Li, Rongxi; Dong, Shuwen; Lehrmann, Daniel; Duan, Lizhi (2013): (Table 1) Geochemical and geothermometry data from fibrous calcite vein fills in the Dabashan Fold Belt, China [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.811050, Supplement to: Li, R et al. (2013): Tectonically driven organic fluid migration in the Dabashan Foreland Belt: evidenced by geochemistry and geothermometry of vein-filling fibrous calcite with organic inclusions. Journal of Asian Earth Sciences, 75, 202-212, https://doi.org/10.1016/j.jseaes.2013.07.026
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Published: 2013-05-02 • DOI registered: 2013-05-30
Abstract:
Fibrous calcite veins with organic inclusions have been widely considered as indicators of oil and gas generation and migration under overpressure. Abundant fibrous calcite veins containing organic-bearing inclusions occur in faulted Lower Paleozoic through Triassic hydrocarbon source rocks in the Dabashan Foreland Belt (DBF). d13CPDB and d18OPDB values of the fibrous calcite range from - 4.8 to -1.9 to per mil and - 12.8 to - 8.4 per mil respectively, which is lighter than that of associated carbonate host rocks ranging from - 1.7 to + 3.1 per mil and - 8.7 to - 4.5 per mil. A linear relationship between d13CPDB and d18OPDB indicates that the calcite veins were precipitated from a mixture of basinal and surface fluids. The fibrous calcite contains a variety of inclusions, such as solid bitumen, methane bearing all-liquid inclusions, and vapor-liquid aqueous inclusions. Homogenization temperatures of aqueous inclusions range from 140 to 196° with an average of 179°. Salinities of aqueous inclusions average 9.7 wt% NaCl. Independent temperatures from bitumen reflectance and inclusion phase relationships of aqueous and methane inclusions were used to determine fluid pressures. Results indicate high pressures, elevated above typical lithostatic confining pressure, from 150 to 200 MPa. The elevated salinity and high temperature and pressure conditions of the fibrous calcite veins argue against an origin solely from burial overpressure resulting from clay transformation and dehydration reactions. Instead fluid inclusion P-T data and geochemistry results and regional geology indicate abnormally high pressures during fluid migration. These findings indicate that tectonic stress generated fracture and fault fluid pathways and caused migration of organic bearing fluids from the DBF during the Yanshan orogeny.
Coverage:
Median Latitude: 32.049611 * Median Longitude: 108.319511 * South-bound Latitude: 31.350000 * West-bound Longitude: 107.617500 * North-bound Latitude: 32.522500 * East-bound Longitude: 108.643500
Date/Time Start: 2008-06-04T00:00:00 * Date/Time End: 2008-07-19T00:00:00
Event(s):
