<?xml version="1.0" encoding="UTF-8"?><md:MetaData xmlns:md="http://www.pangaea.de/MetaData" version="2026-04-13">
<md:citation id="dataset771986">
<md:author id="dataset.author482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:author>
<md:author id="dataset.author25857">
<md:lastName>Domeyer</md:lastName>
<md:firstName>Bettina</md:firstName>
<md:eMail>bdomeyer@geomar.de</md:eMail>
</md:author>
<md:author id="dataset.author25856">
<md:lastName>Bleyer</md:lastName>
<md:firstName>Anke</md:firstName>
<md:eMail>ableyer@geomar.de</md:eMail>
</md:author>
<md:year>2011</md:year>
<md:title>Geochemistry of sediment core AL355_311</md:title>
<md:type id="dataset.reftype10" includeInCitation="true">dataset</md:type>
<md:source id="dataset.sourceinst6" semanticURI="https://ror.org/02h2x0161" type="institution">IFM-GEOMAR Leibniz-Institute of Marine Sciences, Kiel University</md:source>
<md:URI>https://doi.org/10.1594/PANGAEA.771986</md:URI>
<md:dateTime>2011-11-29T13:44:15</md:dateTime>
</md:citation>
<md:extent>
<md:geographic>
<md:westBoundLongitude>20.72483</md:westBoundLongitude>
<md:eastBoundLongitude>20.72483</md:eastBoundLongitude>
<md:southBoundLatitude>57.4415</md:southBoundLatitude>
<md:northBoundLatitude>57.4415</md:northBoundLatitude>
<md:meanLongitude>20.72483</md:meanLongitude>
<md:meanLatitude>57.4415</md:meanLatitude>
</md:geographic>
<md:temporal>
<md:minDateTime>2010-06-01T08:00:00</md:minDateTime>
<md:maxDateTime>2010-06-01T08:00:00</md:maxDateTime>
</md:temporal>
<md:elevation geocodeId="geocode1" name="DEPTH, sediment/rock" unit="m">
<md:min>0.0</md:min>
<md:max>0.265</md:max>
</md:elevation>
<md:topoType id="topotype3">vertical profile</md:topoType>
</md:extent>
<md:project id="project4122" type="EU">
<md:label>HYPOX</md:label>
<md:name>In situ monitoring of oxygen depletion in hypoxic ecosystems of coastal and open seas and land-locked water bodies</md:name>
<md:URI>https://cordis.europa.eu/project/id/226213</md:URI>
</md:project>
<md:award id="award58">
<md:funder id="award58.funder20486" semanticURI="doi:10.13039/100011102">
<md:name>Seventh Framework Programme of the European Commission</md:name>
<md:optionalName>FP7</md:optionalName>
<md:crossrefFunderId>https://doi.org/10.13039/100011102</md:crossrefFunderId>
</md:funder>
<md:number>226213</md:number>
<md:title>In situ monitoring of oxygen depletion in hypoxic ecosystems of coastal and open seas and land-locked water bodies</md:title>
<md:URI>https://cordis.europa.eu/project/id/226213</md:URI>
</md:award>
<md:event displayTypeName="Event" id="event2652237" typeName="Generic Event">
<md:label>AL355_311</md:label>
<md:optionalLabel>MUC2</md:optionalLabel>
<md:latitude>57.4415</md:latitude>
<md:longitude>20.72483</md:longitude>
<md:location id="event2652237.loc1.term20625">
<md:name>Baltic Sea</md:name>
</md:location>
<md:elevation>-65.0</md:elevation>
<md:dateTime>2010-06-01T08:00:00</md:dateTime>
<md:campaign displayTypeName="Campaign" id="event2652237.campaign3385506" legacyId="event2652237.campaign36879" typeName="Generic Campaign">
<md:label>AL355</md:label>
<md:name warning="deprecated">AL355</md:name>
<md:location id="event2652237.campaign3385506.loc1.term40384">
<md:name>Kiel, Germany</md:name>
</md:location>
<md:dateTime>2010-05-29T00:00:00</md:dateTime>
<md:start warning="deprecated">2010-05-29</md:start>
<md:location2 id="event2652237.campaign3385506.loc2.term40384">
<md:name>Kiel, Germany</md:name>
</md:location2>
<md:dateTime2>2010-06-21T00:00:00</md:dateTime2>
<md:end warning="deprecated">2010-06-21</md:end>
<md:basis id="event2652237.campaign3385506.basis25">
<md:name>Alkor (1990)</md:name>
<md:URI>https://www2.bsh.de/aktdat/dod/fahrtplanung/Alkor.htm</md:URI>
<md:callSign>DBND</md:callSign>
<md:IMOnumber>8905880</md:IMOnumber>
</md:basis>
<md:responsible>Pfannkuche, Olaf</md:responsible>
<md:chiefScientist warning="deprecated">Pfannkuche, Olaf</md:chiefScientist>
<md:attribute attid="76863" name="Report">doi:10.3289/CR_AL355</md:attribute>
<md:attribute attid="2055" name="BSH ID">20100331</md:attribute>
<md:comment>48-10, HYPOX, OFOS</md:comment>
</md:campaign>
<md:basis id="event2652237.basis25">
<md:name>Alkor (1990)</md:name>
<md:URI>https://www2.bsh.de/aktdat/dod/fahrtplanung/Alkor.htm</md:URI>
<md:callSign>DBND</md:callSign>
<md:IMOnumber>8905880</md:IMOnumber>
</md:basis>
<md:method id="event2652237.method10668">
<md:name>MultiCorer</md:name>
<md:optionalName>MUC</md:optionalName>
</md:method>
</md:event>
<md:size unit="data points">642</md:size>
<md:license id="license101">
<md:label>CC-BY-3.0</md:label>
<md:name>Creative Commons Attribution 3.0 Unported</md:name>
<md:URI>https://creativecommons.org/licenses/by/3.0/</md:URI>
</md:license>
<md:comment>Iodide data need to be multiplied by factor 1.142</md:comment>
<md:matrixColumn behaviour="1" col="0" format="#0.000" id="col0.ds1422592" source="geocode" type="numeric">
<md:parameter id="col0.ds1422592.geocode1">
<md:name>DEPTH, sediment/rock</md:name>
<md:shortName>Depth sed</md:shortName>
<md:unit>m</md:unit>
<md:term endOffset="5" fragment="1" id="col0.ds1422592.geocode1.term1073131" semanticURI="urn:obo:pato:term:0001595" startOffset="0" terminologyId="14" terminologyLabel="PATO">
<md:name>depth</md:name>
<md:URI>http://purl.obolibrary.org/obo/PATO_0001595</md:URI>
</md:term>
<md:term endOffset="15" fragment="2" id="col0.ds1422592.geocode1.term38263" startOffset="7" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>sediment</md:name>
