustrates the importance of vertical as well as spatial hydrographic reorganization in amplifying or driving climatic cooling of the middle Eocene to early Oligocene by facilitating increases in the relative or absolute burial of organic carbon.

Other version:

Anderson, Linda Davis; Delaney, Margaret Lois (2005): NOAA/WDS Paleoclimatology - Southern Ocean Middle Eocene to Early Oligocene Paleoceanographic Data. NOAA National Centers for Environmental Information, https://doi.org/10.25921/TTWX-JW26

Project(s):

Ocean Drilling Program (ODP)

Coverage:

Median Latitude: -42.913650 * Median Longitude: 8.899850 * South-bound Latitude: -42.913700 * West-bound Longitude: 8.899700 * North-bound Latitude: -42.913600 * East-bound Longitude: 8.900000

Date/Time Start: 1997-12-26T15:22:00 * Date/Time End: 1997-12-30T00:55:00

Minimum DEPTH, sediment/rock: 211.6 m * Maximum DEPTH, sediment/rock: 357.3 m

Event(s):

177-1090B * Latitude: -42.913700 * Longitude: 8.899700 * Date/Time Start: 1997-12-26T15:22:00 * Date/Time End: 1997-12-28T14:55:00 * Elevation: -3699.4 m * Penetration: 397.5 m * Recovery: 373.23 m * Location: South Atlantic Ocean * Campaign: * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 43 cores; 397.5 m cored; 0 m drilled; 93.9 % recovery

177-1090D * Latitude: -42.913600 * Longitude: 8.900000 * Date/Time Start: 1997-12-28T23:25:00 * Date/Time End: 1997-12-30T00:55:00 * Elevation: -3702.1 m * Penetration: 225.9 m * Recovery: 213.64 m * Location: South Atlantic Ocean * Campaign: * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 24 cores; 225.9 m cored; 0 m drilled; 94.6 % recovery

Comment:

DEPTH, sediment/rock is given in mbsf. Analytical detection limits in typical size samples ( three times the standard deviation of replicate measures of a low concentration solution standard): 0.3 mmol/g for oxide-associated P, 0.4 mmol/g for authigenic P, 0.1 mmol/g for detrital P, and 0.1 mmol/g for organic P. With the exception of oxide-associated P concentrations in some samples, P concentrations were generally well above these detection limits. The relative errors (1s) on the long-term means solid consistency standards were relatively high for the components that constitute small fractions of total P, ranging from 14% to 40% for oxide-associated. P in the detrital component for site 1090 was well above the detection limit but more variable (20%) than the Ceara Rise consistency standard (6%).

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Method/Device	Comment
1	Event label	Event
2	Sample code/label	Sample label		Anderson, Linda Davis	DSDP/ODP/IODP sample designation
3	DEPTH, sediment/rock	Depth sed	m			Geocode
4	Depth, composite	Depth comp	mcd	Anderson, Linda Davis
5	AGE	Age	ka BP			Geocode
6	Calcium	Ca2+	mmol/kg	Anderson, Linda Davis
7	Manganese	Mn	mmol/kg	Anderson, Linda Davis
8	Barium	Ba2+	µmol/kg	Anderson, Linda Davis
9	Uranium	U	µmol/kg	Anderson, Linda Davis
10	Titanium	Ti	mmol/kg	Anderson, Linda Davis
11	Aluminium	Al	mg/kg	Anderson, Linda Davis
12	Method comment	Method comm		Anderson, Linda Davis
13	Aluminium/Titanium ratio	Al/Ti		Anderson, Linda Davis		mmol/mol
14	Barium excess	Ba xs	mmol/kg	Anderson, Linda Davis
15	Calcium carbonate	CaCO3	%	Anderson, Linda Davis		wt%
16	Silicon dioxide	SiO2	%	Anderson, Linda Davis		wt%
17	Terrigenous	Terr	%	Anderson, Linda Davis		wt%, detrital
18	Phosphorus, reactive	P react	µmol/g	Anderson, Linda Davis		P reactive = P total - P detrital
19	Phosphorus, total	TP	µmol/g	Anderson, Linda Davis		P total= all components of the sequential extraction
20	Phosphorus, total	TP	µmol/g	Anderson, Linda Davis		PTD= P oncentration from total digestion of the sediment
21	Phosphorus, detrital	P detr	µmol/g	Anderson, Linda Davis
22	Accumulation rate, phosphorus	Acc rate P	µmol/cm²/ka	Anderson, Linda Davis
23	Accumulation rate, barium, excess	Acc rate Ba ex	µmol/cm²/ka	Anderson, Linda Davis
24	Accumulation rate, calcium carbonate	Acc rate CaCO3	mmol/cm²/ka	Anderson, Linda Davis
25	Accumulation rate, opal	Acc rate opal	mmol/cm²/ka	Anderson, Linda Davis

License:

Creative Commons Attribution 3.0 Unported (CC-BY-3.0)

Size:

