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Data Publisher for Earth & Environmental Science

Möller, Lars; Sowers, Todd A; Bock, Michael; Spahni, Renato; Behrens, Melanie; Schmitt, Jochen; Miller, Heinz; Fischer, Hubertus (2013): Carbon isotopic data of atmospheric methane from EDML ice core [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.812111, In supplement to: Möller, L et al. (2013): Independent variations of CH4 emissions and isotopic composition over the past 160,000 years. Nature Geoscience, 6, 885-890, https://doi.org/10.1038/ngeo1922

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Related to:
Fischer, Hubertus; Behrens, Melanie; Bock, Michael; Richter, Ulrike; Schmitt, Jochen; Loulergue, Laetitia; Chappellaz, Jérôme A; Spahni, Renato; Blunier, Thomas; Leuenberger, Markus Christian; Stocker, Thomas F (2008): Changing boreal methane sources and constant biomass burning during the last termination. Nature, 452(7189), 864-867, https://doi.org/10.1038/nature06825
Lemieux-Dudon, Bénédicte; Blayo, Eric; Waelbroeck, Claire; Svensson, Anders M; Ritz, Catherine; Barnola, Jean-Marc; Narcisi, Biancamaria; Parrenin, Frédéric (2010): Consistent dating for Antarctic and Greenland ice cores. Quaternary Science Reviews, 29(1-2), 8-20, https://doi.org/10.1016/j.quascirev.2009.11.010
Schmitt, Jochen; Seth, Barbara; Bock, Michael; van der Veen, Carina; Möller, Lars; Sapart, Célia-Julia; Prokopiou, M; Sowers, Todd A; Röckmann, Thomas; Fischer, Hubertus (2013): On the interference of 86Kr2+ during carbon isotope analysis of atmospheric methane using continuous flow combustion – isotope ratio mass spectrometry. Atmospheric Measurement Techniques Disscusions, 6(1), 1409-1460, https://doi.org/10.5194/amtd-6-1409-2013
Funding:
Fifth Framework Programme (FP5), grant/award no. EVK2-CT-2000-00077: European Project for Ice Coring in Antarctica
Fourth Framework Programme (FP4), grant/award no. ENV4980702: European Project for Ice Coring in Antarctica
German Research Foundation (DFG), grant/award no. 5472008: Priority Programme 1158 Antarctic Research with Comparable Investigations in Arctic Sea Ice Areas
Coverage:
Latitude: -75.002500 * Longitude: 0.068400
Date/Time Start: 2001-01-10T00:00:00 * Date/Time End: 2006-01-17T00:00:00
Minimum DEPTH, ice/snow: 647.000 m * Maximum DEPTH, ice/snow: 1950.000 m
Event(s):
EDML (EPICA Dronning Maud Land, DML28C01_00) * Latitude: -75.002500 * Longitude: 0.068400 * Date/Time Start: 2001-01-10T00:00:00 * Date/Time End: 2006-01-17T00:00:00 * Elevation: 2891.7 m * Recovery: 2774.15 m * Campaign: EPICA-Campaigns * Basis: Kohnen Station * Method/Device: EPICA drill (EDRILL) * Comment: Elevation is given with reference to WGS84
Comment:
Samples above 1010 m are from Fischer et al. 2008, but have here been corrected for Kr interference and processed similar to the data presented here. It is mandatory to cite both publications, if you want to use the full dataset.
All d13CH4 values reported with respect to VPDB.
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
DEPTH, ice/snowDepth ice/snowmGeocode
Gas ageGas ageka BPMöller, LarsUnified gas age (see Lemieux-Dudon et al. 2010, doi:10.1016/j.quascirev.2009.11.010)
δ13C, methaneδ13C CH4‰ PDBMöller, Larsvalues corrected for machine specific drifts and referenced to VPDB
δ13Cδ13C‰ PDBMöller, Larsshift caused by the mass spectrometer interference with atmospheric krypton (see Schmitt et al. 2013, doi:10.5194/amtd-6-1409-2013)
δ13C, methaneδ13C CH4‰ PDBMöller, LarsVPDB, values corrected for Kr interference
δ13C, methaneδ13C CH4‰ PDBMöller, LarsVPDB, values (column 5) corrected for a constant glacial offset of 0.41 per mil due to gravitational settling in the firn layer
δ13C, standard deviationδ13C std dev±Möller, Larsreplicate standard deviation (1-sigma, per mil)
Size:
999 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Depth ice/snow [m]

Gas age [ka BP]
(Unified gas age (see Lemieux-...)