<md:URI>http://purl.obolibrary.org/obo/ENVO_00002007</md:URI>
</md:term>
<md:term endOffset="20" fragment="3" id="col0.ds1422592.geocode1.term41056" startOffset="16" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>rock</md:name>
</md:term>
<md:term id="col0.ds1422592.geocode1.term43863" semanticURI="http://qudt.org/1.1/vocab/quantity#Length" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Length</md:name>
<md:optionalName>L</md:optionalName>
<md:URI>http://dbpedia.org/resource/Length</md:URI>
</md:term>
</md:parameter>
<md:caption>Depth sed [m]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="1" format="#0.000" id="col1.ds12289763" source="data" type="numeric">
<md:parameter id="col1.ds12289763.param762">
<md:name>Alkalinity, total</md:name>
<md:shortName>AT</md:shortName>
<md:unit>mmol(Eq)/l</md:unit>
<md:term endOffset="17" fragment="1" id="col1.ds12289763.param762.term38253" startOffset="12" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>total</md:name>
<md:URI>https://www.oxforddictionaries.com/definition/american_english/total</md:URI>
</md:term>
<md:term id="col1.ds12289763.param762.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col1.ds12289763.method7467">
<md:name>Titration, Pavlova</md:name>
</md:method>
<md:PI id="col1.ds12289763.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>AT [mmol(Eq)/l] (main sample, Titration, Pavlova)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="2" format="#0.000" id="col2.ds12289764" source="data" type="numeric">
<md:parameter id="col2.ds12289764.param2216">
<md:name>Boron</md:name>
<md:shortName>B</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term id="col2.ds12289764.param2216.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col2.ds12289764.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col2.ds12289764.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col2.ds12289764.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col2.ds12289764.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>B [mmol/l] (main sample, ICP, Inductively...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="3" format="#0.000" id="col3.ds12289765" source="data" type="numeric">
<md:parameter id="col3.ds12289765.param2216">
<md:name>Boron</md:name>
<md:shortName>B</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term id="col3.ds12289765.param2216.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col3.ds12289765.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col3.ds12289765.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col3.ds12289765.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col3.ds12289765.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>sampled with rhizones</md:comment>
<md:caption>B [mmol/l] (sampled with rhizones, ICP, I...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="4" format="#0.000" id="col4.ds12289766" source="data" type="numeric">
<md:parameter id="col4.ds12289766.param722">
<md:name>Barium</md:name>
<md:shortName>Ba</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="6" fragment="1" id="col4.ds12289766.param722.term40966" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>barium</md:name>
</md:term>
<md:term id="col4.ds12289766.param722.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col4.ds12289766.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col4.ds12289766.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col4.ds12289766.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col4.ds12289766.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Ba [µmol/l] (main sample, ICP, Inductively...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="5" format="#0.000" id="col5.ds12289767" source="data" type="numeric">
<md:parameter id="col5.ds12289767.param722">
<md:name>Barium</md:name>
<md:shortName>Ba</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="6" fragment="1" id="col5.ds12289767.param722.term40966" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>barium</md:name>
</md:term>
<md:term id="col5.ds12289767.param722.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col5.ds12289767.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col5.ds12289767.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col5.ds12289767.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col5.ds12289767.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>sampled with rhizones</md:comment>
<md:caption>Ba [µmol/l] (sampled with rhizones, ICP, I...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="6" format="##0.000" id="col6.ds12289768" source="data" type="numeric">
<md:parameter id="col6.ds12289768.param161330">
<md:name>Bromide</md:name>
<md:shortName>Br-</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col6.ds12289768.param161330.term1073605" semanticURI="http://purl.obolibrary.org/obo/CHEBI_15858" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>bromide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_15858</md:URI>
</md:term>
<md:term id="col6.ds12289768.param161330.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col6.ds12289768.method68">
<md:name>Ion chromatography</md:name>
<md:term id="col6.ds12289768.method68.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col6.ds12289768.method68.term2299500" semanticURI="SDN:L22::TOOL0884" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>Scripps Institution of Oceanography Hydrographic Doppler Sonar System</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L22/current/TOOL0884/</md:URI>
