<?xml version="1.0" encoding="UTF-8"?><md:MetaData xmlns:md="http://www.pangaea.de/MetaData" version="2026-04-13">
<md:citation id="dataset786364">
<md:author id="dataset.author898">
<md:lastName>Dickens</md:lastName>
<md:firstName>Gerald Roy</md:firstName>
<md:eMail>DICKENSG@tcd.ie</md:eMail>
<md:orcid>0000-0003-2869-4860</md:orcid>
</md:author>
<md:year>2002</md:year>
<md:title>(Table T1) Manganese concentration in pore waters from ODP Leg 181 sites, southwest Pacific</md:title>
<md:type id="dataset.reftype10" includeInCitation="true">dataset</md:type>
<md:URI>https://doi.org/10.1594/PANGAEA.786364</md:URI>
<md:supplementTo id="ref36777">
<md:author id="ref36777.author898">
<md:lastName>Dickens</md:lastName>
<md:firstName>Gerald Roy</md:firstName>
<md:eMail>DICKENSG@tcd.ie</md:eMail>
<md:orcid>0000-0003-2869-4860</md:orcid>
</md:author>
<md:year>2002</md:year>
<md:title>Data report: Dissolved manganese concentrations in deep drill holes off New Zealand (ODP Leg 181)</md:title>
<md:type id="ref36777.reftype15">book chapter</md:type>
<md:source>In: Richter, C (ed.) Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program)</md:source>
<md:volume>181</md:volume>
<md:URI>https://doi.org/10.2973/odp.proc.sr.181.202.2002</md:URI>
<md:pages>1-5</md:pages>
</md:supplementTo>
</md:citation>
<md:abstract>During Leg 181, seven locations (Sites 1119-1125) were drilled off the eastern coast of New Zealand. Although the sites were primarily targeted to reconstruct the stratigraphy and paleoceanography of the region (Shipboard Scientific Party, 1999, doi:10.2973/odp.proc.ir.181.101.2000), they are particularly interesting from a geochemical perspective because, as clearly evidenced by shipboard pore water and gas analyses, recovered sediment cores span an exceptional range of chemical environments. Pore water alkalinity, NH4+, SO4**2-, and PO4**3- concentrations, as well as headspace CH4 concentrations, indicate significant differences in sediment redox conditions across the region (Shipboard Scientific Party, 1999, doi:10.2973/odp.proc.ir.181.101.2000). The distribution of solid and dissolved manganese plays an important role in geochemical interpretations of such sedimentary environments (e.g., Froelich et al., 1979, doi:10.1016/0016-7037(79)90095-4; Thamdrup and Dalsgaard, 2000, doi:10.1016/S0016-7037(00)00496-8). Dissolved Mn2+ concentrations of pore waters at four sites (1119, 1122, 1123, and 1125) drilled during Leg 181 are presented in this report.</md:abstract>
<md:extent>
<md:geographic>
<md:westBoundLongitude>172.3933</md:westBoundLongitude>
<md:eastBoundLongitude>-171.49898</md:eastBoundLongitude>
<md:southBoundLatitude>-46.57968</md:southBoundLatitude>
<md:northBoundLatitude>-41.78578</md:northBoundLatitude>
<md:meanLongitude>-176.6529775</md:meanLongitude>
<md:meanLatitude>-43.5465575</md:meanLatitude>
</md:geographic>
<md:temporal>
<md:minDateTime>1998-08-23T10:20:00</md:minDateTime>
<md:maxDateTime>1998-10-06T17:30:00</md:maxDateTime>
</md:temporal>
<md:elevation geocodeId="geocode1" name="DEPTH, sediment/rock" unit="m">
<md:min>1.4</md:min>
<md:max>591.8</md:max>
</md:elevation>
</md:extent>
<md:project id="project3" type="International">
<md:label>ODP</md:label>
<md:name>Ocean Drilling Program</md:name>
<md:URI>https://www-odp.tamu.edu:443/</md:URI>
<md:institution id="project3.inst34">
<md:name>Ocean Drilling Program, Texas A&amp;M University</md:name>
<md:optionalName>ODP</md:optionalName>
<md:URI>http://www-odp.tamu.edu/</md:URI>
<md:ROR>https://ror.org/01f5ytq51</md:ROR>
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<md:label>181-1119B</md:label>
<md:latitude>-44.75553</md:latitude>
<md:longitude>172.3933</md:longitude>
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<md:name>South Pacific Ocean</md:name>
</md:location>
<md:elevation>-396.8</md:elevation>
<md:dateTime>1998-08-23T10:20:00</md:dateTime>
<md:dateTime2>1998-08-24T00:20:00</md:dateTime2>