3696 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 Event	2 Sample label	3 Depth sed [m]	4 Depth comp [mcd]	5 Age [ka BP]	6 Ca2+ [mmol/kg]	7 Mn [mmol/kg]	8 Ba2+ [µmol/kg]	9 U [µmol/kg]	10 Ti [mmol/kg]	11 Al [mg/kg]	12 Method comm	13 Al/Ti (mmol/mol)	14 Ba xs [mmol/kg]	15 CaCO3 [%] (wt%)	16 SiO2 [%] (wt%)	17 Terr [%] (wt%, detrital)	18 P react [µmol/g] (P reactive = P total - P detr...)	19 TP [µmol/g] (P total= all components of th...)	20 TP [µmol/g] (PTD= P oncentration from tota...)	21 P detr [µmol/g]	22 Acc rate P [µmol/cm²/ka]	23 Acc rate Ba ex [µmol/cm²/ka]	24 Acc rate CaCO3 [mmol/cm²/ka]	25 Acc rate opal [mmol/cm²/ka]
177-1090D	177-1090D-23H-4,23.5-25.5	211.6	224.3	33070	2390	13.88	7280	1.63	42.04	0.77		18.37	6.14	26.61	19.73	53.66	21.17	26.21		5.04	59.47	17.25	7.48	8.65
177-1090D	177-1090D-23H-4,102.5-104.5	212.4	225.1	33090	4920	15.62	5560	2.26	44.11	0.97		22.01	4.13	48.87	9.50	41.63	15.41	18.81		3.40	43.27	11.61	13.73	4.16
177-1090D	177-1090D-23H-5,25-27	213.2	225.8	33110	5310	18.29	9330	1.55	30.07	0.60		20.05	8.44	55.73	11.31	32.96	9.93	12.56		2.63	26.06	22.16	14.63	4.63
177-1090D	177-1090D-23H-5,100-102	213.9	226.5	33130	4880	18.69	8260	1.92	38.51	0.74		19.27	7.17	53.81	10.15	36.05	11.46	14.20		2.74	30.08	18.81	14.12	4.15
177-1090D	177-1090D-23H-6,25-27	214.7	227.3	33150	4790	21.17	8100	1.86	44.33	0.78		17.66	6.95	48.45	10.94	40.60	13.19	16.37		3.18	34.63	18.24	12.71	4.48
177-1090D	177-1090D-24H-1,25-27	216.7	228.3	33170	5440	23.34	8030	2.62	37.48	0.62		16.57	7.11	56.07	10.79	33.15	8.83	11.65		2.82	23.17	18.67	14.71	4.42
177-1090D	177-1090D-24H-1,100-102	217.4	229.0	33190	4960	23.13	8320	3.91	40.37	0.72		17.89	7.26	52.05	11.90	36.05	10.12	12.57		2.45	26.56	19.06	13.66	4.87
177-1090D	177-1090D-24H-2,27-29	218.2	229.8	33220	4950	26.21	7510	4.11	33.69	0.65		19.38	6.55	52.97	5.57	41.46	8.21	10.33		2.13	21.54	17.18	13.90	2.28
177-1090D	177-1090D-24H-2,100-102	218.9	230.5	33230	6410	33.97	4910	3.96	19.77	0.40		20.07	4.33	70.54	4.81	24.65	7.97	9.37		1.40	20.92	11.36	18.51	1.97
177-1090D	177-1090D-24H-3,27-29	219.7	231.3	33260	5730	29.90	7040	3.31	28.94	0.57		19.61	6.21	60.09	4.70	35.21	8.72	10.87		2.15	22.90	16.30	15.77	1.92
177-1090D	177-1090D-24H-3,100-102	220.4	232.0	33280	5200	26.89	6330	3.75	28.43	0.52		18.24	5.56	56.23	8.33	35.44	8.29	9.84		1.55	21.75	14.60	14.76	3.41
177-1090D	177-1090D-24H-4,27-29	221.2	232.8	33300										46.32	13.23	40.46	8.59	11.94		3.35	22.55		12.15	5.42
177-1090D	177-1090D-24H-4,100-102	221.9	233.5	33320	5710	32.11	5980	4.28	25.43	0.52		20.42	5.22	61.09	6.54	32.37	7.77	9.40		1.63	20.40	13.70	16.03	2.68
177-1090D	177-1090D-24H-5,26.5-28.5	222.7	234.3	33340	4860	23.00	6570	5.07	33.00	0.61		18.59	5.67	50.23	13.75	36.02	7.67	9.59		1.92	20.12	14.88	13.18	5.63
177-1090D	177-1090D-24H-5,100-102	223.4	235.0	33360	5600	30.42	6450	4.34	26.49	0.48		18.15	5.75	59.98	11.03	28.99	8.42	10.02		1.60	22.10	15.08	15.74	4.51
177-1090D	177-1090D-24H-6,25-27	224.2	235.8	33380	4580	24.51	7310	4.74	38.01	0.67		17.52	6.33	48.90	13.88	37.23	10.31	12.88		2.57	27.07	16.61	12.83	5.68
177-1090D	177-1090D-24H-6,100-102	224.9	236.5	33400	6130	33.88	7370	3.59	28.17	0.59		20.77	6.51	64.20	7.68	28.12	10.21	11.95		1.74	26.78	17.09	16.85	3.14
177-1090D	177-1090D-24H-7,27-29	225.7	237.3	33420	5830	33.94	6860	2.82	26.89	0.52		19.37	6.10	60.84	10.01	29.15	7.14	8.83		1.69	18.73	16.00	15.97	4.10
177-1090B	177-1090B-24X-1,60-62	214.4	225.4	33090	3450	15.01	8840	1.53	38.47	0.75		19.61	7.73	40.55	17.36	42.09	10.95	13.87		2.92	28.74	20.29	10.64	7.11
177-1090B	177-1090B-24X-2,58-60	215.9	226.8	33130	5530	20.96	5730	1.61	36.14	0.69	reruns with low HF:HNO3 digestion method	18.97	4.72	65.59	6.75	27.66	8.93	11.18		2.24	23.45	12.40	17.21	2.76
177-1090B	177-1090B-24X-3,53-55	217.3	228.3	33170	4610	21.98	8990	1.65	40.80	0.64	reruns with low HF:HNO3 digestion method	15.69	8.05	54.85	11.45	33.70	8.13	11.18		3.06	21.33	21.11	14.39	4.69
177-1090B	177-1090B-24X-4,60-62	218.9	229.9	33220	4940	26.77	6150	3.63	33.39	0.59	reruns with low HF:HNO3 digestion method	17.57	5.29	58.53	12.18	29.29	5.82	8.01		2.19	15.27	13.89	15.36	4.99
177-1090B	177-1090B-24X-5,60-62	220.4	231.4	33260	4970	27.56	6530	2.81	30.59	0.56	reruns with low HF:HNO3 digestion method	18.39	5.71	61.22	9.91	28.87	6.31	8.49		2.19	16.56	14.98	16.07	4.06
177-1090B	177-1090B-24X-6,60-62	221.9	232.9	33300	3910	23.58	5350	3.80	43.33	0.76	reruns with low HF:HNO3 digestion method	17.53	4.23	48.51	13.05	38.43	7.22	10.99		3.77	18.96	11.10	12.73	5.34
177-1090B	177-1090B-24X-7,25-27	223.1	234.0	33330	4020	28.13	4980	1.65	34.97	0.71	reruns with low HF:HNO3 digestion method	20.17	3.94	62.71	10.66	26.63	6.59	8.58		1.99	17.30	10.35	16.46	4.36