</md:term>
</md:method>
<md:PI id="col6.ds12289768.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Br- [µmol/l] (main sample, Ion chromatography)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="7" format="#0.0000" id="col7.ds12289769" source="data" type="numeric">
<md:parameter id="col7.ds12289769.param67">
<md:name>Carbon, organic, total</md:name>
<md:shortName>TOC</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="6" fragment="1" id="col7.ds12289769.param67.term38477" semanticURI="http://purl.obolibrary.org/obo/CHEBI_27594" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>carbon</md:name>
<md:optionalName>C</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:27594</md:URI>
</md:term>
<md:term endOffset="15" fragment="2" id="col7.ds12289769.param67.term44419" startOffset="8" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>organic</md:name>
</md:term>
<md:term endOffset="22" fragment="3" id="col7.ds12289769.param67.term38253" startOffset="17" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>total</md:name>
<md:URI>https://www.oxforddictionaries.com/definition/american_english/total</md:URI>
</md:term>
<md:term id="col7.ds12289769.param67.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col7.ds12289769.method4623">
<md:name>Element analyser CHN, Carlo Erba</md:name>
<md:term id="col7.ds12289769.method4623.term67625" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chemical property sensors</md:name>
</md:term>
<md:term id="col7.ds12289769.method4623.term2299833" semanticURI="SDN:L22::TOOL0631" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>CHN elemental analyser</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L22/current/TOOL0631/</md:URI>
</md:term>
</md:method>
<md:PI id="col7.ds12289769.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>TOC [%] (main sample, Element analyser...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="8" format="#0.00" id="col8.ds12289770" source="data" type="numeric">
<md:parameter id="col8.ds12289770.param59">
<md:name>Calcium</md:name>
<md:shortName>Ca</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col8.ds12289770.param59.term38520" semanticURI="http://purl.obolibrary.org/obo/CHEBI_22984" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>calcium</md:name>
<md:optionalName>Ca</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:22984</md:URI>
</md:term>
<md:term id="col8.ds12289770.param59.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col8.ds12289770.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col8.ds12289770.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col8.ds12289770.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col8.ds12289770.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Ca [mmol/l] (main sample, ICP, Inductively...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="9" format="#0.00" id="col9.ds12289771" source="data" type="numeric">
<md:parameter id="col9.ds12289771.param59">
<md:name>Calcium</md:name>
<md:shortName>Ca</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col9.ds12289771.param59.term38520" semanticURI="http://purl.obolibrary.org/obo/CHEBI_22984" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>calcium</md:name>
<md:optionalName>Ca</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:22984</md:URI>
</md:term>
<md:term id="col9.ds12289771.param59.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col9.ds12289771.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col9.ds12289771.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col9.ds12289771.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col9.ds12289771.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>sampled with rhizones</md:comment>
<md:caption>Ca [mmol/l] (sampled with rhizones, ICP, I...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="10" format="#0.000" id="col10.ds12289772" source="data" type="numeric">
<md:parameter id="col10.ds12289772.param70">
<md:name>Calcium carbonate</md:name>
<md:shortName>CaCO3</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="17" fragment="1" id="col10.ds12289772.param70.term1074204" semanticURI="http://purl.obolibrary.org/obo/CHEBI_3311" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>calcium carbonate</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_3311</md:URI>
</md:term>
<md:term id="col10.ds12289772.param70.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col10.ds12289772.method4623">
<md:name>Element analyser CHN, Carlo Erba</md:name>
<md:term id="col10.ds12289772.method4623.term67625" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chemical property sensors</md:name>
</md:term>
<md:term id="col10.ds12289772.method4623.term2299833" semanticURI="SDN:L22::TOOL0631" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>CHN elemental analyser</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L22/current/TOOL0631/</md:URI>
</md:term>
</md:method>
<md:PI id="col10.ds12289772.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>CaCO3 [%] (main sample, Element analyser...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="11" format="##0.000" id="col11.ds12289773" source="data" type="numeric">
<md:parameter id="col11.ds12289773.param54">
<md:name>Chloride</md:name>