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<md:label>Leg181</md:label>
<md:name warning="deprecated">Leg181</md:name>
<md:dateTime>1998-08-05T00:00:00</md:dateTime>
<md:start warning="deprecated">1998-08-05</md:start>
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<md:responsible>Carter, Robert M</md:responsible>
<md:chiefScientist warning="deprecated">Carter, Robert M</md:chiefScientist>
<md:responsible>McCave, I Nicholas</md:responsible>
<md:chiefScientist warning="deprecated">McCave, I Nicholas</md:chiefScientist>
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<md:name>Drilling/drill rig</md:name>
<md:optionalName>DRILL</md:optionalName>
</md:method>
<md:attribute attid="19162" name="Penetration">155.8 m</md:attribute>
<md:attribute attid="19163" name="Recovery">164.47 m</md:attribute>
<md:comment>17 cores; 155.8 m cored; 0 m drilled; 105.6 % recovery</md:comment>
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<md:label>181-1122A</md:label>
<md:latitude>-46.57968</md:latitude>
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<md:location id="event2034470.term21005">
<md:name>South Pacific Ocean</md:name>
</md:location>
<md:elevation>-4435.0</md:elevation>
<md:dateTime>1998-09-04T10:45:00</md:dateTime>
<md:dateTime2>1998-09-07T04:15:00</md:dateTime2>
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<md:label>Leg181</md:label>
<md:name warning="deprecated">Leg181</md:name>
<md:dateTime>1998-08-05T00:00:00</md:dateTime>
<md:start warning="deprecated">1998-08-05</md:start>
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</md:basis>
<md:responsible>Carter, Robert M</md:responsible>
<md:chiefScientist warning="deprecated">Carter, Robert M</md:chiefScientist>
<md:responsible>McCave, I Nicholas</md:responsible>
<md:chiefScientist warning="deprecated">McCave, I Nicholas</md:chiefScientist>
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<md:name>Drilling/drill rig</md:name>
<md:optionalName>DRILL</md:optionalName>
</md:method>
<md:attribute attid="19162" name="Penetration">123.9 m</md:attribute>
<md:attribute attid="19163" name="Recovery">87.46 m</md:attribute>
<md:comment>13 cores; 123.9 m cored; 0 m drilled; 70.6 % recovery</md:comment>
</md:event>
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<md:label>181-1122C</md:label>
<md:latitude>-46.57966</md:latitude>
<md:longitude>-177.3937</md:longitude>
<md:location id="event2034472.term21005">
<md:name>South Pacific Ocean</md:name>
</md:location>
<md:elevation>-4431.8</md:elevation>
<md:dateTime>1998-09-07T06:25:00</md:dateTime>
<md:dateTime2>1998-09-12T08:00:00</md:dateTime2>
<md:campaign displayTypeName="Campaign" id="event2034472.campaign3383774" legacyId="event2034472.campaign21652" typeName="Generic Campaign">
<md:label>Leg181</md:label>
<md:name warning="deprecated">Leg181</md:name>
<md:dateTime>1998-08-05T00:00:00</md:dateTime>
<md:start warning="deprecated">1998-08-05</md:start>
<md:dateTime2>1998-10-06T00:00:00</md:dateTime2>
<md:end warning="deprecated">1998-10-06</md:end>
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<md:URI>https://www-odp.tamu.edu:443/resolutn.html</md:URI>
</md:basis>
<md:responsible>Carter, Robert M</md:responsible>
<md:chiefScientist warning="deprecated">Carter, Robert M</md:chiefScientist>
<md:responsible>McCave, I Nicholas</md:responsible>
<md:chiefScientist warning="deprecated">McCave, I Nicholas</md:chiefScientist>
<md:attribute attid="76863" name="Report">doi:10.2973/odp.proc.ir.181.2000</md:attribute>
</md:campaign>
<md:basis id="event2034472.basis5">
<md:name>Joides Resolution</md:name>
<md:URI>https://www-odp.tamu.edu:443/resolutn.html</md:URI>
</md:basis>
<md:method id="event2034472.method10974">
<md:name>Drilling/drill rig</md:name>
<md:optionalName>DRILL</md:optionalName>
</md:method>
<md:attribute attid="19162" name="Penetration">627.4 m</md:attribute>
<md:attribute attid="19163" name="Recovery">351.44 m</md:attribute>
