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Rampen, Sebastiaan W; Willmott, Verónica; Kim, Jung-Hyun; Uliana, Eleonora; Mollenhauer, Gesine; Schefuß, Enno; Sinninghe Damsté, Jaap S; Schouten, Stefan (2012): Long chain 1,13- and 1,15-diols in surface sediments ans SST reconstruction for sediment core GeoB6518-1. doi:10.1594/PANGAEA.825638,
Supplement to: Rampen, SW et al. (2012): Long chain 1,13- and 1,15-diols as a potential proxy for palaeotemperature reconstruction. Geochimica et Cosmochimica Acta, 84, 204-216, doi:10.1016/j.gca.2012.01.024

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Although commonly reported in marine and freshwater environments, little is known about the biological sources of long chain alkyl 1,13- and 1,15-diols, and factors controlling their distributions. Here we analyzed the occurrence and distribution of these lipids in a comprehensive set of marine surface sediments and compare their distributions with environmental conditions like sea surface temperature (SST), salinity and nutrient concentrations. Fractional abundances of the C28 1,13-, C30 1,13- and C30 1,15-diols show a strong correlation with SST and based on these results, we propose the Long chain Diol Index (LDI), which expresses the C30 1,15-diol abundance relative to those of C28 1,13-, C30 1,13- and C30 1,15-diols. The LDI shows a strong linear correlation with SST (LDI = 0.033 × SST + 0.095; R2 = 0.969, n = 162) over a temperature range of -3 to 27 °C. Long chain diol distributions in sediments from the South Atlantic close to the Congo River outflow (West Africa) provided a 43 kyr LDI SST record. This record reflects several known climatic events and shows similarities with an alkenone-derived SST record obtained using the same suite of sediments, both in trend and in terms of absolute SST. This confirms the potential of the LDI as a proxy for palaeo-SST reconstruction.
Median Latitude: -17.585787 * Median Longitude: -17.436292 * South-bound Latitude: -77.466000 * West-bound Longitude: -158.269000 * North-bound Latitude: 80.500000 * East-bound Longitude: 147.490000
Date/Time Start: 1989-10-15T03:24:00 * Date/Time End: 2009-04-04T15:43:00
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