δ13C CH4 [‰ PDB]
(values corrected for machine ...)

δ13C [‰ PDB]
(shift caused by the mass spec...)

δ13C CH4 [‰ PDB]
(VPDB, values corrected for Kr...)

δ13C CH4 [‰ PDB]
(VPDB, values (column 5) corre...)

δ13C std dev [±]
(replicate standard deviation ...)
647.0009.937-46.13440.06-46.0744-46.484
660.00010.284-46.50130.16-46.3413-46.751
672.00010.592-46.10510.15-45.9551-46.365
684.00010.875-46.01820.15-45.8682-46.2780.032
684.12510.878-45.92500.12-45.8050-46.2150.032
696.00011.158-45.64910.12-45.5291-45.939
709.00011.448-45.00300.18-44.8230-45.233
720.12511.645-45.56840.27-45.2984-45.708
731.00011.803-44.85920.13-44.7292-45.139
743.00012.029-44.77870.14-44.6387-45.0490.101
743.12512.032-44.52640.09-44.4364-44.8460.101
757.00012.393-44.67050.18-44.4905-44.901
768.00012.705-45.73870.18-45.5587-45.969
781.00013.093-46.15600.15-46.0060-46.416
792.00013.410-45.91960.15-45.7696-46.1800.058
792.12513.413-45.83410.18-45.6541-46.0640.058
804.00013.759-46.06790.25-45.8179-46.228
816.00014.139-46.16210.22-45.9421-46.352
828.12514.497-46.20880.29-45.9188-46.329
839.00014.786-44.76140.11-44.6514-45.061
852.12515.121-45.49360.35-45.1436-45.554
864.00015.430-44.08730.09-43.9973-44.407
877.00015.784-44.24340.27-43.9734-44.383
888.12516.093-44.08420.29-43.7942-44.204
913.12516.826-43.92220.32-43.6022-44.012
924.12517.228-42.85410.31-42.5441-42.954
934.00017.633-43.31150.62-42.6915-43.1020.049
934.12517.638-43.09920.31-42.7892-43.1990.049
961.00018.770-42.57830.24-42.3383-42.748
973.00019.372-42.88440.26-42.6244-43.0340.034
973.12519.378-42.90330.21-42.6933-43.1030.034
984.00019.900-42.67670.12-42.5567-42.967
996.00020.454-43.33930.28-43.0593-43.469
1009.00021.010-43.45400.25-43.2040-43.614
1019.00021.419-43.20150.54-42.6615-43.072
1044.00022.393-43.47440.67-42.8044-43.214
1068.00023.131-43.75100.66-43.0910-43.501
1080.00023.772-43.95920.81-43.1492-43.559
1092.00024.433-43.51520.70-42.8152-43.225
1104.00025.119-43.61020.72-42.8902-43.300
1116.00025.766-43.77080.69-43.0808-43.491
1140.00026.991-43.72370.69-43.0337-43.444
1163.00028.264-43.82610.61-43.2161-43.626
1188.00029.595-44.11990.72-43.3999-43.810
1200.00030.265-43.84020.59-43.2502-43.660
1213.00031.147-44.06230.57-43.4923-43.902
1224.00031.897-43.79520.36-43.4352-43.845
1236.00032.545-45.04690.55-44.4969-44.9070.026
1236.12532.554-45.03490.59-44.4449-44.8550.026
1248.00033.330-44.33180.59-43.7418-44.152
1260.00033.718-44.44590.53-43.9159-44.326
1268.12534.268-45.11780.82-44.2978-44.708
1272.00034.540-44.93430.68-44.2543-44.6640.335
1272.12534.548-45.58480.66-44.9248-45.3350.335
1277.12534.851-44.70730.56-44.1473-44.557
1280.12535.035-44.82450.63-44.1945-44.605
1284.00035.279-44.47350.55-43.9235-44.3340.140
1284.12535.286-44.76420.56-44.2042-44.6140.140
1289.12535.569-45.65130.72-44.9313-45.341