<md:comment>68 cores; 627.4 m cored; 0 m drilled; 56 % recovery</md:comment>
</md:event>
<md:event displayTypeName="Event" id="event2034473" typeName="Generic Event">
<md:label>181-1123A</md:label>
<md:latitude>-41.78623</md:latitude>
<md:longitude>-171.499</md:longitude>
<md:location id="event2034473.term21005">
<md:name>South Pacific Ocean</md:name>
</md:location>
<md:elevation>-3290.1</md:elevation>
<md:dateTime>1998-09-12T08:00:00</md:dateTime>
<md:dateTime2>1998-09-14T23:55:00</md:dateTime2>
<md:campaign displayTypeName="Campaign" id="event2034473.campaign3383774" legacyId="event2034473.campaign21652" typeName="Generic Campaign">
<md:label>Leg181</md:label>
<md:name warning="deprecated">Leg181</md:name>
<md:dateTime>1998-08-05T00:00:00</md:dateTime>
<md:start warning="deprecated">1998-08-05</md:start>
<md:dateTime2>1998-10-06T00:00:00</md:dateTime2>
<md:end warning="deprecated">1998-10-06</md:end>
<md:basis id="event2034473.campaign3383774.basis5">
<md:name>Joides Resolution</md:name>
<md:URI>https://www-odp.tamu.edu:443/resolutn.html</md:URI>
</md:basis>
<md:responsible>Carter, Robert M</md:responsible>
<md:chiefScientist warning="deprecated">Carter, Robert M</md:chiefScientist>
<md:responsible>McCave, I Nicholas</md:responsible>
<md:chiefScientist warning="deprecated">McCave, I Nicholas</md:chiefScientist>
<md:attribute attid="76863" name="Report">doi:10.2973/odp.proc.ir.181.2000</md:attribute>
</md:campaign>
<md:basis id="event2034473.basis5">
<md:name>Joides Resolution</md:name>
<md:URI>https://www-odp.tamu.edu:443/resolutn.html</md:URI>
</md:basis>
<md:method id="event2034473.method10974">
<md:name>Drilling/drill rig</md:name>
<md:optionalName>DRILL</md:optionalName>
</md:method>
<md:attribute attid="19162" name="Penetration">158.1 m</md:attribute>
<md:attribute attid="19163" name="Recovery">158.63 m</md:attribute>
<md:comment>17 cores; 158.1 m cored; 0 m drilled; 100.3 % recovery</md:comment>
</md:event>
<md:event displayTypeName="Event" id="event2034474" typeName="Generic Event">
<md:label>181-1123B</md:label>
<md:latitude>-41.786</md:latitude>
<md:longitude>-171.49898</md:longitude>
<md:location id="event2034474.term21005">
<md:name>South Pacific Ocean</md:name>
</md:location>
<md:elevation>-3289.8</md:elevation>
<md:dateTime>1998-09-14T23:55:00</md:dateTime>
<md:dateTime2>1998-09-19T09:55:00</md:dateTime2>
<md:campaign displayTypeName="Campaign" id="event2034474.campaign3383774" legacyId="event2034474.campaign21652" typeName="Generic Campaign">
<md:label>Leg181</md:label>
<md:name warning="deprecated">Leg181</md:name>
<md:dateTime>1998-08-05T00:00:00</md:dateTime>
<md:start warning="deprecated">1998-08-05</md:start>
<md:dateTime2>1998-10-06T00:00:00</md:dateTime2>
<md:end warning="deprecated">1998-10-06</md:end>
<md:basis id="event2034474.campaign3383774.basis5">
<md:name>Joides Resolution</md:name>
<md:URI>https://www-odp.tamu.edu:443/resolutn.html</md:URI>
</md:basis>
<md:responsible>Carter, Robert M</md:responsible>
<md:chiefScientist warning="deprecated">Carter, Robert M</md:chiefScientist>
<md:responsible>McCave, I Nicholas</md:responsible>
<md:chiefScientist warning="deprecated">McCave, I Nicholas</md:chiefScientist>
<md:attribute attid="76863" name="Report">doi:10.2973/odp.proc.ir.181.2000</md:attribute>
</md:campaign>
<md:basis id="event2034474.basis5">
<md:name>Joides Resolution</md:name>
<md:URI>https://www-odp.tamu.edu:443/resolutn.html</md:URI>
</md:basis>
<md:method id="event2034474.method10974">
<md:name>Drilling/drill rig</md:name>
<md:optionalName>DRILL</md:optionalName>
</md:method>
<md:attribute attid="19162" name="Penetration">489 m</md:attribute>
<md:attribute attid="19163" name="Recovery">451.4 m</md:attribute>
<md:comment>52 cores; 489 m cored; 0 m drilled; 92.3 % recovery</md:comment>
</md:event>
<md:event displayTypeName="Event" id="event2034475" typeName="Generic Event">
<md:label>181-1123C</md:label>
<md:latitude>-41.78578</md:latitude>