Dabashan_Foreland_Belt * Latitude Start: 31.350000 * Longitude Start: 107.617500 * Latitude End: 32.522500 * Longitude End: 108.535000 * Date/Time Start: 2008-06-04T00:00:00 * Date/Time End: 2008-07-19T00:00:00 * Location: Sichuan, Shaanxi, China * Method/Device: Sampling by hand (HAND)
Parameter(s):
License:
Creative Commons Attribution 3.0 Unported (CC-BY-3.0)
Size:
726 data points
Data
| 1 Sample label | 2 Latitude | 3 Longitude | 4 Lithology | 5 Th [°C] (Linkam THMS600 microscope stage) | 6 Th [°C] (Linkam THMS600 microscope stage) | 7 Th [°C] (Linkam THMS600 microscope stage) | 8 Th [°C] (Linkam THMS600 microscope stage) | 9 Th [°C] (Linkam THMS600 microscope stage) | 10 Th [°C] (Linkam THMS600 microscope stage) | 11 Th [°C] (Linkam THMS600 microscope stage) | 12 Tm [°C] (Linkam THMS600 microscope stage) | 13 Tm [°C] (Linkam THMS600 microscope stage) | 14 Tm [°C] (Linkam THMS600 microscope stage) | 15 Tm [°C] (Linkam THMS600 microscope stage) | 16 Tm [°C] (Linkam THMS600 microscope stage) | 17 Tm [°C] (Linkam THMS600 microscope stage) | 18 Tm [°C] (Linkam THMS600 microscope stage) | 19 Th [°C] (Thm, Linkam THMS600 microscop...) | 20 Th [°C] (Thm, Linkam THMS600 microscop...) | 21 Rb [%] (Microphotometer LEITZ MPV-3) | 22 δ13C OM [‰ PDB] (Mass spectrometer Finnigan MA...) | 23 δ18O OM [‰] (Mass spectrometer Finnigan MA...) | 24 SiO2 [%] (Weight %, Electron microprobe...) | 25 Al2O3 [%] (Weight %, Electron microprobe...) | 26 Na2O [%] (Weight %, Electron microprobe...) | 27 K2O [%] (Weight %, Electron microprobe...) | 28 MgO [%] (Weight %, Electron microprobe...) | 29 CaO [%] (Weight %, Electron microprobe...) | 30 MnO [%] (Weight %, Electron microprobe...) | 31 FeO [%] (Weight %, Electron microprobe...) | 32 P2O5 [%] (Weight %, Electron microprobe...) | 33 [SO3]2- [%] (Weight %, Electron microprobe...) | 34 TiO2 [%] (Weight %, Electron microprobe...) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| B002-1 | 32.340500 | 107.617500 | fibrous calcite vein | 141.2 | 139.6 | -4.1 | -3.9 | ||||||||||||||||||||||||||
| B026-3 | 32.214700 | 108.117500 | fibrous calcite vein | 144.7 | 151.3 | 146.9 | -5.7 | -6.0 | -5.6 | -110.4 | |||||||||||||||||||||||
| B053-4 | 31.918700 | 108.337500 | fibrous calcite vein | 154.6 | 161.0 | -8.3 | -7.2 | ||||||||||||||||||||||||||
| D001-2 | 32.522500 | 108.517900 | Calcite vein | 212.1 | 139.3 | 184.0 | 196.5 | 191.4 | 147.0 | -6.6 | -5.1 | -5.0 | -4.8 | -6.3 | -4.8 | ||||||||||||||||||
| D010-3 | 32.470700 | 108.438700 | Fibrous calcite | 169.8 | 174.3 | -6.2 | -5.4 | -2.1 | -10.8 | 0.36 | 55.46 | 0.13 | 0.56 | ||||||||||||||||||||
| D014-1 | 32.438300 | 108.361500 | fibrous calcite vein | 187.4 | 190.3 | -6.8 | -6.4 | -113.4 | |||||||||||||||||||||||||
| D014-1 | 32.438300 | 108.361500 | bitumen vein | 2.03 | |||||||||||||||||||||||||||||
| D016-1 | 32.396700 | 108.314400 | fibrous calcite vein | 162.7 | 178.6 | 167.4 | -6.8 | -6.1 | -7.7 | ||||||||||||||||||||||||
| D017-1 | 32.381300 | 108.299500 | fibrous calcite vein | 186.5 | -7.3 | ||||||||||||||||||||||||||||
