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Li, Rongxi; Dong, Shuwen; Lehrmann, Daniel; Duan, Lizhi (2013): (Table 1) Geochemical and geothermometry data from fibrous calcite vein fills in the Dabashan Fold Belt, China [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.811050, Supplement to: Li, R et al. (2013): Tectonically driven organic fluid migration in the Dabashan Foreland Belt: evidenced by geochemistry and geothermometry of vein-filling fibrous calcite with organic inclusions. Journal of Asian Earth Sciences, 75, 202-212, https://doi.org/10.1016/j.jseaes.2013.07.026

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Published: 2013-05-02DOI registered: 2013-05-30

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Abstract:
Fibrous calcite veins with organic inclusions have been widely considered as indicators of oil and gas generation and migration under overpressure. Abundant fibrous calcite veins containing organic-bearing inclusions occur in faulted Lower Paleozoic through Triassic hydrocarbon source rocks in the Dabashan Foreland Belt (DBF). d13CPDB and d18OPDB values of the fibrous calcite range from - 4.8 to -1.9 to per mil and - 12.8 to - 8.4 per mil respectively, which is lighter than that of associated carbonate host rocks ranging from - 1.7 to + 3.1 per mil and - 8.7 to - 4.5 per mil. A linear relationship between d13CPDB and d18OPDB indicates that the calcite veins were precipitated from a mixture of basinal and surface fluids. The fibrous calcite contains a variety of inclusions, such as solid bitumen, methane bearing all-liquid inclusions, and vapor-liquid aqueous inclusions. Homogenization temperatures of aqueous inclusions range from 140 to 196° with an average of 179°. Salinities of aqueous inclusions average 9.7 wt% NaCl. Independent temperatures from bitumen reflectance and inclusion phase relationships of aqueous and methane inclusions were used to determine fluid pressures. Results indicate high pressures, elevated above typical lithostatic confining pressure, from 150 to 200 MPa. The elevated salinity and high temperature and pressure conditions of the fibrous calcite veins argue against an origin solely from burial overpressure resulting from clay transformation and dehydration reactions. Instead fluid inclusion P-T data and geochemistry results and regional geology indicate abnormally high pressures during fluid migration. These findings indicate that tectonic stress generated fracture and fault fluid pathways and caused migration of organic bearing fluids from the DBF during the Yanshan orogeny.
Coverage:
Median Latitude: 32.049611 * Median Longitude: 108.319511 * South-bound Latitude: 31.350000 * West-bound Longitude: 107.617500 * North-bound Latitude: 32.522500 * East-bound Longitude: 108.643500
Date/Time Start: 2008-06-04T00:00:00 * Date/Time End: 2008-07-19T00:00:00
Event(s):
Dabashan_Foreland_Belt * Latitude Start: 31.350000 * Longitude Start: 107.617500 * Latitude End: 32.522500 * Longitude End: 108.535000 * Date/Time Start: 2008-06-04T00:00:00 * Date/Time End: 2008-07-19T00:00:00 * Location: Sichuan, Shaanxi, China * Method/Device: Sampling by hand (HAND)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Sample code/labelSample labelLi, Rongxi
LATITUDELatitudeGeocode
LONGITUDELongitudeGeocode
Lithology/composition/faciesLithologyLi, Rongxi
Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
10 Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
11 Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
12 Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
13 Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
14 Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
15 Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
16 Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
17 Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
18 Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
19 Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stageThm
20 Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stageThm
21 Maximal reflectance of bitumenRb%Li, RongxiMicrophotometer LEITZ MPV-3
22 δ13C, organic matterδ13C OM‰ PDBLi, RongxiMass spectrometer Finnigan MAT 251EM
23 δ18O, organic matterδ18O OMLi, RongxiMass spectrometer Finnigan MAT 251EM
24 Silicon dioxideSiO2%Li, RongxiElectron microprobe (EMP)Weight %
25 Aluminium oxideAl2O3%Li, RongxiElectron microprobe (EMP)Weight %
26 Sodium oxideNa2O%Li, RongxiElectron microprobe (EMP)Weight %
27 Potassium oxideK2O%Li, RongxiElectron microprobe (EMP)Weight %
28 Magnesium oxideMgO%Li, RongxiElectron microprobe (EMP)Weight %
29 Calcium oxideCaO%Li, RongxiElectron microprobe (EMP)Weight %
30 Manganese oxideMnO%Li, RongxiElectron microprobe (EMP)Weight %
31 Iron oxide, FeOFeO%Li, RongxiElectron microprobe (EMP)Weight %
32 Phosphorus pentoxideP2O5%Li, RongxiElectron microprobe (EMP)Weight %
33 Sulfite[SO3]2-%Li, RongxiElectron microprobe (EMP)Weight %
34 Titanium dioxideTiO2%Li, RongxiElectron microprobe (EMP)Weight %
Size:
726 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Sample label