<md:longitude>-171.499</md:longitude>
<md:location id="event2034475.term21005">
<md:name>South Pacific Ocean</md:name>
</md:location>
<md:elevation>-3290.1</md:elevation>
<md:dateTime>1998-09-19T09:55:00</md:dateTime>
<md:dateTime2>1998-09-24T10:00:00</md:dateTime2>
<md:campaign displayTypeName="Campaign" id="event2034475.campaign3383774" legacyId="event2034475.campaign21652" typeName="Generic Campaign">
<md:label>Leg181</md:label>
<md:name warning="deprecated">Leg181</md:name>
<md:dateTime>1998-08-05T00:00:00</md:dateTime>
<md:start warning="deprecated">1998-08-05</md:start>
<md:dateTime2>1998-10-06T00:00:00</md:dateTime2>
<md:end warning="deprecated">1998-10-06</md:end>
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<md:responsible>Carter, Robert M</md:responsible>
<md:chiefScientist warning="deprecated">Carter, Robert M</md:chiefScientist>
<md:responsible>McCave, I Nicholas</md:responsible>
<md:chiefScientist warning="deprecated">McCave, I Nicholas</md:chiefScientist>
<md:attribute attid="76863" name="Report">doi:10.2973/odp.proc.ir.181.2000</md:attribute>
</md:campaign>
<md:basis id="event2034475.basis5">
<md:name>Joides Resolution</md:name>
<md:URI>https://www-odp.tamu.edu:443/resolutn.html</md:URI>
</md:basis>
<md:method id="event2034475.method10974">
<md:name>Drilling/drill rig</md:name>
<md:optionalName>DRILL</md:optionalName>
</md:method>
<md:attribute attid="19162" name="Penetration">632.8 m</md:attribute>
<md:attribute attid="19163" name="Recovery">289.44 m</md:attribute>
<md:comment>33 cores; 309.9 m cored; 322.9 m drilled; 93.4 % recovery</md:comment>
</md:event>
<md:event displayTypeName="Event" id="event2034480" typeName="Generic Event">
<md:label>181-1125A</md:label>
<md:latitude>-42.54993</md:latitude>
<md:longitude>-178.16648</md:longitude>
<md:location id="event2034480.term21005">
<md:name>South Pacific Ocean</md:name>
</md:location>
<md:elevation>-1364.6</md:elevation>
<md:dateTime>1998-10-01T23:30:00</md:dateTime>
<md:dateTime2>1998-10-03T20:00:00</md:dateTime2>
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<md:dateTime>1998-08-05T00:00:00</md:dateTime>
<md:start warning="deprecated">1998-08-05</md:start>
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<md:responsible>Carter, Robert M</md:responsible>
<md:chiefScientist warning="deprecated">Carter, Robert M</md:chiefScientist>
<md:responsible>McCave, I Nicholas</md:responsible>
<md:chiefScientist warning="deprecated">McCave, I Nicholas</md:chiefScientist>
<md:attribute attid="76863" name="Report">doi:10.2973/odp.proc.ir.181.2000</md:attribute>
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<md:basis id="event2034480.basis5">
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<md:name>Drilling/drill rig</md:name>
<md:optionalName>DRILL</md:optionalName>
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<md:attribute attid="19162" name="Penetration">203.5 m</md:attribute>
<md:attribute attid="19163" name="Recovery">209.07 m</md:attribute>
<md:comment>22 cores; 203.5 m cored; 0 m drilled; 102.7 % recovery</md:comment>
</md:event>
<md:event displayTypeName="Event" id="event2034481" typeName="Generic Event">
<md:label>181-1125B</md:label>
<md:latitude>-42.54965</md:latitude>
<md:longitude>-178.16645</md:longitude>
<md:location id="event2034481.term21005">
<md:name>South Pacific Ocean</md:name>
</md:location>
<md:elevation>-1365.6</md:elevation>
<md:dateTime>1998-10-03T20:00:00</md:dateTime>
<md:dateTime2>1998-10-06T17:30:00</md:dateTime2>
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<md:dateTime>1998-08-05T00:00:00</md:dateTime>
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<md:responsible>Carter, Robert M</md:responsible>
<md:chiefScientist warning="deprecated">Carter, Robert M</md:chiefScientist>
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<md:chiefScientist warning="deprecated">McCave, I Nicholas</md:chiefScientist>