177-1090B	177-1090B-25X-1,30-32	223.8	234.5	33340	4160	25.87	5930	3.61	29.50	0.52	reruns with low HF:HNO3 digestion method	17.52	5.17	56.40	14.76	28.84	6.22	8.89		2.67	16.32	13.56	14.80	6.04
177-1090B	177-1090B-25X-1,80-82	224.3	235.0	33360	5450	32.52	5200	3.43	25.85	0.46	reruns with low HF:HNO3 digestion method	17.61	4.53	73.05	7.88	19.07	6.00	8.39		2.39	15.75	11.89	19.17	3.23
177-1090B	177-1090B-25X-1,130-132	224.8	235.5	33370	4300	24.23	6670	4.76	41.07	0.71	reruns with low HF:HNO3 digestion method	17.19	5.63	53.10	12.39	34.51	8.66	12.18		3.52	22.72	14.78	13.94	5.07
177-1090B	177-1090B-25X-2,30-32	225.3	236.0	33380	4340	25.68	5800	5.67	38.99	0.79	reruns with low HF:HNO3 digestion method	20.28	4.64	59.44	10.15	30.41	9.70	13.93		4.24	25.44	12.18	15.60	4.15
177-1090B	177-1090B-25X-2,80-82	225.8	236.5	33400	5430	33.39	7210	3.99	31.43	0.60	reruns with low HF:HNO3 digestion method	18.94	6.34	68.57	7.76	23.68	7.58	10.14		2.56	19.89	16.63	17.99	3.17
177-1090B	177-1090B-25X-2,130-132	226.3	237.0	33410	5030	33.98	5900	3.97	30.50	0.54	reruns with low HF:HNO3 digestion method	17.67	5.11	66.33	8.55	25.12	6.09	8.58		2.50	15.97	13.40	17.41	3.50
177-1090B	177-1090B-25X-3,30-32	226.8	237.5	33420	4860	29.75	5140	2.29	24.64	0.43	reruns with low HF:HNO3 digestion method	17.40	4.51	67.38	10.58	22.05	7.36	9.49		2.14	19.30	11.83	17.68	4.33
177-1090B	177-1090B-25X-3,80-82	227.3	238.0	33440	4560	27.78	5940	2.50	27.07	0.47	reruns with low HF:HNO3 digestion method	17.54	5.25	64.61	11.35	24.04	8.87	11.84		2.97	23.29	13.77	16.96	4.65
177-1090B	177-1090B-25X-3,130-132	227.8	238.5	33450	4920	32.38	5300	2.97	30.67	0.45	reruns with low HF:HNO3 digestion method	14.79	4.63	65.65	10.57	23.78	8.70	11.78		3.08	22.84	12.15	17.23	4.33
177-1090B	177-1090B-25X-4,30-32	228.3	239.0	33460	4590	33.74	5770	2.94	35.39	0.53	reruns with low HF:HNO3 digestion method	14.96	4.99	54.24	12.62	33.13	9.34	12.83		3.49	24.50	13.09	14.24	5.17
177-1090B	177-1090B-25X-4,80-82	228.8	239.5	33480	3830	28.26	5520	2.50	31.07	0.50	reruns with low HF:HNO3 digestion method	16.14	4.78	43.58	13.17	43.25	7.79	10.58		2.79	20.45	12.55	11.44	5.39
177-1090B	177-1090B-25X-4,130-132	229.3	240.0	33490	3140	18.41	6080	2.64	28.01	0.57	reruns with low HF:HNO3 digestion method	20.41	5.24	40.73	11.59	47.69	9.33	11.10		1.77	24.47	13.76	10.69	4.74
177-1090B	177-1090B-25X-5,30-32	229.8	240.5	33500	2490	11.94	5580	2.77	29.17	0.54	reruns with low HF:HNO3 digestion method	18.66	4.78	30.66	20.91	48.42	9.27	11.00		1.74	24.32	12.55	8.05	8.56
177-1090B	177-1090B-25X-5,78-80	230.3	241.0	33520	2600	11.95	5300	2.99	23.08	0.39	reruns with low HF:HNO3 digestion method	16.96	4.72	32.77	19.14	48.09	9.87	11.60		1.73	25.89	12.40	8.60	7.84
177-1090B	177-1090B-25X-5,132-134	230.8	241.5	33530	1850	6.79	4540	2.96	21.84	0.36		16.67	4.01	18.04	22.77	59.19	10.01	11.17		1.16	26.26	10.51	4.73	9.32
177-1090B	177-1090B-25X-6,32-34	231.3	242.0	33550	1990	8.74	5550	3.22	26.52	0.43		16.36	4.91	23.48	20.10	56.42	12.55	14.08		1.54	33.71	13.19	6.31	8.42
177-1090B	177-1090B-25X-6,82-84	231.8	242.5	33560	2450	14.63	6480	2.99	35.71	0.62	reruns with low HF:HNO3 digestion method	17.48	5.57	29.62	21.10	49.28	10.89	13.12		2.23	29.27	14.95	7.96	8.84
177-1090B	177-1090B-25X-6,132-134	232.3	243.0	33570	2320	10.56	6340	2.53	28.18	0.47		16.54	5.65	24.34	20.24	55.42	8.52	10.02		1.50	22.89	15.19	6.54	8.48
177-1090B	177-1090B-25X-7,28-30	232.8	243.5	33580	2710	19.40	6210	3.07	31.79	0.65	reruns with low HF:HNO3 digestion method	20.40	5.26	34.66	16.97	48.37	12.71	15.24		2.53	34.16	14.13	9.31	7.11
177-1090B	177-1090B-26X-1,31-33	233.5	245.5	33640	1930	17.84	7600	4.23	53.22	0.95		17.90	6.20	19.95	17.87	62.18	16.71	20.04		3.33	44.90	16.65	5.36	7.49
177-1090B	177-1090B-26X-1,83-85	234.0	246.0	33650	3030	23.72	6980	2.47	42.95	0.90	reruns with low HF:HNO3 digestion method	20.87	5.66	40.92	9.09	49.99	21.53	26.81		5.28	57.85	15.21	10.99	3.81
177-1090B	177-1090B-26X-1,130.5-132.5	234.5	246.5	33660	1630	20.94	10110	3.29	72.81	1.33	reruns with low HF:HNO3 digestion method	18.26	8.15	18.40	13.14	68.46	21.09	27.45		6.36	56.65	21.90	4.94	5.51
177-1090B	177-1090B-26X-2,32-34	235.0	247.0	33680	1610	20.02	8900	2.80	65.42	1.26	reruns with low HF:HNO3 digestion method	19.23	7.05	19.68	16.99	63.33	20.68	29.13		8.45	55.55	18.94	5.29	7.12
177-1090B	177-1090B-26X-2,82-84	235.5	247.5	33690	1600	22.52	8740	2.98	79.47	1.32	reruns with low HF:HNO3 digestion method	16.56	6.81	19.10	14.65	66.25	23.98	31.77		7.79	64.41	18.29	5.13	6.14
177-1090B	177-1090B-26X-2,132.5-134.5	236.0	248.0	33700	2780	26.51	10030	2.24	54.09	1.10	reruns with low HF:HNO3 digestion method	20.38	8.41	33.54	13.59	52.86	18.46	22.43		3.97	49.58	22.60	9.01	5.70
177-1090B	177-1090B-26X-3,32-34	236.5	248.5	33720	1630	13.40	7910	2.64	76.99	1.04		13.47	6.39	18.11	16.94	64.95	16.69	22.59		5.88	30.94	11.85	3.36	4.90
