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Mottl, Michael J; Druffel, Ellen R M; Hart, Stanley R; Lawrence, James R; Saltzman, Eric S (1985): (Table 2) Composition of water samples from basement in DSDP Hole 83-504B [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.805113, In supplement to: Mottl, MJ et al. (1985): Chemistry of hot waters sampled from basaltic basement in Hole 504B, Deep Sea Drilling Project Leg 83, Costa Rica Rift. In: Anderson, RN; Honnorez, J; Becker, K; et al. (eds.), Initial Reports of the Deep Sea Drilling Project, Washington (U.S. Govt. Printing Office), 83, 315-328, https://doi.org/10.2973/dsdp.proc.83.115.1985

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Project(s):
Coverage:
Latitude: 1.227200 * Longitude: -83.730200
Date/Time Start: 1981-11-22T00:00:00 * Date/Time End: 1982-01-02T00:00:00
Minimum DEPTH, sediment/rock: 194.0 m * Maximum DEPTH, sediment/rock: 1285.5 m
Event(s):
83-504B * Latitude: 1.227200 * Longitude: -83.730200 * Date/Time Start: 1981-11-22T00:00:00 * Date/Time End: 1982-01-02T00:00:00 * Elevation: -3460.0 m * Penetration: 1350 m * Recovery: 107.7 m * Campaign: Leg83 * Basis: Glomar Challenger * Method/Device: Drilling/drill rig (DRILL) * Comment: Leg 83 of DSDP was devoted entirely to coring and experiments in Hole 504B, the deepest borehole to date into the oceanic crust. Hole 504B now extends over a kilometer into basement, nearly twice as far as any other DSDP hole, and it is the only DSDP hole to have clearly penetrated into the intrusive sheeted dikes that underlie the extrusive pillow lavas of the upper oceanic crust. At Hole 504B, Leg 83 continued an ongoing DSDP effort that began during Legs 68, 69, and 70 in 1979, and also included part of Leg 92 in 1983. 71 cores; 514 m cored; 0 m drilled; 21 % recovery
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
IdentificationIDMottl, Michael J
DEPTH, sediment/rockDepth sedmGeocode – mbsf
CommentCommentMottl, Michael J
pHpHMottl, Michael JTitration
SalinitySalMottl, Michael JTitration
Chlorinityclmmol/kgMottl, Michael JTitrationAs mmol/kg chloride, equals chlorinity (per mil) 35.453*1000
Alkalinity, totalATmmol(eq)/kgMottl, Michael JTitration
Sulfate[SO4]2-mmol/kgMottl, Michael JChromatographic
SodiumNa+mmol/kgMottl, Michael JCalculated, see reference(s)
10 PotassiumK+mmol/kgMottl, Michael JFlame atomic absorption spectrometry (FAAS)
11 CalciumCa2+mmol/kgMottl, Michael JTitration
12 MagnesiumMg2+mmol/kgMottl, Michael JTitration
13 StrontiumSr2+µmol/kgMottl, Michael JICP-OES, Inductively coupled plasma - optical emission spectrometry
14 BariumBa2+µmol/kgMottl, Michael JICP-OES, Inductively coupled plasma - optical emission spectrometry
15 RubidiumRbµmol/kgMottl, Michael JMass spectrometry
16 CaesiumCsµmol/kgMottl, Michael JMass spectrometry
17 BoronBµmol/kgMottl, Michael JICP-OES, Inductively coupled plasma - optical emission spectrometry
18 SiliconSimmol/kgMottl, Michael JColorimetry
19 AmmoniaNH3mmol/kgMottl, Michael JColorimetry
20 Nitrite[NO2]-µmol/kgMottl, Michael JColorimetry
21 Nitrate and Nitrite[NO3]- + [NO2]-µmol/kgMottl, Michael JAutoanalyzer (AA)
22 OxygenO2µmol/kgMottl, Michael JTitration, Winkler
23 Hydrogen sulfideH2Smmol/kgMottl, Michael JTitration, Winkler
24 Hydrogen sulfideH2Smmol/kgMottl, Michael JFlame atomic absorption spectrometry (FAAS)Values for the PA-3 aliquots are maxima, as they were exposed to the atmosphere and precipitated Fe-oxyhydroxides prior to analysis
25 Δ14CΔ14CMottl, Michael Jsee reference(s)# - As measured on combined 2C and 2D aliquots. Aliquots were not separated by one-way valves, which probably accounts for relative homogeneity
26 Δ14C, standard deviationΔ14C std dev±Mottl, Michael J# - As measured on combined 2C and 2D aliquots. Aliquots were not separated by one-way valves, which probably accounts for relative homogeneity. Uncertainties represent one std dev about the mean for replicate counts of single aliquot of each sample
27 δ34Sδ34S‰ CDTMottl, Michael JAutoanalyzer (AA)Of the dissolved sulfate sulfur only. These are preliminary data, uncorrected for the value of d18O in the SO2 gas. Correction is expected to lower these values by about 1.0 per mil
28 δ18Oδ18OMottl, Michael Jsee reference(s)
29 Strontium-87/Strontium-86 ratio87Sr/86SrMottl, Michael JMass spectrometry
30 Strontium-87/Strontium-86 ratio, error87Sr/86Sr e±Mottl, Michael J
Size:
458 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


ID

Depth sed [m]
(mbsf)

Comment

pH
(Titration)

Sal
(Titration)

cl [mmol/kg]
(As mmol/kg chloride, equals c...)