Latitude

Longitude

Lithology

Th [°C]
(Linkam THMS600 microscope stage)

Th [°C]
(Linkam THMS600 microscope stage)

Th [°C]
(Linkam THMS600 microscope stage)

Th [°C]
(Linkam THMS600 microscope stage)

Th [°C]
(Linkam THMS600 microscope stage)
10 
Th [°C]
(Linkam THMS600 microscope stage)
11 
Th [°C]
(Linkam THMS600 microscope stage)
12 
Tm [°C]
(Linkam THMS600 microscope stage)
13 
Tm [°C]
(Linkam THMS600 microscope stage)
14 
Tm [°C]
(Linkam THMS600 microscope stage)
15 
Tm [°C]
(Linkam THMS600 microscope stage)
16 
Tm [°C]
(Linkam THMS600 microscope stage)
17 
Tm [°C]
(Linkam THMS600 microscope stage)
18 
Tm [°C]
(Linkam THMS600 microscope stage)
19 
Th [°C]
(Thm, Linkam THMS600 microscop...)
20 
Th [°C]
(Thm, Linkam THMS600 microscop...)
21 
Rb [%]
(Microphotometer LEITZ MPV-3)
22 
δ13C OM [‰ PDB]
(Mass spectrometer Finnigan MA...)
23 
δ18O OM []
(Mass spectrometer Finnigan MA...)
24 
SiO2 [%]
(Weight %, Electron microprobe...)
25 
Al2O3 [%]
(Weight %, Electron microprobe...)
26 
Na2O [%]
(Weight %, Electron microprobe...)
27 
K2O [%]
(Weight %, Electron microprobe...)
28 
MgO [%]
(Weight %, Electron microprobe...)
29 
CaO [%]
(Weight %, Electron microprobe...)
30 
MnO [%]
(Weight %, Electron microprobe...)
31 
FeO [%]
(Weight %, Electron microprobe...)
32 
P2O5 [%]
(Weight %, Electron microprobe...)
33 
[SO3]2- [%]
(Weight %, Electron microprobe...)
34 
TiO2 [%]
(Weight %, Electron microprobe...)
B002-132.340500107.617500fibrous calcite vein141.2139.6-4.1-3.9
B026-332.214700108.117500fibrous calcite vein144.7151.3146.9-5.7-6.0-5.6-110.4
B053-431.918700108.337500fibrous calcite vein154.6161.0-8.3-7.2
D001-232.522500108.517900Calcite vein212.1139.3184.0196.5191.4147.0-6.6-5.1-5.0-4.8-6.3-4.8
D010-332.470700108.438700Fibrous calcite169.8174.3-6.2-5.4-2.1-10.80.3655.460.130.56
D014-132.438300108.361500fibrous calcite vein187.4190.3-6.8-6.4-113.4
D014-132.438300108.361500bitumen vein2.03
D016-132.396700108.314400fibrous calcite vein162.7178.6167.4-6.8-6.1-7.7
D017-132.381300108.299500fibrous calcite vein186.5-7.3
D017-232.381300108.299500carbonaceous mudstone, Cambrian2.47
D017-332.354900108.277900fibrous calcite vein175.6184.4-8.6-6.3-107.1-1.9-12.80.030.020.040.1861.570.100.014
D017-332.354900108.277900fibrous calcite vein-1.7-6.1
D017-332.354900108.277900bitumen vein in limestone, Cambrian2.640.110.020.020.022.4149.260.031.420.010.021
D017-332.354900108.277900host rock
D017-432.354900108.277900bitumen vein2.41
D017-532.354900108.277900bitumen vein in limestone, Cambrian2.29
D017-632.354900108.277900fibrous calcite vein177.1-6.1
D018-132.336600108.238300bitumen vein in limestone, Cambrian2.61
D018-1w32.336600108.238300host rock, limestone containing bitumen, Cambrian2.63
D018-232.336600108.238300fibrous calcite vein188.6174.9182.7-9.4-8.8-7.7-108.7-106.8
D018-232.336600108.238300bitumen vein2.31
