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Kasemann, Simone A; Pogge von Strandmann, Philip A E; Prave, Anthony R; Fallick, Anthony E; Elliott, Tim; Hoffmann, Karl-Heinz (2014): (Table 1) Boron, carbon, magnesium and calcium isotope data, post-Marinoan Neoproterozoic carbonate sections, Namibia [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.833928, Supplement to: Kasemann, SA et al. (2014): Continental weathering following a Cryogenian glaciation: Evidence from calcium and magnesium isotopes. Earth and Planetary Science Letters, 396, 66-77, https://doi.org/10.1016/j.epsl.2014.03.048

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Abstract:
A marked ocean acidification event and elevated atmospheric carbon dioxide concentrations following the extreme environmental conditions of the younger Cryogenian glaciation have been inferred from boron isotope measurements. Calcium and magnesium isotope analyses offer additional insights into the processes occurring during this time. Data from Neoproterozoic sections in Namibia indicate that following the end of glaciation the continental weathering flux transitioned from being of mixed carbonate and silicate character to a silicate-dominated one. Combined with the effects of primary dolomite formation in the cap dolostones, this caused the ocean to depart from a state of acidification and return to higher pH after climatic amelioration. Differences in the magnitude of stratigraphic isotopic changes across the continental margin of the southern Congo craton shelf point to local influences modifying and amplifying the global signal, which need to be considered in order to avoid overestimation of the worldwide chemical weathering flux.
Related to:
Kasemann, Simone A; Hawkesworth, Chris J; Prave, Anthony R; Fallick, Anthony E; Pearson, Paul N (2005): Boron and calcium isotope composition in Neoproterozoic carbonate rocks from Namibia: evidence for extreme environmental change. Earth and Planetary Science Letters, 231(1-2), 73-86, https://doi.org/10.1016/j.epsl.2004.12.006
Kasemann, Simone A; Prave, Anthony R; Fallick, Anthony E; Hawkesworth, Chris J; Hoffmann, Karl-Heinz (2010): Neoproterozoic ice ages, boron isotopes, and ocean acidification: Implications for a snowball Earth. Geology, 38(9), 775-778, https://doi.org/10.1130/G30851.1
Coverage:
Median Latitude: -19.586229 * Median Longitude: 14.336760 * South-bound Latitude: -20.199167 * West-bound Longitude: 13.995608 * North-bound Latitude: -19.256564 * East-bound Longitude: 15.016164
Minimum SECTION, height: 0.0 m * Maximum SECTION, height: 300.3 m
Event(s):
Fransfontein  * Latitude: -20.199167 * Longitude: 15.016164 * Location: NW Namibia * Method/Device: Profile sampling (PROFILE)
Khowarib  * Latitude: -19.302956 * Longitude: 13.995608 * Location: NW Namibia * Method/Device: Profile sampling (PROFILE)
Ombaatjie  * Latitude: -19.256564 * Longitude: 13.998508 * Location: NW Namibia * Method/Device: Profile sampling (PROFILE)
Comment:
SECTION, height [m]: heights are meters above base of cap carbonate.
#: uncertainty for Ca isotope data is ± 0.2 per mil 2 Sigma; uncertainties for Mg isotope data are valid for the last digits (2 Sigma).
+: C, O and B isotope data taken from Kasemann et al., (2005, 2010).
Ombaatjie: Ca isotope data taken from Kasemann et al., (2005).
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Event labelEvent
Lithologic unit/sequenceUnitKasemann, Simone A
Lithology/composition/faciesLithologyKasemann, Simone A
Sample code/labelSample labelKasemann, Simone A
SECTION, heightSectionmGeocode
δ13C, carbonateδ13C carb‰ PDBKasemann, Simone A+
δ18O, carbonateδ18O carb‰ PDBKasemann, Simone A
δ11Bδ11B‰ SRMKasemann, Simone A+
δ44/40 Caδ44/40 Ca‰ SRM 915aKasemann, Simone AFinnigan TRITON thermal ionization mass spectrometer (TIMS)#
10 δ26Mgδ26MgKasemann, Simone A#
11 UncertaintyUncertainty±Kasemann, Simone A#
Size:
419 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Event

Unit

Lithology

Sample label

Section [m]

δ13C carb [‰ PDB]

δ18O carb [‰ PDB]

δ11B [‰ SRM]