| D017-2 | 32.381300 | 108.299500 | carbonaceous mudstone, Cambrian | 2.47 | |||||||||||||||||||||||||||||
| D017-3 | 32.354900 | 108.277900 | fibrous calcite vein | 175.6 | 184.4 | -8.6 | -6.3 | -107.1 | -1.9 | -12.8 | 0.03 | 0.02 | 0.04 | 0.18 | 61.57 | 0.10 | 0.014 | ||||||||||||||||
| D017-3 | 32.354900 | 108.277900 | fibrous calcite vein | -1.7 | -6.1 | ||||||||||||||||||||||||||||
| D017-3 | 32.354900 | 108.277900 | bitumen vein in limestone, Cambrian | 2.64 | 0.11 | 0.02 | 0.02 | 0.02 | 2.41 | 49.26 | 0.03 | 1.42 | 0.01 | 0.021 | |||||||||||||||||||
| D017-3 | 32.354900 | 108.277900 | host rock | ||||||||||||||||||||||||||||||
| D017-4 | 32.354900 | 108.277900 | bitumen vein | 2.41 | |||||||||||||||||||||||||||||
| D017-5 | 32.354900 | 108.277900 | bitumen vein in limestone, Cambrian | 2.29 | |||||||||||||||||||||||||||||
| D017-6 | 32.354900 | 108.277900 | fibrous calcite vein | 177.1 | -6.1 | ||||||||||||||||||||||||||||
| D018-1 | 32.336600 | 108.238300 | bitumen vein in limestone, Cambrian | 2.61 | |||||||||||||||||||||||||||||
| D018-1w | 32.336600 | 108.238300 | host rock, limestone containing bitumen, Cambrian | 2.63 | |||||||||||||||||||||||||||||
| D018-2 | 32.336600 | 108.238300 | fibrous calcite vein | 188.6 | 174.9 | 182.7 | -9.4 | -8.8 | -7.7 | -108.7 | -106.8 | ||||||||||||||||||||||
| D018-2 | 32.336600 | 108.238300 | bitumen vein | 2.31 | |||||||||||||||||||||||||||||
| D019-1 | 32.336900 | 108.238000 | fibrous calcite vein | 184.3 | -8.2 | -1.8 | -10.3 | 0.02 | 0.01 | 0.07 | 0.06 | 0.25 | 64.69 | 0.20 | 1.39 | 0.015 | |||||||||||||||||
| D019-1 | 32.336900 | 108.238000 | host rock | 1.4 | -8.7 | 0.10 | 0.21 | 0.01 | 1.81 | 42.11 | 0.07 | 1.62 | |||||||||||||||||||||
| D020-1 | 32.336900 | 108.238000 | Calcite vein | 201.5 | 146.7 | 214.6 | 179.8 | 139.4 | 153.2 | -7.1 | -5.6 | -6.2 | -6.6 | -5.8 | -5.7 | -114.0 | |||||||||||||||||
| D020-2 | 32.336900 | 108.238000 | Calcite vein | 194.5 | 152.7 | 166.4 | -8.4 | -5.7 | -4.8 | -105.5 | -109.2 | ||||||||||||||||||||||
| D020-2 | 32.336900 | 108.238000 | bitumen vein | 2.07 | |||||||||||||||||||||||||||||
| D021-1 | 32.322600 | 108.231200 | fibrous calcite vein | 187.5 | -6.7 | ||||||||||||||||||||||||||||
| D021-2 | 32.322600 | 108.231200 | Calcite vein | 203.7 | 157.8 | 184.0 | 169.7 | 176.0 | -8.8 | -6.8 | -6.1 | -8.2 | |||||||||||||||||||||
| D022-1 | 32.308000 | 108.236400 | fibrous calcite vein | 199.2 | 180.4 | -9.7 | -6.1 | -115.9 | -2.6 | -10.4 | 0.02 | 0.25 | 54.37 | 0.04 | 1.67 | 0.011 | |||||||||||||||||
| D024-1 | 32.301500 | 108.209500 | fibrous calcite vein | 174.3 | -6.8 | ||||||||||||||||||||||||||||
| D024-2 | 32.308000 | 108.236400 | fibrous calcite vein | 187.6 | 174.9 | -6.3 | -6.7 | -108.3 | -106.6 | -4.8 | -9.2 | 0.11 | 0.04 | 0.42 | 57.04 | 0.10 | 1.87 | ||||||||||||||||
| D024-2 | 32.308000 | 108.236400 | bitumen vein | 2.14 | |||||||||||||||||||||||||||||
