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Schöps, Dietmar; Herzig, Peter M (1994): (Table 1) Determined and theoretical chemical composition of thaumasite of ODP Hole 135-841B [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.800253, Supplement to: Schöps, D; Herzig, PM (1994): Thaumasite in Lau Basin basaltic andesite, Hole 841B. In: Hawkins, J; Parson, L; Allan, J; et al. (eds.), Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program), 135, 647-651, https://doi.org/10.2973/odp.proc.sr.135.128.1994

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Abstract:
Hole 841B was drilled in the forearc region of the Lau Basin at a water depth of 4810 m. The hole penetrated a roughly 500-m-thick series of Miocene volcanic sediments with a number of basaltic to andesitic units (sills?) varying in thickness between 7 cm and 17 m. The volcanics are slightly to moderately altered and contain analcite, chabazite, natrolite-thompsonite, heulandite (?), prehnite, and quartz as secondary phases. In addition, thaumasite [Ca3Si(OH)6 * 12H2O](SO4)(CO3) was identified in the altered sequence. Sulfur isotope data of two thaumasite separates (+23.5 per mil and +21.1 per mil d34S) indicate a seawater origin of the sulfate sulfur. It is suggested that thaumasite is a product of low-temperature (<60 °C), seawater-derived CaCl2-rich fluids that were almost identical in composition to those presently circulating in the sub-seafloor.
Project(s):
Coverage:
Latitude: -23.346000 * Longitude: -175.297000
Date/Time Start: 1991-02-02T15:40:00 * Date/Time End: 1991-02-10T20:30:00
Minimum DEPTH, sediment/rock: 325.14 m * Maximum DEPTH, sediment/rock: 325.14 m
Event(s):
135-841B * Latitude: -23.346000 * Longitude: -175.297000 * Date/Time Start: 1991-02-02T15:40:00 * Date/Time End: 1991-02-10T20:30:00 * Elevation: -4821.0 m * Penetration: 834.2 m * Recovery: 182.54 m * Location: South Pacific Ocean * Campaign: Leg135 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 70 cores; 664.4 m cored; 0 m drilled; 27.5 % recovery
Comment:
Sediment depth is given in mbsf. Thaumasite = [Ca3Si (OH)6 * 12H2O](SO4)(CO3)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1DEPTH, sediment/rockDepth sedmGeocode
2Silicon dioxideSiO2%Schöps, DietmarX-ray fluorescence (XRF)
3Silicon dioxideSiO2%Schöps, Dietmartheoretical
4Titanium dioxideTiO2%Schöps, DietmarX-ray fluorescence (XRF)
5Aluminium oxideAl2O3%Schöps, DietmarX-ray fluorescence (XRF)
6Iron oxide, Fe2O3Fe2O3%Schöps, DietmarX-ray fluorescence (XRF)
7Manganese oxideMnO%Schöps, DietmarX-ray fluorescence (XRF)
8Magnesium oxideMgO%Schöps, DietmarX-ray fluorescence (XRF)
9Calcium oxideCaO%Schöps, DietmarX-ray fluorescence (XRF)
10Calcium oxideCaO%Schöps, Dietmartheoretical
11Sodium oxideNa2O%Schöps, DietmarX-ray fluorescence (XRF)
12Potassium oxideK2O%Schöps, DietmarX-ray fluorescence (XRF)
13Phosphorus pentoxideP2O5%Schöps, DietmarX-ray fluorescence (XRF)
14Sulfite[SO3]2-%Schöps, DietmarX-ray fluorescence (XRF)
15Sulfite[SO3]2-%Schöps, Dietmartheoretical
16Carbon dioxideCO2%Schöps, DietmarX-ray fluorescence (XRF)
17Carbon dioxideCO2%Schöps, Dietmartheoretical
18Water in rockH2O%Schöps, DietmarX-ray fluorescence (XRF)
19Water in rockH2O%Schöps, Dietmartheoretical
20Elements, totalTotal%Schöps, DietmarX-ray fluorescence (XRF)
21ScandiumScmg/kgSchöps, DietmarX-ray fluorescence (XRF)
22ChromiumCrmg/kgSchöps, DietmarX-ray fluorescence (XRF)
