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Li, Rongxi; Dong, Shuwen; Lehrmann, Daniel; Duan, Lizhi (2013): (Table 1) Geochemical and geothermometry data from fibrous calcite vein fills in the Dabashan Fold Belt, China [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.811050, Supplement to: Li, R et al. (2013): Tectonically driven organic fluid migration in the Dabashan Foreland Belt: evidenced by geochemistry and geothermometry of vein-filling fibrous calcite with organic inclusions. Journal of Asian Earth Sciences, 75, 202-212, https://doi.org/10.1016/j.jseaes.2013.07.026

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Published: 2013-05-02DOI registered: 2013-05-30

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Abstract:
Fibrous calcite veins with organic inclusions have been widely considered as indicators of oil and gas generation and migration under overpressure. Abundant fibrous calcite veins containing organic-bearing inclusions occur in faulted Lower Paleozoic through Triassic hydrocarbon source rocks in the Dabashan Foreland Belt (DBF). d13CPDB and d18OPDB values of the fibrous calcite range from - 4.8 to -1.9 to per mil and - 12.8 to - 8.4 per mil respectively, which is lighter than that of associated carbonate host rocks ranging from - 1.7 to + 3.1 per mil and - 8.7 to - 4.5 per mil. A linear relationship between d13CPDB and d18OPDB indicates that the calcite veins were precipitated from a mixture of basinal and surface fluids. The fibrous calcite contains a variety of inclusions, such as solid bitumen, methane bearing all-liquid inclusions, and vapor-liquid aqueous inclusions. Homogenization temperatures of aqueous inclusions range from 140 to 196° with an average of 179°. Salinities of aqueous inclusions average 9.7 wt% NaCl. Independent temperatures from bitumen reflectance and inclusion phase relationships of aqueous and methane inclusions were used to determine fluid pressures. Results indicate high pressures, elevated above typical lithostatic confining pressure, from 150 to 200 MPa. The elevated salinity and high temperature and pressure conditions of the fibrous calcite veins argue against an origin solely from burial overpressure resulting from clay transformation and dehydration reactions. Instead fluid inclusion P-T data and geochemistry results and regional geology indicate abnormally high pressures during fluid migration. These findings indicate that tectonic stress generated fracture and fault fluid pathways and caused migration of organic bearing fluids from the DBF during the Yanshan orogeny.
Coverage:
Median Latitude: 32.049611 * Median Longitude: 108.319511 * South-bound Latitude: 31.350000 * West-bound Longitude: 107.617500 * North-bound Latitude: 32.522500 * East-bound Longitude: 108.643500
Date/Time Start: 2008-06-04T00:00:00 * Date/Time End: 2008-07-19T00:00:00
Event(s):
Dabashan_Foreland_Belt * Latitude Start: 31.350000 * Longitude Start: 107.617500 * Latitude End: 32.522500 * Longitude End: 108.535000 * Date/Time Start: 2008-06-04T00:00:00 * Date/Time End: 2008-07-19T00:00:00 * Location: Sichuan, Shaanxi, China * Method/Device: Sampling by hand (HAND)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Sample code/labelSample labelLi, Rongxi
2LATITUDELatitudeGeocode
3LONGITUDELongitudeGeocode
4Lithology/composition/faciesLithologyLi, Rongxi
5Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
6Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
7Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
8Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
9Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
10Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
11Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stage
12Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
13Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
14Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
15Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
16Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
17Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
18Freezing point depressionTm°CLi, RongxiLinkam THMS600 microscope stage
19Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stageThm
20Homogenization temperatureTh°CLi, RongxiLinkam THMS600 microscope stageThm
21Maximal reflectance of bitumenRb%Li, RongxiMicrophotometer LEITZ MPV-3
22δ13C, organic matterδ13C OM‰ PDBLi, RongxiMass spectrometer Finnigan MAT 251EM
23δ18O, organic matterδ18O OMLi, RongxiMass spectrometer Finnigan MAT 251EM
24Silicon dioxideSiO2%Li, RongxiElectron microprobe (EMP)Weight %
25Aluminium oxideAl2O3%Li, RongxiElectron microprobe (EMP)Weight %
26Sodium oxideNa2O%Li, RongxiElectron microprobe (EMP)Weight %
27Potassium oxideK2O%Li, RongxiElectron microprobe (EMP)Weight %
28Magnesium oxideMgO%Li, RongxiElectron microprobe (EMP)Weight %
29Calcium oxideCaO%Li, RongxiElectron microprobe (EMP)Weight %
30Manganese oxideMnO%Li, RongxiElectron microprobe (EMP)Weight %
31Iron oxide, FeOFeO%Li, RongxiElectron microprobe (EMP)Weight %
32Phosphorus pentoxideP2O5%Li, RongxiElectron microprobe (EMP)Weight %
33Sulfite[SO3]2-%Li, RongxiElectron microprobe (EMP)Weight %
34Titanium dioxideTiO2%Li, RongxiElectron microprobe (EMP)Weight %
Size:
726 data points

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