| D025-1 | 32.288300 | 108.200200 | bitumen vein | 2.27 | |||||||||||||||||||||||||||||
| D025-2 | 32.286700 | 108.198700 | calcite veins | 179.1 | 126.0 | 199.4 | 132.7 | 189.3 | -6.4 | -5.2 | -7.9 | -5.4 | -6.9 | -113.7 | |||||||||||||||||||
| D025-3 | 32.284200 | 108.194200 | Quartz vein | 216.7 | 196.4 | 153.4 | 224.7 | 176.0 | 134.8 | 143.0 | -9.5 | -6.3 | -5.7 | -8.4 | -6.1 | -5.1 | -5.7 | ||||||||||||||||
| D026-1 | 32.283700 | 108.193200 | fibrous calcite vein | 174.8 | 182.0 | -7.8 | -7.7 | -4.3 | -8.4 | 0.03 | 0.04 | 0.02 | 0.35 | 65.73 | 0.22 | 1.58 | 0.073 | ||||||||||||||||
| D026-1 | 32.283700 | 108.193200 | host rock | 0.14 | 0.14 | 5.76 | 54.76 | 0.24 | 1.04 | ||||||||||||||||||||||||
| D028-1 | 32.288300 | 108.169600 | calcite vein | 184.6 | 157.9 | 176.0 | -8.4 | -5.4 | -6.1 | -115.7 | |||||||||||||||||||||||
| D030-1 | 32.287200 | 108.127800 | fibrous calcite vein | 168.3 | 172.0 | -5.2 | -7.2 | -107.0 | -1.4 | -7.4 | |||||||||||||||||||||||
| D030-1 | 32.287200 | 108.127800 | fibrous calcite vein | -1.9 | -10.1 | 0.08 | 0.03 | 0.01 | 0.04 | 0.31 | 66.25 | 0.12 | 1.07 | 0.017 | 0.03 | ||||||||||||||||||
| D030-1 | 32.287200 | 108.127800 | fibrous calcite vein | 2.1 | -6.7 | ||||||||||||||||||||||||||||
| D030-1 | 32.287200 | 108.127800 | host rock | 0.25 | 0.40 | 0.04 | 4.08 | 50.71 | 0.03 | 0.98 | |||||||||||||||||||||||
| D033-1 | 32.274000 | 108.089000 | Calcite vein | 176.4 | 191.2 | 143.1 | 112.3 | 179.5 | -5.7 | -7.1 | -4.6 | -3.4 | -5.6 | ||||||||||||||||||||
| D033-2 | 32.278300 | 108.083900 | fibrous calcite vein | 165.3 | 171.2 | -6.2 | -6.6 | -105.5 | |||||||||||||||||||||||||
| D033-2 | 32.278300 | 108.083900 | bitumen vein in black limestone, Cambrian | 1.98 | |||||||||||||||||||||||||||||
| D033-2w | 32.278300 | 108.083900 | host rock, limestone containing bitumen, Cambrian | 2.31 | |||||||||||||||||||||||||||||
| D033-4 | 32.280100 | 108.083900 | fibrous calcite vein | 188.9 | -7.8 | -2.0 | -9.1 | ||||||||||||||||||||||||||
| D033-4 | 32.280100 | 108.083900 | host rock | 3.1 | -6.5 | 0.07 | 0.18 | 56.18 | 0.02 | 0.94 | |||||||||||||||||||||||
| D034-3 | 32.278900 | 108.064200 | fibrous calcite vein | 172.4 | 194.3 | -5.8 | -8.1 | 0.16 | 0.20 | 0.12 | 8.97 | 50.87 | 0.17 | 1.32 | |||||||||||||||||||
| D034-4 | 32.282800 | 108.058200 | Calcite vein | 177.1 | 141.6 | 193.7 | 142.3 | 159.7 | -5.3 | -5.9 | -8.2 | -4.0 | -3.6 | ||||||||||||||||||||
| D035-2 | 32.282800 | 108.058200 | fibrous calcite vein | 186.1 | -6.9 | ||||||||||||||||||||||||||||
| D036-1 | 32.281100 | 108.051500 | Calcite vein | 143.1 | 152.8 | 165.0 | 154.0 | -5.7 | -6.0 | -5.7 | -4.1 | ||||||||||||||||||||||
| D038-1 | 32.318100 | 107.990900 | fibrous calcite vein | 146.3 | 141.2 | -3.5 | -3.3 | ||||||||||||||||||||||||||
| D039-1 | 32.296300 | 107.966400 | bitumen vein in carbonaceous mudstone, Triassic | 1.81 | |||||||||||||||||||||||||||||