23CobaltComg/kgSchöps, DietmarX-ray fluorescence (XRF)
24BromineBrmg/kgSchöps, DietmarX-ray fluorescence (XRF)
25UraniumUmg/kgSchöps, DietmarX-ray fluorescence (XRF)
26NickelNimg/kgSchöps, DietmarX-ray fluorescence (XRF)
27ZincZnmg/kgSchöps, DietmarX-ray fluorescence (XRF)
28ArsenicAsmg/kgSchöps, DietmarX-ray fluorescence (XRF)
29SeleniumSemg/kgSchöps, DietmarX-ray fluorescence (XRF)
30RubidiumRbmg/kgSchöps, DietmarX-ray fluorescence (XRF)
31StrontiumSrmg/kgSchöps, DietmarX-ray fluorescence (XRF)
32MolybdenumMomg/kgSchöps, DietmarX-ray fluorescence (XRF)
33SilverAgmg/kgSchöps, DietmarX-ray fluorescence (XRF)
34CopperCumg/kgSchöps, DietmarX-ray fluorescence (XRF)
35NiobiumNbmg/kgSchöps, DietmarX-ray fluorescence (XRF)
36ZirconiumZrmg/kgSchöps, DietmarX-ray fluorescence (XRF)
37YttriumYmg/kgSchöps, DietmarX-ray fluorescence (XRF)
38GalliumGamg/kgSchöps, DietmarX-ray fluorescence (XRF)
39CobaltComg/kgSchöps, DietmarX-ray fluorescence (XRF)
40AntimonySbmg/kgSchöps, DietmarX-ray fluorescence (XRF)
41CaesiumCsmg/kgSchöps, DietmarX-ray fluorescence (XRF)
42BariumBamg/kgSchöps, DietmarX-ray fluorescence (XRF)
43HafniumHfmg/kgSchöps, DietmarX-ray fluorescence (XRF)
44TantalumTamg/kgSchöps, DietmarX-ray fluorescence (XRF)
45TungstenWmg/kgSchöps, DietmarX-ray fluorescence (XRF)
46ThoriumThmg/kgSchöps, DietmarX-ray fluorescence (XRF)
47LanthanumLamg/kgSchöps, DietmarX-ray fluorescence (XRF)
48CeriumCemg/kgSchöps, DietmarX-ray fluorescence (XRF)
49NeodymiumNdmg/kgSchöps, DietmarX-ray fluorescence (XRF)
50SamariumSmmg/kgSchöps, DietmarX-ray fluorescence (XRF)
51EuropiumEumg/kgSchöps, DietmarX-ray fluorescence (XRF)
52TerbiumTbmg/kgSchöps, DietmarX-ray fluorescence (XRF)
53YtterbiumYbmg/kgSchöps, DietmarX-ray fluorescence (XRF)
54LutetiumLumg/kgSchöps, DietmarX-ray fluorescence (XRF)
55GoldAung/kgSchöps, DietmarX-ray fluorescence (XRF)
56IridiumIrng/kgSchöps, DietmarX-ray fluorescence (XRF)
57SiliconSi# of ionsSchöps, DietmarCalculated based on oxygen number25 O-atoms
58AluminiumAl# of ionsSchöps, DietmarCalculated based on oxygen number25 O-atoms
59Iron 2+ and 3+Fe# of ionsSchöps, DietmarCalculated based on oxygen number25 O-atoms
60MagnesiumMg# of ionsSchöps, DietmarCalculated based on oxygen number25 O-atoms
61CalciumCa# of ionsSchöps, DietmarCalculated based on oxygen number25 O-atoms
62SodiumNa# of ionsSchöps, DietmarCalculated based on oxygen number25 O-atoms
63SulfurS# of ionsSchöps, DietmarCalculated based on oxygen number25 O-atoms
64CarbonC# of ionsSchöps, DietmarCalculated based on oxygen number25 O-atoms
65HydroxideOH# of ionsSchöps, DietmarCalculated based on oxygen number25 O-atoms
66WaterH2O# of ionsSchöps, DietmarCalculated based on oxygen number25 O-atoms
67SiliconSi# of ionsSchöps, DietmarCalculated(Si, Ca, Na, K, S) = 5
68AluminiumAl# of ionsSchöps, DietmarCalculated(Si, Ca, Na, K, S) = 5
69Iron 2+ and 3+Fe# of ionsSchöps, DietmarCalculated(Si, Ca, Na, K, S) = 5
70MagnesiumMg# of ionsSchöps, DietmarCalculated(Si, Ca, Na, K, S) = 5
71CalciumCa# of ionsSchöps, DietmarCalculated(Si, Ca, Na, K, S) = 5
72SodiumNa# of ionsSchöps, DietmarCalculated(Si, Ca, Na, K, S) = 5
73SulfurS# of ionsSchöps, DietmarCalculated(Si, Ca, Na, K, S) = 5
74CarbonC# of ionsSchöps, DietmarCalculated(Si, Ca, Na, K, S) = 5
75HydroxideOH# of ionsSchöps, DietmarCalculated(Si, Ca, Na, K, S) = 5
76WaterH2O# of ionsSchöps, DietmarCalculated(Si, Ca, Na, K, S) = 5
Size:
75 data points

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