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Prezbindowski, D R; Pittman, Edward D (1987): (Table 1) Calcite, siderite, and stable isotopes δ¹³C and δ¹⁸O at DSDP Hole 93-603B [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.788946, Supplement to: Prezbindowski, DR; Pittman, ED (1987): Petrology and geochemistry of sandstones in the Lower Cretaceous Submarine Fan Complex, Deep Sea Drilling Project Hole 603B. In: van Hinte, JE; Wise, SW Jr; et al. (eds.), Initial Reports of the Deep Sea Drilling Project, Washington (U.S. Govt. Printing Office), 93, 961-976, https://doi.org/10.2973/dsdp.proc.93.135.1987

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Abstract:
Diagenesis of the fine-grained, feldspathic sandstones in the Lower Cretaceous submarine fan complex cored in DSDP Hole 603B can be considered to have occurred in three stages: (1) replacement of matrix and framework grains by pyrite, siderite, phillipsite (?), and particularly by ferroan calcite; (2) dissolution of ferroan calcite and feldspars to produce secondary macroporosity; and (3) development of sparse feldspar and quartz overgrowths, and authigenic modification of remnant matrix. Only ferroan calcite is a volumetrically important diagenetic mineral phase (up to 50 vol.%).
Matrix in thin sandstone turbidite deposits has been extensively replaced by ferroan calcite. Carbon stable isotope data suggest that organic diagenesis had only a minor influence on calcite precipitation. Oxygen stable isotope data indicate that the minimum average calcite precipitation temperature was 40° C. Preliminary calculations show that steadystate diffusion of Ca+ + from the dissolution of nannoplankton skeletal material in the interbedded pelagic marls to the associated sandstones is a feasible transport mechanism.
A thick sandstone unit from 1234-1263 m sub-bottom is extensively replaced by calcite near the upper and lower contacts. Farther into the sand body away from the contacts, the sandstone has good secondary porosity resulting from the dissolution of ferroan calcite that partially replaced matrix and framework grains. The central portion of the thick sand appears to be a channel with high-energy clean sand. We believe that the channel provided a conduit for focused flow of diagenetic compactional fluids responsible for dissolution. Focused flow may be the result of the earlier lithification of the pelagic limestones and thin-bedded sandstones which, then formed vertical permeability barriers. Calcite dissolution has occurred and may still be occurring at temperatures less than 65°C.
Project(s):
Coverage:
Latitude: 35.495200 * Longitude: -70.028500
Date/Time Start: 1983-05-05T00:00:00 * Date/Time End: 1983-05-05T00:00:00
Minimum Elevation: -4633.0 m * Maximum Elevation: -4633.0 m
Event(s):
93-603B * Latitude: 35.495200 * Longitude: -70.028500 * Date/Time: 1983-05-05T00:00:00 * Elevation: -4633.0 m * Penetration: 1576.2 m * Recovery: 485.6 m * Campaign: Leg93 * Basis: Glomar Challenger * Method/Device: Drilling/drill rig (DRILL) * Comment: 74 cores; 674.6 m cored; 0 m drilled; 72 % recovery
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Sample code/labelSample labelPrezbindowski, D R
CalciteCal%Prezbindowski, D RElectron microprobe ARL SEMQ
SideriteSd%Prezbindowski, D RElectron microprobe ARL SEMQ<1 = traces
δ13C, carbonateδ13C carb‰ PDBPrezbindowski, D RMass spectrometer Finnigan MAT 251
δ18O, carbonateδ18O carb‰ PDBPrezbindowski, D RMass spectrometer Finnigan MAT 251
Size:
160 data points

Data

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Sample label

Cal [%]

Sd [%]

δ13C carb [‰ PDB]

δ18O carb [‰ PDB]
93-603B-46-1,55200-6.9-5.6
93-603B-46-1,60300-10.1-5.9
93-603B-46-2,30-32<5<1-0.8-3.0
93-603B-47-1,35-39<50-3.0-3.1
93-603B-47-1,69-73<50-0.1-1.3
93-603B-47-1,54-66<5<1-0.4-3.0
93-603B-48-1,47-51<500.7-0.8
93-603B-50-1,96-1042500.6-3.0
93-603B-51-1,16-23501.2-2.6
93-603B-51-3,88-922001.0-3.3
93-603B-53-1,41-43150-0.6-8.4
93-603B-53-1,47-50150-0.8-6.3
93-603B-53-1,51-55850-0.3-3.7
93-603B-55-2,15-201501.4-2.4
93-603B-55-4,93-952501.7-2.6
93-603B-57-4,55-56<501.2-2.3
93-603B-57-4,61-6650-0.6-8.3
93-603B-57-4,69-75300-0.4-8.5
93-603B-58-1,61-65200-0.9-7.9
93-603B-61-1,86-91800-0.1-4.4
93-603B-62-2,50-568000.2-4.5
93-603B-62-2,56-578500.2-4.2
93-603B-66-1,7-10<500.7-2.6
93-603B-66-1,7-100<5-1.7-6.7
93-603B-66-2,110-1134501.4-7.4
93-603B-66-3,109-1143001.1-7.5
93-603B-66-4,45-494000.2-8.3
93-603B-66-5,28-333500.6-8.4
93-603B-66-5,49-54<501.4-3.1
93-603B-66-5,49-540<5-1.1-10.3
93-603B-68-2,92-952501.0-8.0
93-603B-71-4,68-715<12.0-2.8