177-1090B	177-1090B-26X-3,82.5-84.5	237.0	249.0	33730	4430	28.02	4740	1.77	37.92	0.71		18.76	3.70	47.10	14.66	38.24	10.15	12.67		2.52	18.82	6.85	8.73	4.24
177-1090B	177-1090B-26X-3,132.5-134.5	237.5	249.5	33740	3000	27.21	8790	3.05	66.89	1.05		15.67	7.25	31.69	16.28	52.02	21.52	25.97		4.45	39.89	13.44	5.88	4.71
177-1090B	177-1090B-26X-4,32-34	238.0	250.0	33760	1350	20.26	9500	3.57	81.02	1.32		16.24	7.56	14.08	11.96	73.96	23.32	29.61		6.29	43.24	14.02	2.61	3.46
177-1090B	177-1090B-26X-4,81-83	238.5	250.5	33770	1680	24.24	8340	3.99	76.37	1.11		14.59	6.70	18.89	10.72	70.39	25.19	30.75		5.56	46.71	12.42	3.50	3.10
177-1090B	177-1090B-26X-4,133-135	239.0	251.0	33780	1750	27.28	10030	3.17	72.07	1.06		14.71	8.48	16.98	13.12	69.90	19.69	24.56		4.87	36.50	15.71	3.15	3.80
177-1090B	177-1090B-26X-5,27-28	239.5	251.5	33800	3720	33.15	6960	2.11	41.48	0.71		17.12	5.92	40.23	9.86	49.91	14.30	17.37		3.07	29.76	12.32	8.37	3.20
177-1090B	177-1090B-26X-5,86-88	240.1	252.1	33810	180	5.30	12570	2.37	72.04	1.04		14.43	11.04	0.32	10.98	88.70	15.47	20.50		5.02	32.20	22.98	0.07	3.57
177-1090B	177-1090B-26X-5,136.5-138.5	240.6	252.6	33820	230	5.11	3050	1.86	43.76	0.96		21.90	1.64		31.01	68.99	8.43	10.38		1.95	17.54	3.42	0.00
177-1090B	177-1090B-26X-6,32-34	241.0	253.0	33840	230	7.74	12620	2.62	63.47	1.44		22.74	10.50		16.68	83.32	12.13	15.75		3.62	25.25	21.85	0.00	5.41
177-1090B	177-1090B-26X-6,81-83	241.5	253.5	33850	170	4.43	11150	3.11	88.94	1.21		13.65	9.36		11.04	88.96	15.79	21.04		5.25	32.86	19.49	0.00	3.58
177-1090B	177-1090B-26X-6,138-140	242.1	254.1	33860	220	6.30	8950	3.47	94.08	1.40		14.93	6.89	0.49	15.61	83.90	8.02	10.06		2.04	16.69	14.34	0.10	5.07
177-1090B	177-1090B-26X-7,31-33	242.5	254.5	33880	240	4.01	10860	3.61	72.23	1.10		15.20	9.25		13.45	86.55	15.63	19.96		4.33	26.02	15.40	0.00	3.49
177-1090B	177-1090B-27X-1,32.5-34.5	243.2	255.2	33890	1570	15.18	12190	4.48	70.51	1.11		15.76	10.56	15.22	13.45	71.33	26.37	34.00		7.64	43.90	17.58	2.53	3.49
177-1090B	177-1090B-27X-1,78-80	243.7	255.7	33910	2280	21.98	11500	3.64	68.65	1.19		17.38	9.75	21.60	13.74	64.65	24.33	31.14		6.81	40.50	16.23	3.60	3.57
177-1090B	177-1090B-27X-1,132.5-134.5	244.2	256.2	33920	1230	15.38	9810	3.28	69.08	1.29	reruns with low HF:HNO3 digestion method	18.65	7.92	10.22	12.43	77.35	15.43	20.24	22.38	4.80	28.61	14.68	1.89	3.60
177-1090B	177-1090B-27X-2,32-34	244.7	256.7	33930	1140	14.10	8630	2.37	59.50	0.90	reruns with low HF:HNO3 digestion method	15.11	7.31	10.16	14.75	75.08	21.11	28.72	22.28	7.62	39.13	13.55	1.88	4.27
177-1090B	177-1090B-27X-2,82-84	245.2	257.2	33950	2720	17.65	6960	1.19	23.43	0.50	reruns with low HF:HNO3 digestion method	21.29	6.23	30.18	14.02	55.81	15.16	21.83	11.39	6.67	28.12	11.55	5.59	4.05
177-1090B	177-1090B-27X-2,133-135	245.7	257.7	33960	2380	19.87	9470	2.19	50.74	0.89	reruns with low HF:HNO3 digestion method	17.48	8.17	24.07	14.80	61.14	16.29	22.51	21.53	6.23	35.74	17.93	5.28	5.07
177-1090B	177-1090B-27X-3,31.5-33.5	246.2	258.2	33970	2050	20.10	10800	2.65	71.38	1.90	reruns with low HF:HNO3 digestion method	26.55	8.02	21.46	13.85	64.70	23.17	28.06	31.79	4.89	50.84	17.60	4.71	4.74
177-1090B	177-1090B-27X-3,82-84	246.7	258.7	33990	1540	15.21	11660	3.23	84.10	1.59	reruns with low HF:HNO3 digestion method	18.88	9.33	13.26	9.60	77.13	16.63	21.64	29.16	5.01	36.50	20.48	2.91	3.29
177-1090B	177-1090B-27X-3,133-135	247.2	259.2	34000	4020	22.92	7840	1.95	56.61	1.31	reruns with low HF:HNO3 digestion method	23.22	5.90	44.03	13.66	42.31	15.96	21.23	21.34	5.27	35.02	12.95	9.66	4.68
177-1090B	177-1090B-27X-4,31.5-33.5	247.7	259.7	34010	1290	15.98	9340	2.88	95.97	2.13	reruns with low HF:HNO3 digestion method	22.19	6.21	11.15	12.28	76.57	12.79	19.39	29.72	6.60	28.08	13.63	2.45	4.20
177-1090B	177-1090B-27X-4,82-84	248.2	260.2	34030	1390	13.74	9030	2.93	90.72	2.32	reruns with low HF:HNO3 digestion method	25.56	5.62	12.37	11.45	76.18	24.23	33.49	30.81	9.26	53.18	12.33	2.72	3.92
177-1090B	177-1090B-27X-4,133.5-135.5	248.7	260.7	34040	1480	15.21	9310	3.26	85.46	2.50	reruns with low HF:HNO3 digestion method	29.25	5.64	13.38	8.79	77.82	30.83	41.77	36.40	10.94	66.49	12.16	2.89	2.96
177-1090B	177-1090B-27X-5,31-33	249.2	261.2	34050	1640	16.06	10530	2.47	71.52	1.46	reruns with low HF:HNO3 digestion method	20.44	8.39	15.18	12.05	72.77	32.24	39.41	33.06	7.17	69.54	18.09	3.27	4.05
177-1090B	177-1090B-27X-5,80-82	249.7	261.7	34070	1240	17.09	10860	3.30	83.07	1.69	reruns with low HF:HNO3 digestion method	20.36	8.38	10.35	10.90	78.76	30.84	37.49	35.78	6.65	66.52	18.07	2.23	3.67
177-1090B	177-1090B-27X-5,132-134	250.2	262.2	34080	3090	24.97	10650	2.16	50.70	1.47	reruns with low HF:HNO3 digestion method	29.07	8.48	31.71	11.48	56.81	25.84	35.44	32.94	9.60	55.73	18.29	6.84	3.86