1292.12535.712-45.07500.71-44.3650-44.775
1296.00035.895-45.37240.70-44.6724-45.0820.095
1296.12535.901-44.99150.51-44.4815-44.8920.095
1299.12536.045-45.41530.82-44.5953-45.005
1304.12536.304-44.84150.63-44.2115-44.622
1308.00036.501-45.08990.56-44.5299-44.9400.059
1308.12536.508-45.26720.62-44.6472-45.0570.059
1311.12536.674-45.58150.71-44.8715-45.282
1316.12536.982-45.01650.53-44.4865-44.897
1320.00037.262-44.86390.45-44.4139-44.8240.221
1320.12537.271-45.43510.58-44.8551-45.2650.221
1325.12537.573-45.86810.43-45.4381-45.848
1328.00037.747-45.40140.39-45.0114-45.4210.063
1328.12537.754-45.50610.62-44.8861-45.2960.063
1332.00037.969-45.15700.52-44.6370-45.0470.260
1332.12537.976-45.69720.54-45.1572-45.5670.260
1340.00038.351-45.89740.54-45.3574-45.7670.194
1340.12538.357-46.36520.62-45.7452-46.1550.194
1344.00038.516-45.25250.57-44.6825-45.0930.127
1344.12538.521-45.49610.56-44.9361-45.3460.127
1349.12538.718-45.77060.83-44.9406-45.351
1352.00038.834-45.65530.58-45.0753-45.4850.170
1352.12538.839-45.39480.66-44.7348-45.1450.170
1356.00038.998-45.16550.61-44.5555-44.9660.160
1356.12539.003-45.50640.63-44.8764-45.2860.160
1361.12539.220-45.93780.72-45.2178-45.628
1364.00039.370-44.22690.68-43.5469-43.9570.201
1364.12539.378-43.80460.66-43.1446-43.5550.201
1368.00039.600-44.30390.67-43.6339-44.0440.345
1368.12539.608-45.01400.69-44.3240-44.7340.345
1373.00039.910-45.47370.82-44.6537-45.064
1376.00040.063-45.38590.73-44.6559-45.0660.301
1376.12540.068-44.78460.73-44.0546-44.4650.301
1380.00040.226-44.77520.66-44.1152-44.5250.517
1380.12540.231-45.84850.70-45.1485-45.5590.517
1385.12540.452-45.36830.79-44.5783-44.988
1392.00040.721-45.00130.64-44.3613-44.771
1395.41040.882-45.73500.61-45.1250-45.5350.332
1395.53540.888-45.12060.66-44.4606-44.8710.332
1403.00041.318-44.79440.41-44.3844-44.794
1407.30041.558-45.83250.78-45.0525-45.4630.126
1407.42541.564-45.34960.55-44.7996-45.2100.126
1416.00042.018-45.12230.55-44.5723-44.982
1418.99042.165-45.72610.70-45.0261-45.4360.019
1419.11542.172-45.66340.60-45.0634-45.4730.019
1427.00042.552-45.39680.50-44.8968-45.307
1431.30042.765-45.70000.56-45.1400-45.5500.208
1431.42542.772-46.18700.63-45.5570-45.9670.208
1440.00043.239-45.62820.65-44.9782-45.3880.110
1440.12543.246-45.21880.46-44.7588-45.1690.110
1444.30043.548-45.72400.52-45.2040-45.6140.148
1444.42543.560-46.06070.56-45.5007-45.9110.148
1451.00044.202-45.81280.59-45.2228-45.633
1455.30044.555-46.58760.52-46.0676-46.4780.168
1455.42544.564-47.05400.65-46.4040-46.8140.168
1465.00045.246-46.60790.57-46.0379-46.4480.080
1465.12545.254-46.68710.49-46.1971-46.6070.080
1466.00045.309-47.14010.62-46.5201-46.9300.102
1466.12545.316-46.63620.32-46.3162-46.7260.102
1475.00045.850-47.29240.49-46.8024-47.212
1480.42546.169-47.02480.40-46.6248-47.035
