Liebetrau, Volker; Krause, Stefan (2014): U-Th isotope systematics and light stable isotope data of carbonate enriched sediments at MASOX site (methane seepage off Svalbard) at sediment core MSM21/4_657-1 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.826110, In supplement to: Berndt, Christian; Feseker, Tomas; Treude, Tina; Krastel, Sebastian; Liebetrau, Volker; Niemann, Helge; Bertics, Victoria J; Dumke, Ines; Dünnbier, Karolin; Ferre, Benedicte; Graves, Carolyn; Gross, Felix; Hissmann, Karen; Hühnerbach, Veit; Krause, Stefan; Lieser, Kathrin; Schauer, Jürgen; Steinle, Lea (2014): Temporal constraints on hydrate-controlled methane seepage off Svalbard. Published Online January 2 2014, Science, https://doi.org/10.1126/science.1246298
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Coverage:
Latitude: 78.555670 * Longitude: 9.473000
Date/Time Start: 2012-09-04T04:45:00 * Date/Time End: 2012-09-04T04:45:00
Minimum DEPTH, sediment/rock: 0.45 m * Maximum DEPTH, sediment/rock: 1.80 m
Event(s):
MSM21/4_657-1 * Latitude: 78.555670 * Longitude: 9.473000 * Date/Time: 2012-09-04T04:45:00 * Elevation: -388.4 m * Location: North Greenland Sea * Campaign: MSM21/4 * Basis: Maria S. Merian * Method/Device: Gravity corer (GC)
Comment:
Values with # mark highly unreliable ages characterized by uncertainties larger than the deduced age or even dominated by 230Th correction values as well as isochron approaches based just on 2-point reference lines. Therefore, the latter may not provide any proof for the petrographic postulation of cogenetic origin.
Uncertainties presented on 2 sigma level.
Note 1: The sample weight represents the analysed amount dissolved in 4 N Acetic Acid and 2.25 N HNO3 (marked by -2), respectively, at room temperature over 2 hours. Remaining material was 2 x centrifuged, dried down and weighed for recalculation of the dissolved sample weight.
Note 2: The equivalent percentage of the analysed non-silicate fraction represented by the sample weight. X-ray diffraction analyses indicated aragonite as the main non-silicate and easily dissolvable phase.
Parameter(s):
# | Name | Short Name | Unit | Principal Investigator | Method/Device | Comment |
---|---|---|---|---|---|---|
1 | DEPTH, sediment/rock | Depth sed | m | Geocode | ||
2 | Depth, top/min | Depth top | m | Krause, Stefan | ||
3 | Depth, bottom/max | Depth bot | m | Krause, Stefan | ||
4 | Sample code/label | Sample label | Krause, Stefan | leachate mode in brackets | ||
5 | Location | Location | Krause, Stefan | |||
6 | Description | Description | Krause, Stefan | |||
7 | Sample mass | Samp m | mg | Liebetrau, Volker | s. note 1 | |
8 | non-silicates, total | non silic tot | % | Liebetrau, Volker | s. note 2 | |
9 | Age, dated | Age dated | ka | Liebetrau, Volker | MC-ICP-MS, isotope dilution | |
10 | Age, error | Age e | ± | Liebetrau, Volker | MC-ICP-MS, isotope dilution | |
11 | Uranium-238 | 238U | mg/kg | Liebetrau, Volker | MC-ICP-MS, isotope dilution | |
12 | Error, absolute | Error a | ± | Liebetrau, Volker | MC-ICP-MS, isotope dilution | |
13 | Thorium-232 | 232Th | mg/kg | Liebetrau, Volker | MC-ICP-MS, isotope dilution | |
14 | Error, absolute | Error a | ± | Liebetrau, Volker | MC-ICP-MS, isotope dilution | |
15 | Uranium-234/Uranium-238 activity ratio | (234U/238U) | Liebetrau, Volker | MC-ICP-MS, isotope dilution | delta234U(o) (meas. 234U/238U act. ratio -1) * 1000 at time 0 (today) | |