| D041-1 | 32.214700 | 108.008300 | fibrous calcite vein | 142.7 | 140.3 | 117.8 | -4.6 | -6.5 | -3.2 | ||||||||||||||||||||||||
| D046-1 | 32.112900 | 108.046100 | fibrous calcite vein | 147.8 | 133.6 | 143.0 | -5.1 | -3.7 | -5.3 | -113.6 | |||||||||||||||||||||||
| D046-2 | 32.112900 | 108.046100 | Calcite vein | 136.4 | 147.6 | 144.5 | 125.0 | -6.5 | -5.8 | -7.0 | -3.4 | ||||||||||||||||||||||
| D046-3 | 32.112900 | 108.046100 | fibrous calcite vein | 134.3 | -5.7 | -2.0 | -11.4 | 0.03 | 0.02 | 0.06 | 0.02 | 0.41 | 61.59 | 0.32 | 1.70 | 0.010 | |||||||||||||||||
| D046-3 | 32.112900 | 108.046100 | host rock | 3.1 | -4.5 | 0.21 | 0.25 | 0.12 | 2.98 | 53.69 | 0.12 | 1.03 | |||||||||||||||||||||
| D046-4 | 32.112900 | 108.046100 | Calcite vein | 144.0 | 137.4 | 132.4 | 143.0 | -5.8 | -5.5 | -4.6 | -5.3 | ||||||||||||||||||||||
| D046-5 | 32.112900 | 108.046100 | Calcite vein | 133.1 | 145.6 | 146.1 | -4.9 | -5.8 | -4.7 | ||||||||||||||||||||||||
| D057-5 | 31.939200 | 107.993000 | Calcite vein | 143.4 | 154.0 | 145.3 | -5.1 | -4.5 | -5.9 | -112.8 | |||||||||||||||||||||||
| D113-1 | 31.350000 | 108.516100 | bitumen vein in limestone, Triassic | 1.78 | |||||||||||||||||||||||||||||
| D113-1W | 31.350000 | 108.516100 | host rock, limestone containing bitumen, Triassic | 1.85 | |||||||||||||||||||||||||||||
| D114-1 | 31.360200 | 108.515000 | bitumen in pores of limestone, Triassic | 1.87 | |||||||||||||||||||||||||||||
| D114-3 | 31.360200 | 108.515000 | Calcite vein | 135.8 | 142.0 | -3.7 | -5.0 | ||||||||||||||||||||||||||
| D114-4 | 31.360200 | 108.515000 | Calcite vein | 146.1 | 137.2 | 154.6 | -6.7 | -6.3 | -6.4 | ||||||||||||||||||||||||
| D114-5 | 31.360200 | 108.515000 | Calcite vein | 142.6 | 138.2 | 147.9 | 136.4 | -6.1 | -5.7 | -4.9 | -5.4 | ||||||||||||||||||||||
| D119-1 | 31.462500 | 108.489800 | bitumen in pores of limestone, Triassic | 1.77 | |||||||||||||||||||||||||||||
| D121-3 | 31.503000 | 108.470700 | Calcite vein | 142.0 | 135.7 | 146.9 | -7.8 | -5.9 | -6.7 | ||||||||||||||||||||||||
| D121-4 | 31.503000 | 108.470700 | Calcite vein | 159.5 | 143.8 | 146.2 | 139.8 | -6.2 | -6.5 | -5.0 | -6.1 | ||||||||||||||||||||||
| D122-3 | 31.534500 | 108.471600 | bitumen vein in limestone, Permian | 1.80 | |||||||||||||||||||||||||||||
| D125-2 | 31.558800 | 108.488700 | Calcite vein | 152.1 | -5.7 | ||||||||||||||||||||||||||||
| D126-2 | 31.560100 | 108.489900 | bitumen in pores of limestone, Permian | 1.83 | |||||||||||||||||||||||||||||
| D126-2w | 31.560100 | 108.489900 | host rock, limestone containing bitumen, Permian | 1.96 | |||||||||||||||||||||||||||||
| D129-1 | 31.559400 | 108.516000 | Calcite vein | ||||||||||||||||||||||||||||||
| D140-1 | 31.569200 | 108.581900 | fibrous calcite vein | 143.2 | 141.0 | -6.2 | -6.5 | -108.7 | -110.2 | ||||||||||||||||||||||||