1487.00046.554-46.67360.42-46.2536-46.664
1492.00046.834-46.65990.46-46.1999-46.610
1499.00047.190-47.02730.57-46.4573-46.8670.284
1499.12547.196-46.40950.52-45.8895-46.3000.284
1504.00047.462-46.36030.59-45.7703-46.180
1511.00047.885-45.90570.53-45.3757-45.786
1516.00048.187-46.26000.52-45.7400-46.150
1524.12548.664-46.22660.57-45.6566-46.067
1528.00048.913-46.03150.52-45.5115-45.922
1536.00049.422-45.97430.37-45.6043-46.014
1540.00049.671-46.98990.49-46.4999-46.910
1548.00050.169-46.99920.50-46.4992-46.909
1552.00050.405-47.07060.45-46.6206-47.031
1560.00050.879-47.08890.48-46.6089-47.019
1578.00051.921-47.52500.48-47.0450-47.455
1589.00052.558-47.29780.47-46.8278-47.238
1602.00053.283-46.75830.46-46.2983-46.708
1615.00054.011-46.47020.52-45.9502-46.3600.051
1615.12554.018-46.44910.60-45.8491-46.2590.051
1627.00054.711-46.20690.44-45.7669-46.177
1639.00055.482-46.31750.50-45.8175-46.2280.009
1639.12555.490-46.29900.50-45.7990-46.2090.009
1651.00056.325-46.34620.45-45.8962-46.306
1662.00057.051-46.38320.41-45.9732-46.383
1674.00057.795-45.98360.41-45.5736-45.984
1680.00058.139-46.20250.50-45.7025-46.113
1687.00058.526-45.35480.41-44.9448-45.355
1692.00058.804-45.71630.48-45.2363-45.646
1698.00059.135-46.53750.57-45.9675-46.378
1704.00059.487-46.69000.67-46.0200-46.430
1709.00059.800-45.33490.53-44.8049-45.2150.213
1709.12559.807-45.79070.56-45.2307-45.6410.213
1716.00060.239-46.15180.57-45.5818-45.992
1722.00060.632-45.33410.50-44.8341-45.244
1727.00060.964-45.39100.58-44.8110-45.221
1734.00061.443-45.09160.52-44.5716-44.982
1740.00061.867-45.08140.61-44.4714-44.881
1747.00062.395-45.33980.54-44.7998-45.210
1751.00062.700-45.12280.51-44.6128-45.023
1758.00063.253-44.48090.50-43.9809-44.3910.147
1758.12563.263-44.76470.49-44.2747-44.6850.147
1765.00063.812-45.73990.63-45.1099-45.520
1770.00064.212-45.55240.56-44.9924-45.402
1775.00064.619-45.48220.57-44.9122-45.322
1782.00065.202-44.96460.54-44.4246-44.835
1788.00065.728-45.57750.56-45.0175-45.428
1800.00066.715-46.15110.59-45.5611-45.971
1806.00067.216-46.07660.54-45.5366-45.947
1812.00067.745-46.38150.48-45.9015-46.312
1819.00068.344-46.37930.53-45.8493-46.259
1824.00068.761-46.72610.25-46.4761-46.886
1830.00069.245-47.23580.58-46.6558-47.066
1837.00069.853-47.41000.56-46.8500-47.260
1842.00070.286-47.87040.48-47.3904-47.800
1854.00071.259-49.25150.55-48.7015-49.112
1860.00071.690-49.07210.61-48.4621-48.8720.046
1860.12571.699-49.00030.63-48.3703-48.7800.046
1866.00072.110-47.54320.47-47.0732-47.4830.452
1866.12572.118-48.60810.63-47.9781-48.3880.452
1872.00072.519-48.62720.49-48.1372-48.547
1878.00072.973-48.67630.56-48.1163-48.526
1890.00073.989-49.26590.59-48.6759-49.086
1902.00074.968-49.68780.54-49.1478-49.558
1926.12576.769-48.71790.44-48.2779-48.688
1950.00078.770-48.94540.48-48.4654-48.875