16 | Uranium-234/Uranium-238 activity ratio, error, absolute | (234U/238U) e | ± | Liebetrau, Volker | MC-ICP-MS, isotope dilution | |
17 | Thorium-230/Thorium-232 activity ratio | (230Th/232Th) | Liebetrau, Volker | MC-ICP-MS, isotope dilution | ||
18 | Error, absolute | Error a | ± | Liebetrau, Volker | MC-ICP-MS, isotope dilution | |
19 | Uranium-238/Thorium-232 activity ratio | (238U/232Th) | Liebetrau, Volker | MC-ICP-MS, isotope dilution | ||
20 | Error, absolute | Error a | ± | Liebetrau, Volker | MC-ICP-MS, isotope dilution | |
21 | Thorium-230/Uranium-234 activity ratio | (230Th/234U) | Liebetrau, Volker | MC-ICP-MS, isotope dilution | 230Th/234U activity ratio corrected for inherited 230Th by application of 230Th/232Th activity ratio of 0.75 ± 0.2 as continental crust average value (according to Wedepohl, 1995) | |
22 | Error, absolute | Error a | ± | Liebetrau, Volker | MC-ICP-MS, isotope dilution | |
23 | Uranium-234/Uranium-238 activity ratio | (234U/238U) | Liebetrau, Volker | Calculated | delta234U(t)(234U/238U act. ratio at zero age -1) * 1000 at time (t = U/Th-age) Measured 234U/238U back-calculated for 234U decay since carbonate precipitation, based on the individual U/Th ingrowth age and half-lives measured by Cheng et al. (2000). | |
24 | Uranium-234/Uranium-238 activity ratio, error, absolute | (234U/238U) e | ± | Liebetrau, Volker | Calculated | |
25 | δ13C, carbonate | δ13C carb | ‰ PDB | Liebetrau, Volker | Mass spectrometer, Finnigan, MAT 253 | with respect to VPDB |
26 | Error, absolute | Error a | ± | Liebetrau, Volker | Mass spectrometer, Finnigan, MAT 253 | |
27 | δ18O, carbonate | δ18O carb | ‰ PDB | Liebetrau, Volker | Mass spectrometer, Finnigan, MAT 253 | with respect to VPDB |
28 | Error, absolute | Error a | ± | Liebetrau, Volker | Mass spectrometer, Finnigan, MAT 253 | |
29 | Carbonates | Carb | Krause, Stefan | X-ray diffractometry (Philips PW1710) | * Although the applied XRD library identified Kutnohorite it seems to be more appropriate to use the general term disordered dolomite instead, due to partially overlapping XRD spectra within this mineral group. | |
30 | Sample code/label | Sample label | Liebetrau, Volker | For sub-samples postulated of cogenetic origin by petrographic observations the isoplot 3.75 software of the Berkeley Geochronology Center, CA, USA is applyied for isochron age estimates. | ||
31 | Uranium-234/Uranium-238 activity ratio | (234U/238U) | Liebetrau, Volker | Calculated | delta234U(t)(234U/238U act. ratio at zero age -1) * 1000 at time (t = U/Th-age) Measured 234U/238U back-calculated for 234U decay since carbonate precipitation, based on the individual U/Th ingrowth age and half-lives measured by Cheng et al. (2000). delta234U(t) of Rosholt-1 isochron approaches based on isoplot 3.75 calculation. | |
32 | Uranium-234/Uranium-238 activity ratio, error, absolute | (234U/238U) e | ± | Liebetrau, Volker | Calculated | |
33 | Age model | Age model | ka | Liebetrau, Volker | Age estimates applying the Rosholt-1 isochron approach in 3 dimensional projection according data reduction system after Ludwig (2008). | |
34 | Age, error | Age e | ± | Liebetrau, Volker | ||
35 | Age model | Age model | ka | Liebetrau, Volker | Age estimates applying the Osmond isochron approach according data reduction system after Ludwig (2008). | |
36 | Age, error | Age e | ± | Liebetrau, Volker |
License:
Creative Commons Attribution 3.0 Unported (CC-BY-3.0)
Size:
281 data points