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Barnes, Jaime D; Cisneros, Miguel (2012): (Table 2) Chlorine geochemistry and mineralogy of altered oceanic crust samples [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.812212, Supplement to: Barnes, JD; Cisneros, M (2012): Mineralogical control on the chlorine isotope composition of altered oceanic crust. Chemical Geology, 326-327, 51-60, https://doi.org/10.1016/j.chemgeo.2012.07.022

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Abstract:
Bulk chlorine concentrations and chlorine stable isotope compositions were determined for hydrothermally altered basalt (extrusive lavas and sheeted dikes) and gabbro samples (n = 50) from seven DSDP/ODP/IODP drill sites. These altered oceanic crust (AOC) samples span a range of crustal ages, tectonic settings, alteration type, and crustal depth. Bulk chlorine concentrations range from < 0.01 wt.% to 0.09 wt.%. In general, higher chlorine concentrations coincide with an increase in temperature of alteration and amphibole content. d37Cl values of whole rock AOC samples range from -1.4 to +1.8 per mil. High d37Cl values (>=~0.5 per mil) are associated with areas of higher amphibole content. This observation is consistent with theoretical calculations that estimate amphibole should be enriched in 37Cl compared to co-existing fluid. Negative to near zero d37Cl values are found in areas dominated by clay minerals. Chlorine geochemistry is a rough indicator of metamorphic grade and mineralogy. AOC is a major Cl host in the subducting oceanic lithospheric slab. Here we show that bulk chlorine concentrations are ~3 times higher than previous estimates resulting in a greater contribution of Cl to the mantle.
Coverage:
Median Latitude: 7.672489 * Median Longitude: -35.986768 * South-bound Latitude: -32.724000 * West-bound Longitude: -101.525000 * North-bound Latitude: 36.878700 * East-bound Longitude: 156.359800
Date/Time Start: 1974-06-17T00:00:00 * Date/Time End: 2002-11-23T03:45:00
Minimum DEPTH, sediment/rock: 1.60 m * Maximum DEPTH, sediment/rock: 2090.00 m
Event(s):
37-332B  * Latitude: 36.878700 * Longitude: -33.641000 * Date/Time: 1974-06-17T00:00:00 * Elevation: -1806.0 m * Penetration: 721.5 m * Recovery: 122.9 m * Location: North Atlantic/VALLEY * Campaign: Leg37 * Basis: Glomar Challenger * Method/Device: Drilling/drill rig (DRILL) * Comment: 48 cores; 582.5 m cored; 0 m drilled; 19.4 % recovery
52-418A  * Latitude: 25.035000 * Longitude: -68.057300 * Date/Time: 1977-02-10T00:00:00 * Elevation: -5511.0 m * Penetration: 570.5 m * Recovery: 205.5 m * Location: North Atlantic/CONT RISE * Campaign: Leg52 * Basis: Glomar Challenger * Method/Device: Drilling/drill rig (DRILL) * Comment: 48 cores; 374 m cored; 0 m drilled; 54.9 % recovery
53-418A  * Latitude: 25.035000 * Longitude: -68.057300 * Date/Time: 1977-03-15T00:00:00 * Elevation: -5514.0 m * Penetration: 868 m * Recovery: 234 m * Campaign: Leg53 * Basis: Glomar Challenger * Method/Device: Drilling/drill rig (DRILL) * Comment: 39 cores; 306.4 m cored; 0 m drilled; 76.4 % recovery
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Event labelEvent
Latitude of eventLatitude
Longitude of eventLongitude
Elevation of eventElevationm
Sample code/labelSample labelBarnes, Jaime DDSDP/ODP/IODP sample designation
DEPTH, sediment/rockDepth sedmGeocode – mbsf
Lithology/composition/faciesLithologyBarnes, Jaime D
ChlorineCl%Barnes, Jaime DInstrumental neutron activation analysis (INAA) (Reimann et al., 1998)wt.%
δ37Clδ37ClBarnes, Jaime DMass spectrometer, Finnigan, MAT 253
10 AmphiboleAmp%Barnes, Jaime DX-ray diffraction (XRD)wt.%, 0 = below detection limit
11 ChloriteChl%Barnes, Jaime DX-ray diffraction (XRD)wt.%, 0 = below detection limit
Size:
293 data points