177-1090B	177-1090B-27X-6,32-34	250.7	262.7	34090	1760	18.74	9200	3.14	81.41	1.84	reruns with low HF:HNO3 digestion method	22.65	6.49	15.00	11.84	73.16	38.06	54.68	44.54	16.62	82.08	14.00	3.24	3.98
177-1090B	177-1090B-27X-6,82-84	251.2	263.2	34110	2960	27.22	9370	2.85	85.37	1.43	reruns with low HF:HNO3 digestion method	16.69	7.27	25.45	10.97	63.58	24.46	32.78	35.17	8.32	52.75	15.69	5.49	3.69
177-1090B	177-1090B-28X-1,32-34	252.9	264.9	34150	1350	14.48	8980	2.75	94.10	1.64	reruns with low HF:HNO3 digestion method	17.41	6.57	10.58	14.47	74.95	26.44	36.60	35.26	10.16	57.02	14.17	2.28	4.87
177-1090B	177-1090B-28X-1,82-84	253.4	265.4	34160	1520	17.92	10370	2.59	76.41	1.30	reruns with low HF:HNO3 digestion method	17.03	8.46	12.35	17.19	70.46	18.63	26.36	27.43	7.72	40.19	18.25	2.66	5.78
177-1090B	177-1090B-28X-1,134-136	253.9	265.9	34180	2140	20.38	8800	2.37	68.62	1.25	reruns with low HF:HNO3 digestion method	18.27	6.96	18.07	17.40	64.53	20.59	27.28	26.09	6.69	44.40	15.01	3.90	5.86
177-1090B	177-1090B-28X-2,31.5-33.5	254.4	266.4	34190	1840	20.74	9500	2.68	76.66	1.30	reruns with low HF:HNO3 digestion method	16.97	7.58	15.37	13.68	70.95	23.50	31.29	33.30	7.79	50.68	16.35	3.31	4.60
177-1090B	177-1090B-28X-2,82-84	254.9	266.9	34200	2140	21.49	9170	2.81	73.48	1.48	reruns with low HF:HNO3 digestion method	20.19	6.99	18.45	13.20	68.35	29.09	37.53	33.65	8.44	62.75	15.07	3.98	4.44
177-1090B	177-1090B-28X-2,134-136	255.4	267.4	34220	1040	16.46	7980	3.18	85.23	1.46	reruns with low HF:HNO3 digestion method	17.14	5.84	8.13	16.91	74.96	33.05	41.17	40.09	8.11	71.29	12.59	1.75	5.69
177-1090B	177-1090B-28X-3,31.5-33.5	255.9	267.9	34230	3790	32.14	7050	1.81	49.48	1.01	reruns with low HF:HNO3 digestion method	20.47	5.57	36.34	12.61	51.05	19.35	24.33	24.76	4.98	41.74	12.00	7.84	4.24
177-1090B	177-1090B-28X-3,81-83	256.4	268.4	34240	1290	14.00	5330	1.40	35.43	0.63	reruns with low HF:HNO3 digestion method	17.74	4.40	12.13	23.90	63.98	10.10	13.41	14.67	3.31	21.79	9.49	2.62	8.04
177-1090B	177-1090B-28X-3,134-136	256.9	268.9	34260	3560	25.20	8310	2.14	39.36	0.80	reruns with low HF:HNO3 digestion method	20.24	7.14	30.69	16.31	53.00	12.16	15.88	16.36	3.71	26.24	15.40	6.62	5.49
177-1090B	177-1090B-28X-4,32-34	257.4	269.4	34270	1530	10.78	6390	1.81	44.44	0.75	reruns with low HF:HNO3 digestion method	16.92	5.28	14.18	22.92	62.90	10.59	15.21	15.84	4.62	22.85	11.39	3.06	7.71
177-1090B	177-1090B-28X-4,82-84	257.9	269.9	34280	1320	5.14	3230	1.19	25.80	0.46	reruns with low HF:HNO3 digestion method	17.74	2.55	11.21	25.31	63.47	5.47	7.54	9.86	2.07	11.80	5.51	2.42	8.52
177-1090B	177-1090B-28X-4,134-136	258.4	270.4	34300	3280	25.41	7030	3.32	44.18	0.94	reruns with low HF:HNO3 digestion method	21.26	5.65	31.02	14.86	54.13	17.82	22.26	21.16	4.44	27.64	8.76	4.81	3.60
177-1090B	177-1090B-28X-5,32-34	258.9	270.9	34310	1830	16.88	6450	2.64	47.76	0.86	reruns with low HF:HNO3 digestion method	17.90	5.19	18.01	11.32	70.67	16.60	21.01	21.97	4.41	25.75	8.05	2.79	2.74
177-1090B	177-1090B-28X-5,82-84	259.4	271.4	34320	2950	23.24	6540	2.17	42.46	0.74	reruns with low HF:HNO3 digestion method	17.40	5.46	28.51	15.63	55.86	10.14	12.99	14.71	2.85	15.73	8.47	4.42	3.78
177-1090B	177-1090B-28X-5,134-136	259.9	271.9	34340	2310	23.54	7700	3.79	62.95	1.14	reruns with low HF:HNO3 digestion method	18.10	6.03	20.04	19.60	60.36	18.10	23.40	24.18	5.30	28.08	9.35	3.11	4.74
177-1090B	177-1090B-28X-6,31.5-33.5	260.4	272.4	34350	2440	24.19	8420	3.53	58.29	1.05	reruns with low HF:HNO3 digestion method	18.08	6.87	24.34	14.66	61.00	14.85	21.34	23.97	6.49	23.04	10.66	3.78	3.55
177-1090B	177-1090B-28X-6,81-83	260.9	272.9	34360	1260	11.87	8140	3.02	63.65	1.09	reruns with low HF:HNO3 digestion method	17.09	6.54	10.63	21.00	68.37	18.49	24.85	20.13	6.36	28.69	10.15	1.65	5.08
177-1090B	177-1090B-28X-6,133-135	261.4	273.4	34380	1190	12.52	7330	3.87	71.90	1.43	reruns with low HF:HNO3 digestion method	19.84	5.23	9.92	13.50	76.57	21.29	28.70	25.07	7.41	33.02	8.12	1.54	3.27
177-1090B	177-1090B-28X-7,32-34	261.9	273.9	34390	620	5.52	3770	1.96	35.20	0.74	reruns with low HF:HNO3 digestion method	20.88	2.69	5.43	17.75	76.82	13.77	17.20	13.99	3.43	21.36	4.17	0.84	4.30
177-1090B	177-1090B-29X-1,32-34	262.6	274.6	34410	1730	11.86	6110	2.57	40.53	0.84	reruns with low HF:HNO3 digestion method	20.64	4.88	15.98	14.27	69.74	9.27	11.85	12.33	2.58	12.62	6.65	2.18	3.03
177-1090B	177-1090B-29X-1,82-84	263.1	275.1	34420	1830	17.05	7400	3.77	42.07	0.85	reruns with low HF:HNO3 digestion method	20.15	6.16	15.10	16.43	68.46	11.69	14.40	14.24	2.71	19.02	10.02	2.46	4.17
177-1090B	177-1090B-29X-1,134-136	263.6	275.6	34430	1200	9.29	6690	3.31	44.07	0.91	reruns with low HF:HNO3 digestion method	20.56	5.36	11.16	14.72	74.12	12.37	15.58	15.33	3.22	20.12	8.72	1.82	3.74