D019-132.336900108.238000fibrous calcite vein184.3-8.2-1.8-10.30.020.010.070.060.2564.690.201.390.015
D019-132.336900108.238000host rock1.4-8.70.100.210.011.8142.110.071.62
D020-132.336900108.238000Calcite vein201.5146.7214.6179.8139.4153.2-7.1-5.6-6.2-6.6-5.8-5.7-114.0
D020-232.336900108.238000Calcite vein194.5152.7166.4-8.4-5.7-4.8-105.5-109.2
D020-232.336900108.238000bitumen vein2.07
D021-132.322600108.231200fibrous calcite vein187.5-6.7
D021-232.322600108.231200Calcite vein203.7157.8184.0169.7176.0-8.8-6.8-6.1-8.2
D022-132.308000108.236400fibrous calcite vein199.2180.4-9.7-6.1-115.9-2.6-10.40.020.2554.370.041.670.011
D024-132.301500108.209500fibrous calcite vein174.3-6.8
D024-232.308000108.236400fibrous calcite vein187.6174.9-6.3-6.7-108.3-106.6-4.8-9.20.110.040.4257.040.101.87
D024-232.308000108.236400bitumen vein2.14
D025-132.288300108.200200bitumen vein2.27
D025-232.286700108.198700calcite veins179.1126.0199.4132.7189.3-6.4-5.2-7.9-5.4-6.9-113.7
D025-332.284200108.194200Quartz vein216.7196.4153.4224.7176.0134.8143.0-9.5-6.3-5.7-8.4-6.1-5.1-5.7
D026-132.283700108.193200fibrous calcite vein174.8182.0-7.8-7.7-4.3-8.40.030.040.020.3565.730.221.580.073
D026-132.283700108.193200host rock0.140.145.7654.760.241.04
D028-132.288300108.169600calcite vein184.6157.9176.0-8.4-5.4-6.1-115.7
D030-132.287200108.127800fibrous calcite vein168.3172.0-5.2-7.2-107.0-1.4-7.4
D030-132.287200108.127800fibrous calcite vein-1.9-10.10.080.030.010.040.3166.250.121.070.0170.03
D030-132.287200108.127800fibrous calcite vein2.1-6.7
D030-132.287200108.127800host rock0.250.400.044.0850.710.030.98
D033-132.274000108.089000Calcite vein176.4191.2143.1112.3179.5-5.7-7.1-4.6-3.4-5.6
D033-232.278300108.083900fibrous calcite vein165.3171.2-6.2-6.6-105.5
D033-232.278300108.083900bitumen vein in black limestone, Cambrian1.98
D033-2w32.278300108.083900host rock, limestone containing bitumen, Cambrian2.31
D033-432.280100108.083900fibrous calcite vein188.9-7.8-2.0-9.1
D033-432.280100108.083900host rock3.1-6.50.070.1856.180.020.94
D034-332.278900108.064200fibrous calcite vein172.4194.3-5.8-8.10.160.200.128.9750.870.171.32
D034-432.282800108.058200Calcite vein177.1141.6193.7142.3159.7-5.3-5.9-8.2-4.0-3.6
D035-232.282800108.058200fibrous calcite vein186.1-6.9
D036-132.281100108.051500Calcite vein143.1152.8165.0154.0-5.7-6.0-5.7-4.1
D038-132.318100107.990900fibrous calcite vein146.3141.2-3.5-3.3
D039-132.296300107.966400bitumen vein in carbonaceous mudstone, Triassic1.81
D041-132.214700108.008300fibrous calcite vein142.7140.3117.8-4.6-6.5-3.2
D046-132.112900108.046100fibrous calcite vein147.8133.6143.0-5.1-3.7-5.3-113.6
D046-232.112900108.046100Calcite vein136.4147.6144.5125.0-6.5-5.8-7.0-3.4
D046-332.112900108.046100fibrous calcite vein134.3-5.7-2.0-11.40.030.020.060.020.4161.590.321.700.010
D046-332.112900108.046100host rock3.1-4.50.210.250.122.9853.690.121.03
D046-432.112900108.046100Calcite vein144.0137.4132.4143.0-5.8-5.5-4.6-5.3