Data

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Event

Latitude

Longitude

Elevation [m]

Sample label

Depth sed [m]

Lithology

Cl [%]

δ37Cl []
10 
Amp [%]
11 
Chl [%]
118-735B -32.72457.266-731118-735B-1D-2W,7.0-10.01.60Gabbro0.091.515
118-735B-32.72457.266-731118-735B-8D-1W,25.0-27.029.47Gabbro0.081.093
118-735B-32.72457.266-731118-735B-19R-4W,0.0-2.079.08Gabbro0.020.464
118-735B-32.72457.266-731118-735B-19R-4W,0.0-2.079.08Gabbro0.9
118-735B-32.72457.266-731118-735B-35R-7W,13.0-15.5170.85Gabbro0.051.8190
118-735B-32.72457.266-731118-735B-35R-7W,13.0-15.5170.85Gabbro1.3
118-735B-32.72457.266-731118-735B-52R-4W,9.0-11.0251.86Gabbro<0.010.3187
118-735B-32.72457.266-731118-735B-67R-4W,94.0-97.0334.91Gabbro<0.01-0.2160
118-735B-32.72457.266-731118-735B-80R-5W,88.0-90.0430.21Gabbro0.01-0.6120
118-735B-32.72457.266-731176-735B-101R-4W,0.0-2.0588.83Gabbro<0.010.220
118-735B-32.72457.266-731176-735B-117R-6W,0.0-2.0688.30Gabbro<0.010.748
118-735B-32.72457.266-731176-735B-147R-4W,69.0-71.0945.11Gabbro<0.010.1
118-735B-32.72457.266-731176-735B-147R-4W,69.0-71.0945.11Gabbro-0.1
118-735B-32.72457.266-731176-735B-170R-2W,90.0-92.01151.21Gabbro<0.01-0.3<1<1
118-735B-32.72457.266-731176-735B-197R-1W,70.0-72.01383.75Gabbro0.010.705
37-332B 36.879-33.641-180637-332B-2-1W,55-60152.05Lava<0.011.0
37-332B36.879-33.641-180637-332B-14-2W,72-74391.22Lava0.020.1
37-332B36.879-33.641-180637-332B-28-1W,100-104523.00Lava<0.010.2
37-332B36.879-33.641-180637-332B-44-1W,55-61674.55Lava<0.010.8
52-418A 25.035-68.057-551152-418A-31-3W,72-75425.61Lava<0.01-0.8
53-418A 25.035-68.057-551453-418A-50-3W,13-17576.48Lava<0.01-0.3
53-418A25.035-68.057-551453-418A-65-3W,62-65708.63Lava<0.01-0.8
53-418A25.035-68.057-551453-418A-83-3W,6-10843.36Lava0.010.0
70-504B 1.227-83.730-346070-504B-67R-1,64-66800.64Lava0.03-1.4
70-504B1.227-83.730-346070-504B-67R-1,64-66800.640.4
70-504B1.227-83.730-346070-504B-67R-1,64-66800.64-0.5
70-504B1.227-83.730-346070-504B-67R-1,64-66800.640.1
70-504B1.227-83.730-346070-504B-67R-1,64-66800.64-0.3
83-504B 1.227-83.730-346083-504B-90R-2,4-6996.04Dike<0.010.3
83-504B1.227-83.730-346083-504B-111R-1,74-761162.24Dike<0.010.0
83-504B1.227-83.730-346083-504B-137R-1,109-1111328.09Dike<0.01-0.4
137-504B 1.227-83.730-3474137-504B-176R-1,102-1041596.32Dike0.03-0.3
140-504B 1.227-83.730-3474140-504B-187R-1,26-291632.26Dike0.040.1
140-504B1.227-83.730-3474140-504B-187R-1,26-291632.26Dike0.3