177-1090B	177-1090B-29X-2,33-35	264.1	276.1	34450	1340	10.50	6170	3.29	45.49	0.92	reruns with low HF:HNO3 digestion method	20.27	4.81	12.46	11.26	76.28	12.37	15.34	14.38	2.97	20.13	7.83	2.03	2.86
177-1090B	177-1090B-29X-2,82-84	264.6	276.6	34460	1320	8.88	6580	2.62	38.96	0.81	reruns with low HF:HNO3 digestion method	20.86	5.38	12.28	13.27	74.44	9.86	12.53	12.94	2.67	16.05	8.76	2.00	3.37
177-1090B	177-1090B-29X-2,134-136	265.1	277.1	34470	1000	5.41	4930	2.54	27.47	0.59	reruns with low HF:HNO3 digestion method	21.59	4.06	9.44	23.26	67.30	8.45	10.84	10.23	2.40	13.74	6.61	1.54	5.90
177-1090B	177-1090B-29X-3,32-34	265.6	277.6	34490	210	1.54	1170	1.54	13.11	0.27	reruns with low HF:HNO3 digestion method	20.84	0.77	1.15	24.02	74.84	7.24	8.28	6.75	1.04	8.76	0.93	0.14	4.54
177-1090B	177-1090B-29X-3,82-84	266.1	278.1	34500	880	5.39	5570	2.41	44.08	0.91	reruns with low HF:HNO3 digestion method	20.70	4.23	7.58	17.68	74.74	10.25	14.13	13.93	3.87	12.42	5.12	0.92	3.34
177-1090B	177-1090B-29X-3,125.5-127.5	266.6	278.6	34510	1090	6.39	6550	2.73	49.39	0.92	reruns with low HF:HNO3 digestion method	18.62	5.19	8.92	17.96	73.13	9.70	13.70	13.84	4.00	11.74	6.29	1.08	3.39
177-1090B	177-1090B-29X-4,32-34	267.1	279.1	34530	1540	15.03	5060	2.50	33.23	0.64	reruns with low HF:HNO3 digestion method	19.23	4.12	14.55	14.35	71.09	11.52	14.31	13.54	2.79	13.95	4.99	1.76	2.71
177-1090B	177-1090B-29X-4,82-84	267.6	279.6	34540	1970	17.87	4730	2.12	28.07	0.55	reruns with low HF:HNO3 digestion method	19.73	3.92	16.72	14.16	69.12	7.97	9.94	10.19	1.97	9.65	4.74	2.02	2.68
177-1090B	177-1090B-29X-4,125-127	268.1	280.0	34550	2990	35.60	6010	2.46	31.05	0.60	reruns with low HF:HNO3 digestion method	19.31	5.12	26.46	12.98	60.56	9.32	11.68	12.54	2.36	11.29	6.20	3.20	2.45
177-1090B	177-1090B-29X-5,32-34	268.6	280.6	34570	1290	12.75	6310	2.36	41.71	0.81	reruns with low HF:HNO3 digestion method	19.30	5.12	10.98	17.32	71.71	10.56	14.09	14.30	3.54	12.78	6.20	1.33	3.27
177-1090B	177-1090B-29X-5,84-86	269.1	281.1	34580	1610	13.78	5350	2.28	40.74	0.80	reruns with low HF:HNO3 digestion method	19.55	4.18	13.64	10.28	76.08	8.00	10.86	11.47	2.86	9.69	5.06	1.65	1.94
177-1090B	177-1090B-29X-5,134-136	269.6	281.6	34590	1990	12.39	5610	2.69	38.31	0.76	reruns with low HF:HNO3 digestion method	19.76	4.50	17.04	15.20	67.75	11.48	14.44	13.81	2.95	17.38	6.81	2.58	3.59
177-1090B	177-1090B-29X-6,31-33	270.1	282.1	34600	1090	7.16	2850	1.97	18.04	0.39	reruns with low HF:HNO3 digestion method	21.66	2.28	10.03	26.09	63.88	11.29	12.79	10.03	1.50	17.09	3.45	1.52	6.16
177-1090B	177-1090B-29X-6,82-84	270.6	282.6	34620	1590	15.45	6110	2.47	37.71	0.76	reruns with low HF:HNO3 digestion method	20.27	4.99	13.51	15.63	70.86	10.15	12.40	12.32	2.24	15.37	7.55	2.05	3.69
177-1090B	177-1090B-29X-6,134-136	271.1	283.1	34630	2350	19.75	4260	1.94	21.31	0.51	reruns with low HF:HNO3 digestion method	23.91	3.51	21.13	18.50	60.38	9.49	10.69	10.89	1.19	14.37	5.31	3.20	4.37
177-1090B	177-1090B-29X-7,34-36	271.6	283.6	34650	910	7.78	3480	1.51	22.96	0.51	reruns with low HF:HNO3 digestion method	22.18	2.73	7.46	18.48	74.06	7.38	8.93	8.72	1.55	11.16	4.13	1.13	4.36
177-1090B	177-1090B-30X-1,61-63	272.6	284.6	34710	2380	24.95	4250	1.38	20.30	0.48	reruns with low HF:HNO3 digestion method	23.51	3.55	21.82	17.45	60.73	6.10	7.88	8.28	1.78	2.57	1.49	0.92	1.15
177-1090B	177-1090B-30X-2,61-63	274.1	286.1	34850	2270	25.47	5370	1.57	24.12	0.55	reruns with low HF:HNO3 digestion method	22.65	4.57	20.72	24.90	54.38	7.24	8.98	8.94	1.75	4.27	2.69	1.22	2.29
177-1090B	177-1090B-30X-3,62.5-64.5	275.6	287.6	35060	1840	13.82	4340	1.55	30.22	0.71	reruns with low HF:HNO3 digestion method	23.45	3.30	16.69	23.63	59.68	6.42	8.40	7.94	1.98	1.34	0.69	0.35	0.77
177-1090B	177-1090B-30X-4,63-65	277.1	289.1	35350	4520	32.90	5540	1.90	40.29	0.72	reruns with low HF:HNO3 digestion method	17.97	4.48	40.05	15.31	44.64	10.00	13.31	11.71	3.32	10.33	4.62	4.14	2.47
177-1090B	177-1090B-30X-5,62-64	278.6	290.6	35410	4020	42.09	3950	1.50	21.88	0.47	reruns with low HF:HNO3 digestion method	21.64	3.25	46.86	13.44	39.70	9.47	11.67	9.32	2.20	9.78	3.36	4.84	2.17
177-1090B	177-1090B-30X-6,62.5-64.5	280.1	292.1	35470	2110	26.88	6950	3.13	78.19	1.51	reruns with low HF:HNO3 digestion method	19.26	4.73	17.07	9.71	73.22	21.33	28.08	21.23	6.74	26.23	5.82	2.10	1.86
177-1090B	177-1090B-30X-7,46-48	281.5	293.5	35520	3690	42.18	5640	1.84	48.57	0.93	reruns with low HF:HNO3 digestion method	19.06	4.28	34.39	11.14	54.47	14.06	18.75	17.60	4.69	12.44	3.79	3.04	1.54
177-1090B	177-1090B-31X-1,62.5-64.5	282.3	294.3	35580	840	12.30	6760	1.72	52.09	0.95	reruns with low HF:HNO3 digestion method	18.28	5.36	6.23	18.09	75.68	10.92	16.46	15.72	5.54	6.18	3.03	0.35	1.60