AT [mmol(eq)/kg]
(Titration)

[SO4]2- [mmol/kg]
(Chromatographic)

Na+ [mmol/kg]
(Calculated, see reference(s))
10 
K+ [mmol/kg]
(Flame atomic absorption spect...)
11 
Ca2+ [mmol/kg]
(Titration)
12 
Mg2+ [mmol/kg]
(Titration)
13 
Sr2+ [µmol/kg]
(ICP-OES, Inductively coupled ...)
14 
Ba2+ [µmol/kg]
(ICP-OES, Inductively coupled ...)
15 
Rb [µmol/kg]
(Mass spectrometry)
16 
Cs [µmol/kg]
(Mass spectrometry)
17 
B [µmol/kg]
(ICP-OES, Inductively coupled ...)
18 
Si [mmol/kg]
(Colorimetry)
19 
NH3 [mmol/kg]
(Colorimetry)
20 
[NO2]- [µmol/kg]
(Colorimetry)
21 
[NO3]- + [NO2]- [µmol/kg]
(Autoanalyzer)
22 
O2 [µmol/kg]
(Titration, Winkler)
23 
H2S [mmol/kg]
(Titration, Winkler)
24 
H2S [mmol/kg]
(Values for the PA-3 aliquots ...)
25 
Δ14C []
(# - As measured on combined 2...)
26 
Δ14C std dev [±]
(# - As measured on combined 2...)
27 
δ34S [‰ CDT]
(Of the dissolved sulfate sulf...)
28 
δ18O []
(see reference(s))
29 
87Sr/86Sr
(Mass spectrometry)
30 
87Sr/86Sr e [±]
Surface seawater (11/23/81)7.7134.1524.92.1427.0450.19.829.7450.7485.50.073720.005380.7202.01302320.2
PW-1, prime194.07.6035.2543.32.4528.2466.310.1210.2552.49100.00.153840.12000<0.010
PW-2, prime451.06.9735.2543.02.5928.1462.69.7517.1047.510.030
PW-2, overflow451.0pH, salinity, and chlorinity are as measured on the aliquot from the overflow chamber that is diluted with distilled water during sampling. Values for all other chemical species have been normalized to the chlorinity of the prime (undiluted) aliquot6.6716.5247.128.0459.49.5717.9645.6080.11.404850.715000.000
PW-3, prime650.06.8635.2541.02.9727.8466.39.9012.780.100
PW-3, overflow650.0pH, salinity, and chlorinity are as measured on the aliquot from the overflow chamber that is diluted with distilled water during sampling. Values for all other chemical species have been normalized to the chlorinity of the prime (undiluted) aliquot6.8020.9319.027.8466.29.2313.0748.7984.51.384620.472000.000
PA-1A (top)478.56.7435.2532.82.3427.5455.49.8213.1749.2389.00.775490.400000.0352.027.50.01400.027-2221419.8
PA-1B478.56.7635.2534.82.4727.0455.39.4714.7748.4089.60.934940.435000.0152.020.40.01300.030-2712519.9
PA-1C478.56.6835.2538.22.3426.0452.79.1120.6444.6591.10.785360.564000.0302.013.9<7.00.01100.028-2511419.9
PA-1D (bottom)478.56.8135.2545.02.5625.8458.39.0922.4043.3791.71.595480.622000.0102.010.4<4.00.00700.023-1921519.90.02
PA-1D via IDMS478.5As analyzed by S. R. Hart using isotope-dilution mass spectrometry. Accuracies are <0.5% for K and Sr, <1% for Rb, and 3% for Cs and Ba. Analytical uncertainties for 87Sr/86Sr given in the table are ± 2sigma8.8589.62.351.400.008740.0000.708770.00002
PA-2A (top)792.56.4934.9533.11.6219.0431.27.5036.6330.3083.01.307941.396000.095<0.210.60.02300.023411419.3
PA-2B792.56.3034.9544.11.8017.7441.47.3338.5527.6580.60.676061.280000.076<0.210.00.02200.012-56140.20
PA-2C792.56.5634.9545.52.5217.7438.27.2740.1428.7386.51.915881.800000.0830.52.50.0170#-242#1419.20.708030.00002
PA-2D (bottom)792.56.5134.9546.92.4817.6439.37.1840.1428.8286.31.315701.881000.0620.42.60.02200.036#-242#1419.3
PA-2D via IDMS792.5As analyzed by S. R. Hart using isotope-dilution mass spectrometry. Accuracies are <0.5% for K and Sr, <1% for Rb, and 3% for Cs and Ba. Analytical uncertainties for 87Sr/86Sr given in the table are ± 2sigma7.1083.31.911.720.013500.000
Surface seawater (12/23/81)8.0034.1521.32.199.8749.94<0.0100.00.2202.00.0000
SJ-1979.07.2434.1521.81.8426.9442.59.4414.0548.6582.61.024020.550000.012<0.40.3
SJ-21273.56.7333.8519.61.8327.2447.09.5411.2448.2887.80.584271.115000.000<0.20.5
PA-3A (top)1285.56.1333.8513.41.6326.4442.59.519.8647.9677.60.683540.298000.075<0.47.6<0.066
PA-3B1285.56.3333.8515.61.5526.4444.59.619.8248.0580.30.604500.314000.070<0.48.1<0.047
PA-3C1285.56.3633.6513.61.6826.5442.29.569.7748.4181.31.064550.288000.060<0.43.90.0008<0.063
PA-3D1285.56.4633.6518.41.7026.3446.69.549.7348.5182.30.624420.267000.070<0.41.60.0020<0.086
PA-3E1285.56.4933.8515.31.7126.4442.79.689.7048.9680.90.653540.278000.050<0.41.70.30.0000<0.090
PA-3F1285.56.5833.8521.51.4126.7449.19.649.8348.9085.00.693550.283000.0650.41.30.0120<0.024
PA-3G (bottom)1285.56.5633.8519.61.7226.9448.69.729.7948.5185.20.734010.319000.0653.0