<md:attribute attid="76863" name="Report">doi:10.2973/odp.proc.ir.181.2000</md:attribute>
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<md:basis id="event2034481.basis5">
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<md:name>Drilling/drill rig</md:name>
<md:optionalName>DRILL</md:optionalName>
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<md:attribute attid="19162" name="Penetration">552.1 m</md:attribute>
<md:attribute attid="19163" name="Recovery">511.56 m</md:attribute>
<md:comment>58 cores; 552.1 m cored; 0 m drilled; 92.7 % recovery</md:comment>
</md:event>
<md:size unit="data points">329</md:size>
<md:license id="license101">
<md:label>CC-BY-3.0</md:label>
<md:name>Creative Commons Attribution 3.0 Unported</md:name>
<md:URI>https://creativecommons.org/licenses/by/3.0/</md:URI>
</md:license>
<md:comment>DEPTH, sediment is given in mbsf.</md:comment>
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<md:caption>Depth sed [m]</md:caption>
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<md:name>Depth, composite</md:name>
<md:shortName>Depth comp</md:shortName>
<md:unit>mcd</md:unit>
<md:term endOffset="5" fragment="1" id="col6.ds11781266.param2.term1073131" semanticURI="urn:obo:pato:term:0001595" startOffset="0" terminologyId="14" terminologyLabel="PATO">
<md:name>depth</md:name>
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<md:term id="col6.ds11781266.param2.term43884" semanticURI="http://qudt.org/1.1/vocab/quantity#LuminousIntensity" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Luminous Intensity</md:name>
<md:optionalName>J</md:optionalName>
<md:URI>http://dbpedia.org/resource/Luminous_intensity</md:URI>
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<md:PI id="col6.ds11781266.pi898">
<md:lastName>Dickens</md:lastName>
<md:firstName>Gerald Roy</md:firstName>
<md:eMail>DICKENSG@tcd.ie</md:eMail>
<md:orcid>0000-0003-2869-4860</md:orcid>
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<md:caption>Depth comp [mcd]</md:caption>
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<md:matrixColumn col="7" format="#0.0" id="col7.ds11781267" source="data" type="numeric">
<md:parameter id="col7.ds11781267.param64">
<md:name>Manganese</md:name>
<md:shortName>Mn</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col7.ds11781267.param64.term38521" semanticURI="http://purl.obolibrary.org/obo/CHEBI_18291" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>manganese</md:name>
<md:optionalName>Mn</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:18291</md:URI>
</md:term>
<md:term id="col7.ds11781267.param64.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col7.ds11781267.method125">
<md:name>Inductively coupled plasma - mass spectrometry (ICP-MS)</md:name>
<md:term id="col7.ds11781267.method125.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
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<md:term id="col7.ds11781267.method125.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
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<md:PI id="col7.ds11781267.pi898">
<md:lastName>Dickens</md:lastName>
<md:firstName>Gerald Roy</md:firstName>
<md:eMail>DICKENSG@tcd.ie</md:eMail>
<md:orcid>0000-0003-2869-4860</md:orcid>
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<md:caption>Mn [µmol/l]</md:caption>
</md:matrixColumn>
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<md:technicalInfo>
<md:entry key="xmlLastModified" value="2026-05-01T03:14:49Z"/>
<md:entry key="lastModified" value="2025-07-15T13:46:13"/>
<md:entry key="filename" value="Leg181_Mn-porewater"/>
<md:entry key="mimeType" value="text/tab-separated-values"/>
<md:entry key="status" value="published"/>
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<md:entry key="DOIRegistryStatus" value="registered"/>
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<md:entry key="DOIRegistrationDate" value="2012-08-15T03:10:55"/>
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