177-1090B	177-1090B-31X-2,63.5-65.5	283.8	295.8	35670	3440	30.56	7020	1.42	48.59	0.91	reruns with low HF:HNO3 digestion method	18.69	5.68	32.17	12.52	55.31	11.85	16.29	15.24	4.44	6.71	3.22	1.82	1.11
177-1090B	177-1090B-31X-3,63-65	285.3	297.3	35750	3850	37.17	6940	1.92	36.85	0.91	reruns with low HF:HNO3 digestion method	24.83	5.59	37.08	11.79	51.14	10.69	14.02	14.08	3.33	7.62	3.99	2.65	1.31
177-1090B	177-1090B-31X-4,62-64	286.8	298.8	35830	1250	22.19	7990	3.35	79.27	1.47	reruns with low HF:HNO3 digestion method	18.61	5.83	9.43	15.25	75.32	28.94	36.20	32.08	7.25	34.99	7.04	1.14	2.88
177-1090B	177-1090B-31X-5,61.5-63.5	288.3	300.3	35900	3010	24.69	6010	2.38	56.65	1.11	reruns with low HF:HNO3 digestion method	19.58	4.38	27.89	9.26	62.85	35.58	50.95	42.03	15.37	36.67	4.52	2.87	1.49
177-1090B	177-1090B-31X-6,62-64	289.8	301.8	35980	3370	25.62	6580	1.52	44.68	0.83	reruns with low HF:HNO3 digestion method	18.61	5.36	33.39	15.05	51.56	12.58	16.93	15.97	4.35	12.96	5.53	3.44	2.42
177-1090B	177-1090B-31X- CC,13.5-15.5	291.4	303.4	36060	950	19.69	8320	1.61	37.58	0.88	reruns with low HF:HNO3 digestion method	23.50	7.02	7.40	19.27	73.32	16.52	19.84	18.31	3.31	17.03	7.23	0.76	3.10
177-1090B	177-1090B-32X-1,61.5-63.5	292.0	304.0	36090	1090	18.29	9390	3.37	57.71	1.45	reruns with low HF:HNO3 digestion method	25.07	7.26	8.57	16.72	74.71	21.50	26.21	25.01	4.71	22.16	7.48	0.88	2.69
177-1090B	177-1090B-32X-2,60.5-62.5	293.5	305.5	36160	1500	35.41	9140	1.68	30.03	0.69	reruns with low HF:HNO3 digestion method	23.05	8.12	13.93	30.43	55.64	10.45	12.58	13.04	2.13	10.77	8.37	1.44	4.89
177-1090B	177-1090B-33X-1,63-65	295.5	307.5	36270	490	26.63	9390	3.85	88.39	1.40	reruns with low HF:HNO3 digestion method	15.87	7.33	43.62	10.20	46.18	28.26	38.79	33.01	10.52	29.12	7.55	4.49	1.64
177-1090B	177-1090B-33X-2,63-65	296.4	308.4	36310	720	15.56	7900	3.22	81.12	1.28	reruns with low HF:HNO3 digestion method	15.73	6.02	1.59	17.93	80.48	29.65	36.95	32.70	7.30	30.55	6.21	0.16	2.88
177-1090B	177-1090B-33X- CC,44-46	297.7	309.7	36360	760	12.61	8410	3.02	82.91	1.26	reruns with low HF:HNO3 digestion method	15.24	6.55	4.89	12.19	82.92	16.45	23.38	19.41	6.93	33.35	13.28	0.99	3.86
177-1090B	177-1090B-34X-1,62.5-64.5	301.7	313.7	36460	470	8.18	7720	4.22		1.47	reruns with low HF:HNO3 digestion method		5.56	1.00	20.55	78.45	31.07	40.43	34.27	9.36	62.99	11.27	0.20	6.50
177-1090B	177-1090B-34X-2,62-64	303.2	315.2	36500	690	24.80	6600	2.43	77.02	1.19	reruns with low HF:HNO3 digestion method	15.48	4.85	4.24	13.51	82.25	19.25	23.91	21.14	4.65	39.03	9.82	0.86	4.27
177-1090B	177-1090B-34X-3,62.5-64.5	304.7	316.7	36540	670	38.19	6930	2.68	95.17	1.35	reruns with low HF:HNO3 digestion method	14.15	4.95	3.51	17.49	79.00	27.16	35.27	31.12	8.11	55.06	10.04	0.71	5.53
177-1090B	177-1090B-34X-4,62-64	306.2	318.2	36580	340	21.94	6790	2.48	84.63	1.19	reruns with low HF:HNO3 digestion method	14.09	5.04	0.62	25.21	74.18	13.05	18.77	18.17	5.72	26.46	10.21	0.13	7.97
177-1090B	177-1090B-34X-5,62-64	307.7	319.7	36620	810	20.39	6320	2.70	94.98	1.42	reruns with low HF:HNO3 digestion method	14.91	4.24	4.99	18.75	76.26	19.37	25.45	22.61	6.09	39.27		1.01	5.93
177-1090B	177-1090B-34X-6,62.5-64.5	309.2	321.2	36680	1360	16.63	5030	1.98	44.93	0.89	reruns with low HF:HNO3 digestion method	19.74	3.72	11.49	17.57	70.94	10.11	13.01	12.63	2.89	12.42	4.57	1.41	3.37
177-1090B	177-1090B-34X- CC,12-14	310.7	322.7	36740	2520	26.59	6670	2.13	71.89	1.22	reruns with low HF:HNO3 digestion method	17.03	4.87	22.54	15.95	61.51	18.09	23.20	19.48	5.11	22.23	5.98	2.77	3.06
177-1090B	177-1090B-35X-1,62-64	311.4	323.4	36770	2570	31.18	5950	2.08	72.06	1.23	reruns with low HF:HNO3 digestion method	17.01	4.15	23.62	12.74	63.64	17.85	22.81	19.44	4.96	21.93	5.09	2.90	2.44
177-1090B	177-1090B-35X-2,63-65	312.9	324.9	36830	2170	25.84	6610	2.69	88.29	1.29	reruns with low HF:HNO3 digestion method	14.58	4.72	16.03	16.44	67.54	17.34	22.01	26.19	4.67	21.30	5.79	1.97	3.15
177-1090B	177-1090B-35X-3,62-64	314.4	326.4	36900	5290	35.62	3930	1.63	55.42	0.90	reruns with low HF:HNO3 digestion method	16.29	2.61	45.53	10.06	44.41	26.32	30.38	17.55	4.06	32.34	3.20	5.59	1.93
177-1090B	177-1090B-35X-4,63-65	315.9	327.9	36960	5040	34.72	3920	1.75	57.80	1.02	reruns with low HF:HNO3 digestion method	17.65					27.43	32.35	19.95	4.92	33.70
177-1090B	177-1090B-35X-5,62-64	317.4	329.4	37020	6130	34.81	3070	1.34	32.83	0.72	reruns with low HF:HNO3 digestion method	21.81	2.01	55.46	7.33	37.21	26.36	28.71	16.14	2.35	32.38	2.47	6.81	1.41
177-1090B	177-1090B-35X-6,62-64	318.9	330.9	37090	5920	37.06	2490	1.79	42.20	0.85	reruns with low HF:HNO3 digestion method	20.23	1.23	38.22	7.79	54.00	10.12	12.90	16.06	2.78	12.43	1.52	4.69	1.49