<md:shortName>Cl-</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="8" fragment="1" id="col11.ds12289773.param54.term1073174" semanticURI="http://purl.obolibrary.org/obo/CHEBI_17996" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>chloride</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_17996</md:URI>
</md:term>
<md:term id="col11.ds12289773.param54.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col11.ds12289773.method68">
<md:name>Ion chromatography</md:name>
<md:term id="col11.ds12289773.method68.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col11.ds12289773.method68.term2299500" semanticURI="SDN:L22::TOOL0884" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>Scripps Institution of Oceanography Hydrographic Doppler Sonar System</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L22/current/TOOL0884/</md:URI>
</md:term>
</md:method>
<md:PI id="col11.ds12289773.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Cl- [mmol/l] (main sample, Ion chromatography)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="12" format="##0.00" id="col12.ds12289774" source="data" type="numeric">
<md:parameter id="col12.ds12289774.param63">
<md:name>Iron</md:name>
<md:shortName>Fe</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term id="col12.ds12289774.param63.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col12.ds12289774.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col12.ds12289774.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col12.ds12289774.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col12.ds12289774.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Fe [µmol/l] (main sample, ICP, Inductively...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="13" format="##0.00" id="col13.ds12289775" source="data" type="numeric">
<md:parameter id="col13.ds12289775.param63">
<md:name>Iron</md:name>
<md:shortName>Fe</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term id="col13.ds12289775.param63.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col13.ds12289775.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col13.ds12289775.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col13.ds12289775.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col13.ds12289775.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>sampled with rhizones</md:comment>
<md:caption>Fe [µmol/l] (sampled with rhizones, ICP, I...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="14" format="#0.00" id="col14.ds12289776" source="data" type="numeric">
<md:parameter id="col14.ds12289776.param19">
<md:name>Water content, wet mass</md:name>
<md:shortName>Water wm</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="13" fragment="1" id="col14.ds12289776.param19.term40555" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>water content</md:name>
</md:term>
<md:term endOffset="23" fragment="2" id="col14.ds12289776.param19.term38563" startOffset="15" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>wet mass</md:name>
</md:term>
<md:term id="col14.ds12289776.param19.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:PI id="col14.ds12289776.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Water wm [%] (main sample)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="15" format="###0.000" id="col15.ds12289777" source="data" type="numeric">
<md:parameter id="col15.ds12289777.param2267">
<md:name>Hydrogen sulfide</md:name>
<md:shortName>H2S</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="16" fragment="1" id="col15.ds12289777.param2267.term1073771" semanticURI="http://purl.obolibrary.org/obo/CHEBI_16136" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>hydrogen sulfide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_16136</md:URI>
</md:term>
<md:term id="col15.ds12289777.param2267.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col15.ds12289777.method72">
<md:name>Photometry</md:name>
</md:method>
<md:PI id="col15.ds12289777.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>H2S [µmol/l] (main sample, Photometry)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="16" format="#0.000" id="col16.ds12289778" source="data" type="numeric">
<md:parameter id="col16.ds12289778.param16140">
<md:name>Iodide</md:name>
<md:shortName>I-</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="6" fragment="1" id="col16.ds12289778.param16140.term1073884" semanticURI="http://purl.obolibrary.org/obo/CHEBI_16382" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>iodide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_16382</md:URI>
</md:term>
<md:term id="col16.ds12289778.param16140.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col16.ds12289778.method68">
<md:name>Ion chromatography</md:name>
<md:term id="col16.ds12289778.method68.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col16.ds12289778.method68.term2299500" semanticURI="SDN:L22::TOOL0884" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>Scripps Institution of Oceanography Hydrographic Doppler Sonar System</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L22/current/TOOL0884/</md:URI>
</md:term>
</md:method>
<md:PI id="col16.ds12289778.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>I- [µmol/l] (main sample, Ion chromatography)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="17" format="#0.0" id="col17.ds12289779" source="data" type="numeric">
<md:parameter id="col17.ds12289779.param57">
<md:name>Potassium</md:name>
