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Croot, Peter L; Bowie, Andrew R; Frew, Russell; Maldonado, Maria T; Hall, Julie A; Safi, Karl A; La Roche, Julie; Boyd, Philip W; Law, Cliff S (2014): Dissolved iron and Fe(II) in an iron induced Southern Ocean phytoplankton bloom measured during TANGAROA cruise SOIREE [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.832530, Supplement to: Croot, PL et al. (2001): Retention of dissolved iron and Fe II in an iron induced Southern Ocean phytoplankton bloom. Geophysical Research Letters, 28(18), 3425-3428, https://doi.org/10.1029/2001GL013023

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Abstract:
During the 13 day Southern Ocean Iron RE-lease Experiment (SOIREE), dissolved iron concentrations decreased rapidly following each of three iron-enrichments, but remained high (>1 nM, up to 80% as FeII) after the fourth and final enrichment on day 8. The former trend was mainly due to dilution (spreading of iron-fertilized waters) and particle scavenging. The latter may only be explained by a joint production-maintenance mechanism; photoreduction is the only candidate process able to produce sufficiently high FeII, but as such levels persisted overnight (8 hr dark period) -ten times the half-life for this species- a maintenance mechanism (complexation of FeII) is required, and is supported by evidence of increased ligand concentrations on day 12. The source of these ligands and their affinity for FeII is not known. This retention of iron probably permitted the longevity of this bloom raising fundamental questions about iron cycling in HNLC (High Nitrate Low Chlorophyll) Polar waters.
Coverage:
Median Latitude: -60.984458 * Median Longitude: 140.018708 * South-bound Latitude: -61.123300 * West-bound Longitude: 139.230000 * North-bound Latitude: -60.900700 * East-bound Longitude: 140.645700
Date/Time Start: 1999-02-09T13:13:00 * Date/Time End: 1999-02-22T08:21:00
Minimum DEPTH, water: 40 m * Maximum DEPTH, water: 40 m
Event(s):
T1136-1  * Latitude: -60.978500 * Longitude: 139.230000 * Date/Time: 1999-02-09T13:13:00 * Location: Southern Ocean - Australasian-Pacific Sector * Campaign: SOIREE * Basis: Tangaroa * Method/Device: Go-Flo bottles (GOFLO) * Comment: OUT-patch of the iron-fertilized area
T1139-1  * Latitude: -60.987000 * Longitude: 139.463300 * Date/Time: 1999-02-10T17:48:00 * Location: Southern Ocean - Australasian-Pacific Sector * Campaign: SOIREE * Basis: Tangaroa * Method/Device: Go-Flo bottles (GOFLO) * Comment: IN-patch of the iron-fertilized area
T1140-6  * Latitude: -60.945800 * Longitude: 139.728200 * Date/Time: 1999-02-12T07:32:00 * Location: Southern Ocean - Australasian-Pacific Sector * Campaign: SOIREE * Basis: Tangaroa * Method/Device: Go-Flo bottles (GOFLO) * Comment: IN-patch of the iron-fertilized area
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Event labelEvent
CommentCommentIn/Out patch
Date/Time of eventDate/Time
Latitude of eventLatitude
Longitude of eventLongitude
DEPTH, waterDepth watermGeocode
Iron-binding ligand, dissolvedFeL dissnmol/lCroot, Peter L
ErrorErrorCroot, Peter LVoltammetryIron-binding ligand
Iron, dissolved, conditional complex stabilityFe LogK´ dissCroot, Peter LVoltammetryK is relative to Fe' where aFe' is 10**10
10 ErrorErrorCroot, Peter LVoltammetryLog K
11 Iron, dissolvedFe dissnmol/lCroot, Peter LVoltammetry
Size:
64 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Event

Comment
(In/Out patch)

Date/Time

Latitude

Longitude

Depth water [m]

FeL diss [nmol/l]

Error
(Iron-binding ligand)

Fe LogK´ diss
(K is relative to Fe' where aF...)
10 
Error
(Log K)
11 
Fe diss [nmol/l]
T1136-1 Out1999-02-09T13:13-60.9785139.2300400.250
T1139-1 In1999-02-10T17:48-60.9870139.4633403.520
T1140-6 In1999-02-12T07:32-60.9458139.7282403.490.0712.280.783.260
T1141-6 Out1999-02-12T17:04-60.9667139.4595403.610.4912.081.960.080
T1144-6 In1999-02-14T09:38-60.9327139.9288404.710.7510.940.480.683
T1151-5 In1999-02-16T09:08-60.9007140.0863404.160.8210.620.684.880
T1152-5 Out1999-02-16T17:56-61.1233140.1375402.710.4011.230.920.630
T1158-5 In1999-02-18T15:17-60.9250140.2367404.270.1211.120.132.350
T1159-6 In1999-02-19T12:25-60.9652140.2758402.410.6211.071.081.340
T1160-3 Out1999-02-19T20:16-60.9703140.6300401.040.0312.980.920.480
T1162-4 In1999-02-20T13:35-61.0170140.4027404.450.3811.530.731.135
T1171-5 In1999-02-22T08:21-61.1013140.6457409.202.8211.191.131.340