D046-532.112900108.046100Calcite vein133.1145.6146.1-4.9-5.8-4.7
D057-531.939200107.993000Calcite vein143.4154.0145.3-5.1-4.5-5.9-112.8
D113-131.350000108.516100bitumen vein in limestone, Triassic1.78
D113-1W31.350000108.516100host rock, limestone containing bitumen, Triassic1.85
D114-131.360200108.515000bitumen in pores of limestone, Triassic1.87
D114-331.360200108.515000Calcite vein135.8142.0-3.7-5.0
D114-431.360200108.515000Calcite vein146.1137.2154.6-6.7-6.3-6.4
D114-531.360200108.515000Calcite vein142.6138.2147.9136.4-6.1-5.7-4.9-5.4
D119-131.462500108.489800bitumen in pores of limestone, Triassic1.77
D121-331.503000108.470700Calcite vein142.0135.7146.9-7.8-5.9-6.7
D121-431.503000108.470700Calcite vein159.5143.8146.2139.8-6.2-6.5-5.0-6.1
D122-331.534500108.471600bitumen vein in limestone, Permian1.80
D125-231.558800108.488700Calcite vein152.1-5.7
D126-231.560100108.489900bitumen in pores of limestone, Permian1.83
D126-2w31.560100108.489900host rock, limestone containing bitumen, Permian1.96
D129-131.559400108.516000Calcite vein
D140-131.569200108.581900fibrous calcite vein143.2141.0-6.2-6.5-108.7-110.2
D140-131.569200108.581900bitumen vein in limestone, Permian1.91
D144-131.700600108.641000fibrous calcite vein146.4140.2-7.6-6.7-115.3
D144-131.700600108.641000bitumen vein in limestone, Permian1.87
D144-1w31.700600108.641000host rock, limestone containing bitumen, Permian1.95
D146-231.727300108.570800fibrous calcite vein143.8-8.4
D147-131.761300108.534700bitumen vein in limestone, Permian1.98
D148-131.763100108.537100bitumen vein in siltstone, Silurian2.20
D149-131.765100108.539900fibrous calcite vein154.9150.4-6.9-6.3-2.9-11.30.010.010.2858.030.201.780.130
D151-131.767800108.541400fibrous calcite vein152.6149.8140.7-7.9-5.4-6.0-3.8-9.4
D151-131.767800108.541400bitumen vein in carbonaceous shale, Silurian2.31
D156-131.789400108.591100bitumen in host rock limestone, Permian2.10
D157-131.790000108.591600Calcite vein167.8172.1120.3154.9160.7-9.4-5.7-3.4-6.8-8.00.060.5159.380.111.41
D157-131.790000108.591600bitumen vein in mudstone, Permian2.03
D159-131.806000108.629500Calcite vein154.6168.7175.3167.0-5.8-8.3-7.9-9.0
D161-131.817400108.643500bitumen in pores of limestone, Cambrian2.37
D161-1w31.817400108.643500host rock , limestone containing bitumen, Cambrian2.32
D161-231.817400108.643500fibrous calcite vein174.5169.1-7.2-6.4-115.4
D161-231.817400108.643500bitumen in pores of limestone limestone, Cambrian2.16
D163-131.941600108.519700Calcite vein184.3179.2191.7-6.8-7.0
D168-131.957600108.533800bitumen in pores of limestone, Permian1.75
D168-231.957600108.533800fibrous calcite vein179.0-6.1-112.7
D168-231.957600108.533800bitumen in pores of limestone, Permian1.77
D168-331.957600108.533800bitumen vein in limestone, Permian1.79
D169-231.625900108.535100fibrous calcite vein188.4179.2-8.4-7.7-3.9-8.20.020.2256.930.131.55