| D140-1 | 31.569200 | 108.581900 | bitumen vein in limestone, Permian | 1.91 | |||||||||||||||||||||||||||||
| D144-1 | 31.700600 | 108.641000 | fibrous calcite vein | 146.4 | 140.2 | -7.6 | -6.7 | -115.3 | |||||||||||||||||||||||||
| D144-1 | 31.700600 | 108.641000 | bitumen vein in limestone, Permian | 1.87 | |||||||||||||||||||||||||||||
| D144-1w | 31.700600 | 108.641000 | host rock, limestone containing bitumen, Permian | 1.95 | |||||||||||||||||||||||||||||
| D146-2 | 31.727300 | 108.570800 | fibrous calcite vein | 143.8 | -8.4 | ||||||||||||||||||||||||||||
| D147-1 | 31.761300 | 108.534700 | bitumen vein in limestone, Permian | 1.98 | |||||||||||||||||||||||||||||
| D148-1 | 31.763100 | 108.537100 | bitumen vein in siltstone, Silurian | 2.20 | |||||||||||||||||||||||||||||
| D149-1 | 31.765100 | 108.539900 | fibrous calcite vein | 154.9 | 150.4 | -6.9 | -6.3 | -2.9 | -11.3 | 0.01 | 0.01 | 0.28 | 58.03 | 0.20 | 1.78 | 0.130 | |||||||||||||||||
| D151-1 | 31.767800 | 108.541400 | fibrous calcite vein | 152.6 | 149.8 | 140.7 | -7.9 | -5.4 | -6.0 | -3.8 | -9.4 | ||||||||||||||||||||||
| D151-1 | 31.767800 | 108.541400 | bitumen vein in carbonaceous shale, Silurian | 2.31 | |||||||||||||||||||||||||||||
| D156-1 | 31.789400 | 108.591100 | bitumen in host rock limestone, Permian | 2.10 | |||||||||||||||||||||||||||||
| D157-1 | 31.790000 | 108.591600 | Calcite vein | 167.8 | 172.1 | 120.3 | 154.9 | 160.7 | -9.4 | -5.7 | -3.4 | -6.8 | -8.0 | 0.06 | 0.51 | 59.38 | 0.11 | 1.41 | |||||||||||||||
| D157-1 | 31.790000 | 108.591600 | bitumen vein in mudstone, Permian | 2.03 | |||||||||||||||||||||||||||||
| D159-1 | 31.806000 | 108.629500 | Calcite vein | 154.6 | 168.7 | 175.3 | 167.0 | -5.8 | -8.3 | -7.9 | -9.0 | ||||||||||||||||||||||
| D161-1 | 31.817400 | 108.643500 | bitumen in pores of limestone, Cambrian | 2.37 | |||||||||||||||||||||||||||||
| D161-1w | 31.817400 | 108.643500 | host rock , limestone containing bitumen, Cambrian | 2.32 | |||||||||||||||||||||||||||||
| D161-2 | 31.817400 | 108.643500 | fibrous calcite vein | 174.5 | 169.1 | -7.2 | -6.4 | -115.4 | |||||||||||||||||||||||||
| D161-2 | 31.817400 | 108.643500 | bitumen in pores of limestone limestone, Cambrian | 2.16 | |||||||||||||||||||||||||||||
| D163-1 | 31.941600 | 108.519700 | Calcite vein | 184.3 | 179.2 | 191.7 | -6.8 | -7.0 | |||||||||||||||||||||||||
| D168-1 | 31.957600 | 108.533800 | bitumen in pores of limestone, Permian | 1.75 | |||||||||||||||||||||||||||||
| D168-2 | 31.957600 | 108.533800 | fibrous calcite vein | 179.0 | -6.1 | -112.7 | |||||||||||||||||||||||||||
| D168-2 | 31.957600 | 108.533800 | bitumen in pores of limestone, Permian | 1.77 | |||||||||||||||||||||||||||||
| D168-3 | 31.957600 | 108.533800 | bitumen vein in limestone, Permian | 1.79 | |||||||||||||||||||||||||||||
| D169-2 | 31.625900 | 108.535100 | fibrous calcite vein | 188.4 | 179.2 | -8.4 | -7.7 | -3.9 | -8.2 | 0.02 | 0.22 | 56.93 | 0.13 | 1.55 |