177-1090B	177-1090B-36X-1,61-63	321.0	333.0	37180	5710	31.91	3990	2.62	65.33	1.23	reruns with low HF:HNO3 digestion method	18.85	2.18	22.28	9.67	68.05	11.87	15.82	20.13	3.95	14.58	2.67	2.74	1.85
177-1090B	177-1090B-36X-2,63-65	322.5	334.5	37240	5490	27.15	6840	3.03	78.86	1.42	reruns with low HF:HNO3 digestion method	17.97	4.75	12.60	13.12	74.28	17.96	23.58	25.69	5.62	22.06	5.84	1.55	2.51
177-1090B	177-1090B-36X-3,62-64	324.0	336.0	37300	5280	25.35	7020	3.14	82.82	1.49	reruns with low HF:HNO3 digestion method	18.04	4.82	7.18	16.15	76.67	18.77	23.49	25.41	4.71	23.07	5.92	0.88	3.09
177-1090B	177-1090B-36X-4,62-64	325.5	337.5	37370	5070	26.38	6060	3.35	94.53	1.61	reruns with low HF:HNO3 digestion method	17.03	3.69	26.59	15.49	57.92	22.43	28.18	29.10	5.75	27.55	4.54	3.27	2.97
177-1090B	177-1090B-36X-5,61-63	327.0	339.0	37430	4850	35.49	5000	2.41	78.11	1.37	reruns with low HF:HNO3 digestion method	17.60	2.97	12.63	10.18	77.19	16.03	20.64	23.81	4.61	19.69	3.65	1.55	1.95
177-1090B	177-1090B-36X-6,61.5-63.5	328.5	340.5	37510	4640	30.69	6450	2.78	85.91	1.68	reruns with low HF:HNO3 digestion method	19.60	3.97	12.23	15.88	71.89	20.45	25.31	27.81	4.86	16.24	3.16	0.97	1.97
177-1090B	177-1090B-36X- CC,11.5-13.5	330.0	342.0	37600	4430	32.63	7500	3.67	93.86	1.69	reruns with low HF:HNO3 digestion method	17.98	5.02	41.61	9.95	48.44	27.58	33.49	33.75	5.91	21.89	3.99	3.30	1.23
177-1090B	177-1090B-37X-1,62.5-64.5	330.6	342.6	37700	4210	34.93	4920	2.34	57.51	1.04	reruns with low HF:HNO3 digestion method	18.06	3.39	31.05	8.52	60.43	16.94	21.58	23.57	4.64	5.42	1.08	0.99	0.42
177-1090B	177-1090B-37X-2,62-64	332.1	344.1	37880	4000	37.16	6520	2.69	64.08	1.30	reruns with low HF:HNO3 digestion method	20.26	4.61	19.52	9.87	70.61	25.27	30.49	31.32	5.22	27.38	5.00	2.11	1.67
177-1090B	177-1090B-37X-3,62-64	333.6	345.6	37990	3790	27.40	7710	2.82	69.26	1.32	reruns with low HF:HNO3 digestion method	19.08	5.77	66.65	13.77	19.58	22.98	28.59	27.89	5.61	24.89	6.25	7.22	2.33
177-1090B	177-1090B-37X-4,61-63	335.1	347.1	38150	3570	30.80	5080	1.25	30.65	0.62	reruns with low HF:HNO3 digestion method	20.32	4.17	66.21	4.01	29.77	11.24	13.72	15.66	2.48	12.17	4.51	7.17	0.68
177-1090B	177-1090B-37X-5,63-65	336.6	348.6	38320	3360	39.97	5170	1.51	35.53	0.74	reruns with low HF:HNO3 digestion method	20.84	4.09	17.89	2.63	79.48	10.36	13.21	15.18	2.86	11.22	4.43	1.94	0.45
177-1090B	177-1090B-38X-2,61.5-63.5	341.7	353.7	38880	3150	33.04	6140	3.63	111.37	2.00	reruns with low HF:HNO3 digestion method	17.99	3.19	40.65	2.02	57.34	36.91	45.69	49.44	8.78	39.98	3.46	4.40	0.34
177-1090B	177-1090B-38X-3,61.5-63.5	343.2	355.2	39040	2930	36.56	7190	2.06	70.00	1.37	reruns with low HF:HNO3 digestion method	19.59	5.17	16.17	2.90	80.93	32.07	39.31	33.89	7.24	34.74	5.60	1.75	0.49
177-1090B	177-1090B-38X-4,61.5-63.5	344.7	356.7	39210	2720	33.73	4590	2.90	91.02	1.81	reruns with low HF:HNO3 digestion method	19.90	1.92	73.98	1.44	24.59	41.07	46.34	46.04	5.27	44.49	2.08	8.01	0.24
177-1090B	177-1090B-38X-5,61.5-63.5	346.2	358.2	39370	2510	28.94	3880	0.66	18.47	0.40	reruns with low HF:HNO3 digestion method	21.75	3.29	73.63	1.55	24.81	9.62	10.80	13.06	1.18	10.41	3.56	7.98	0.26
177-1090B	177-1090B-38X-6,62-64	347.7	359.7	39540	2290	27.89	3360	0.73	18.46	0.45	reruns with low HF:HNO3 digestion method	24.31	2.70	35.10	1.49	63.41	11.42	12.69	17.58	1.27	12.37	2.93	3.80	0.25
177-1090B	177-1090B-38X- CC,6-8	349.1	361.1	39690	2080	31.64	3870	2.71	71.49	1.52	reruns with low HF:HNO3 digestion method	21.20	1.64	9.62	1.86	88.53	28.74	36.48	41.62	7.74	31.13	1.77	1.04	0.31
177-1090B	177-1090B-39X-1,62-64	349.8	361.8	39770	1870	39.91	5100	3.68	77.37	1.95	reruns with low HF:HNO3 digestion method	25.16	2.24		1.72		114.39	170.25	144.39	55.87	123.90	2.43		0.29
177-1090B	177-1090B-39X-2,60-62	351.3	363.3	39930	1650	111.72	2880	3.84	83.23	2.29	reruns with low HF:HNO3 digestion method	27.47	-0.48	1.51	0.81	97.68	53.68	58.35	72.30	4.67	58.15		0.16	0.14
177-1090B	177-1090B-39X-3,59-61	352.8	364.8	40090	1440	69.44	6920	3.44	83.30	2.11	reruns with low HF:HNO3 digestion method	25.34	3.82	1.48	0.79	97.73	41.15	44.74	49.33	3.59	44.58	4.13	0.16	0.13
177-1090B	177-1090B-39X-4,59-61	354.3	366.3	40260	1230	45.44	3730	3.10	83.31	2.11	reruns with low HF:HNO3 digestion method	25.31	0.63	17.01	0.09	82.89	29.57	33.33	35.71	3.76	32.03	0.68	1.84	0.02
177-1090B	177-1090B-39X-5,60-62	355.8	367.8	40420	1010	34.26	2730	2.92	72.16	2.06	reruns with low HF:HNO3 digestion method	28.48	-0.29	1.84	1.73	96.43	52.02	58.36	63.06	6.34	56.35		0.20	0.29
177-1090B	177-1090B-39X-6,60-62	357.3	369.3	40590	800	85.94	4470	3.80	79.42	2.30	reruns with low HF:HNO3 digestion method	29.00	1.09	0.34	1.09	98.57	45.94	50.10	58.48	4.16	49.76	1.18	7.63	0.18