δ44/40 Ca [‰ SRM 915a]
10 
δ26Mg []
11 
Uncertainty [±]
Fransfontein Elandshoek Fmmed-bd dolostoneFF1-46252.20.69-3.14-0.50.9
FransfonteinElandshoek Fmmed-bd dolostoneFF1-44207.22.17-5.17-2.135
FransfonteinElandshoek Fmmed-bd dolostoneFF1-41142.21.34-5.132.01.1
FransfonteinMaieberg Fmthin-bdd dolostoneFF1-40132.21.37-5.62-0.21.1
FransfonteinMaieberg Fmthin-bdd dolostoneFF1-39122.21.39-3.944.7-2.122
FransfonteinMaieberg Fmthin-bdd dolostoneFF1-37102.21.61-4.976.7-1.7811
FransfonteinMaieberg Fmthin-bdd dolostoneFF1-3692.21.57-0.914.51.3
FransfonteinMaieberg Fmthin-bdd dolostoneFF1-3472.21.52-1.462.01.1
FransfonteinMaieberg Fmthin-bdd dolostoneFF1-3252.20.58-5.32-1.00.8
FransfonteinMaieberg Fmthin-bdd dolostoneFF1-3148.2-0.34-6.86-4.30.8-1.813
FransfonteinMaieberg Fmthin-bdd limestoneFF1-3042.7-4.19-9.42-2.5
FransfonteinMaieberg Fmthin-bdd limestoneFF1-2942.0-4.37-9.73-2.00.8
FransfonteinMaieberg Fmthin-bdd limestoneFF1-2814.7-4.13-10.18-3.61.0-1.6910
FransfonteinKeilberg FmdolomicriteFF1-225.4-2.79-8.80-1.553
FransfonteinKeilberg FmdolomicriteFF1-204.6-3.25-8.27-3.5-1.765
FransfonteinKeilberg FmdolomicriteFF1-122.2-2.97-7.53-2.20.9-1.6111
FransfonteinKeilberg FmdolomicriteFF1-91.6-2.25-7.361.0-1.477
FransfonteinKeilberg FmdolomicriteFF1-61.0-2.60-7.29-2.6-1.453
FransfonteinKeilberg FmdolomicriteFF1-50.8-1.74-6.73-1.2-1.435
FransfonteinKeilberg FmdolomicriteFF1-40.6-2.17-7.25-0.51.1-1.6312
FransfonteinKeilberg FmdolomicriteFF1-30.4-1.82-6.991.21.1-1.6011
FransfonteinKeilberg FmdolomicriteFF1-20.2-1.56-6.983.01.1-1.5611
Khowarib Elandshoek Fmmed-bd dolostoneKW1-82300.3-1.49-7.416.50.5
KhowaribElandshoek Fmmed-bd dolostoneKW1-80264.3-2.57-6.214.50.6
KhowaribMaieberg Fmthin-bdd dolostoneKW1-79260.3-4.09-8.616.50.4
KhowaribMaieberg Fmthin-bdd dolostoneKW1-78245.3-3.60-5.945.0
KhowaribMaieberg Fmthin-bdd limestoneKW1-77225.3-3.63-8.106.8
KhowaribMaieberg Fmthin-bdd limestoneKW1-75185.3-4.18-8.590.2
KhowaribMaieberg Fmthin-bdd limestoneKW1-6780.3-5.19-9.522.50.7
KhowaribMaieberg Fmthin-bdd limestoneKW1-6457.3-5.24-9.593.20.5
KhowaribMaieberg Fmthin-bdd limestoneKW1-5831.3-5.24-9.050.20.5
KhowaribMaieberg Fmthin-bdd limestoneKW1-5521.3-5.13-8.562.20.6
KhowaribKeilberg FmdolomicriteKW1-4514.8-4.19-8.960.5
KhowaribKeilberg FmdolomicriteKW1-3710.8-3.25-6.89-1.2
KhowaribKeilberg FmdolomicriteKW1-328.3-3.03-7.55-0.10.6
KhowaribKeilberg FmdolomicriteKW1-296.8-2.77-7.472.70.3
KhowaribKeilberg FmdolomicriteKW1-244.3-2.98-7.731.5
KhowaribKeilberg FmdolomicriteKW1-212.7-2.90-7.622.00.7
KhowaribKeilberg FmdolomicriteKW1-181.4-3.07-7.731.70.4
KhowaribKeilberg FmdolomicriteKW1-181.4-3.10-7.701.50.7
KhowaribKeilberg FmdolomicriteKW1-150.83.5
KhowaribKeilberg FmdolomicriteKW1-140.6-2.96-7.212.80.5
KhowaribKeilberg FmdolomicriteKW1-120.2-3.23-6.093.2
KhowaribKeilberg FmdolomicriteKW1-110.1-3.17-7.346.70.2
KhowaribKeilberg FmdolomicriteKW1-100.0-3.21-7.449.70.4
Ombaatjie Elandshoekmed-bd dolostoneOBTJ 74241.0-1.94-6.13-0.51.1-1.527
OmbaatjieMaieberg Fmthin-bdd dolostoneOBTJ 70181.0-3.02-4.270.00.9-1.6115
OmbaatjieMaieberg Fmthin-bdd limestoneOBTJ 67126.0-4.31-8.570.20.6-1.694
OmbaatjieMaieberg Fmthin-bdd limestoneOBTJ 65106.0-4.08-8.93-0.20.4-1.9414
OmbaatjieMaieberg Fmthin-bdd limestoneOBTJ 5836.0-5.78-11.40-2.40.6-2.143
OmbaatjieKeilberg FmdolomicriteOBTJ 5510.5-3.87-8.50-6.00.8-2.046
OmbaatjieKeilberg FmdolomicriteOBTJ 525.6-3.04-6.82-6.20.9-1.509
OmbaatjieKeilberg FmdolomicriteOBTJ 472.5-3.01-6.87-4.81.0-1.4313
OmbaatjieKeilberg FmdolomicriteOBTJ 461.6-2.56-6.90-5.51.0
OmbaatjieKeilberg FmdolomicriteOBTJ 451.5-2.63-6.30-3.31.0-1.3911
OmbaatjieKeilberg FmdolomicriteOBTJ 430.11.66-4.602.71.1-1.787