140-504B1.227-83.730-3474140-504B-214R-2,29-311820.34Dike0.05-0.4190
140-504B1.227-83.730-3474140-504B-214R-2,29-311820.34Dike0.6
140-504B1.227-83.730-3474140-504B-214R-2,29-311820.34Dike1.4
140-504B1.227-83.730-3474140-504B-214R-2,29-311820.34Dike1.2
140-504B1.227-83.730-3474140-504B-236R-1,26-311980.96Dike0.020.6
148-504B 1.227-83.730-3474148-504B-251R-1,10-122090.00Dike<0.01-0.200
129-801C 18.642156.360-5685129-801C-1R-6,4-6500.01Lava0.020.8020
129-801C18.642156.360-5685129-801C-1R-6,4-6500.01Lava0.6
129-801C18.642156.360-5685129-801C-5R-3,30-40534.07Lava0.01-1.1
129-801C18.642156.360-5685129-801C-5R-3,30-40534.07Lava-1.4
129-801C18.642156.360-5685129-801C-11R-2,20-30579.50Lava0.020.509
185-801C 18.642156.360-5674185-801C-23R-3,30-40684.88Lava<0.01-0.5
185-801C18.642156.360-5674185-801C-30R-1,114-116748.44Lava<0.01-0.4
185-801C18.642156.360-5674185-801C-36R-1,92-94805.02Lava0.01-0.4
185-801C18.642156.360-5674185-801C-36R-1,92-94805.02Lava-0.2
185-801C18.642156.360-5674185-801C-43R-3,34-36872.26Lava0.02-0.1
185-801C18.642156.360-5674185-801C-48R-2,14-16918.14Lava<0.010.7
185-801C18.642156.360-5674185-801C-48R-2,14-16918.14Lava0.7
185-801C18.642156.360-5674185-801C-48R-2,14-16918.14Lava0.0
147-894F 2.300-101.525-3036147-894F-2R-1,29-319.59Gabbro<0.010.6
147-894F2.300-101.525-3036147-894G-5R-1,23-2550.23Gabbro0.030.3
147-894F2.300-101.525-3036147-894G-11R-3,61-6387.61Gabbro0.021.7
147-894F2.300-101.525-3036147-894G-17R-1,18-22125.98Gabbro0.020.3
147-894F2.300-101.525-3036147-894G-17R-1,18-22125.98Gabbro0.6
147-894F2.300-101.525-3036147-894G-20R-CC,69-71148.11Gabbro0.030.9
206-1256D 0.736-91.934-3635206-1256D-45R-1,36-38552.86Lava0.010.2
206-1256D0.736-91.934-3635206-1256D-74R-1,40-42747.60Lava0.020.7
309-U1256D 6.735-91.934-3635309-U1256D-103R-1,22-24936.22Lava<0.01-0.2
309-U1256D6.735-91.934-3635309-U1256D-128R-1,93-951057.03Dike<0.01-0.2
309-U1256D6.735-91.934-3635309-U1256D-151R-1,22-241165.52Dike0.010.0
309-U1256D6.735-91.934-3635312-U1256D-175R-1,80-821272.10Dike0.02-1.0
309-U1256D6.735-91.934-3635312-U1256D-175R-1,80-821272.10Dike0.3
309-U1256D6.735-91.934-3635312-U1256D-175R-1,80-821272.10Dike0.0
309-U1256D6.735-91.934-3635312-U1256D-175R-1,80-821272.10Dike0.2
309-U1256D6.735-91.934-3635312-U1256D-214R-2,37-391412.72Gabbro0.050.2160
309-U1256D6.735-91.934-3635312-U1256D-214R-2,37-391412.72Gabbro1.3
309-U1256D6.735-91.934-3635312-U1256D-214R-2,37-391412.72Gabbro0.1
309-U1256D6.735-91.934-3635312-U1256D-232R-1,21-231493.11Gabbro0.041.2