<md:shortName>K</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col17.ds12289779.param57.term40134" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>potassium</md:name>
<md:optionalName>K</md:optionalName>
</md:term>
<md:term id="col17.ds12289779.param57.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col17.ds12289779.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col17.ds12289779.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col17.ds12289779.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col17.ds12289779.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>K [mmol/l] (main sample, ICP, Inductively...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="18" format="#0.0" id="col18.ds12289780" source="data" type="numeric">
<md:parameter id="col18.ds12289780.param57">
<md:name>Potassium</md:name>
<md:shortName>K</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col18.ds12289780.param57.term40134" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>potassium</md:name>
<md:optionalName>K</md:optionalName>
</md:term>
<md:term id="col18.ds12289780.param57.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col18.ds12289780.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col18.ds12289780.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col18.ds12289780.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col18.ds12289780.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>sampled with rhizones</md:comment>
<md:caption>K [mmol/l] (sampled with rhizones, ICP, I...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="19" format="#0.0" id="col19.ds12289781" source="data" type="numeric">
<md:parameter id="col19.ds12289781.param2212">
<md:name>Lithium</md:name>
<md:shortName>Li</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term id="col19.ds12289781.param2212.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col19.ds12289781.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col19.ds12289781.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col19.ds12289781.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col19.ds12289781.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Li [µmol/l] (main sample, ICP, Inductively...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="20" format="#0.0" id="col20.ds12289782" source="data" type="numeric">
<md:parameter id="col20.ds12289782.param2212">
<md:name>Lithium</md:name>
<md:shortName>Li</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term id="col20.ds12289782.param2212.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col20.ds12289782.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col20.ds12289782.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col20.ds12289782.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col20.ds12289782.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>sampled with rhizones</md:comment>
<md:caption>Li [µmol/l] (sampled with rhizones, ICP, I...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="21" format="#0.0" id="col21.ds12289783" source="data" type="numeric">
<md:parameter id="col21.ds12289783.param60">
<md:name>Magnesium</md:name>
<md:shortName>Mg</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col21.ds12289783.param60.term40665" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>magnesium</md:name>
</md:term>
<md:term id="col21.ds12289783.param60.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col21.ds12289783.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col21.ds12289783.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col21.ds12289783.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col21.ds12289783.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Mg [mmol/l] (main sample, ICP, Inductively...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="22" format="#0.0" id="col22.ds12289784" source="data" type="numeric">
<md:parameter id="col22.ds12289784.param60">
<md:name>Magnesium</md:name>
<md:shortName>Mg</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col22.ds12289784.param60.term40665" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>magnesium</md:name>
</md:term>
<md:term id="col22.ds12289784.param60.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col22.ds12289784.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col22.ds12289784.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col22.ds12289784.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col22.ds12289784.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>sampled with rhizones</md:comment>
<md:caption>Mg [mmol/l] (sampled with rhizones, ICP, I...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="23" format="#0.00" id="col23.ds12289785" source="data" type="numeric">
<md:parameter id="col23.ds12289785.param64">
<md:name>Manganese</md:name>
<md:shortName>Mn</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col23.ds12289785.param64.term38521" semanticURI="http://purl.obolibrary.org/obo/CHEBI_18291" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>manganese</md:name>
<md:optionalName>Mn</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:18291</md:URI>
</md:term>
<md:term id="col23.ds12289785.param64.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col23.ds12289785.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col23.ds12289785.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col23.ds12289785.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col23.ds12289785.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Mn [µmol/l] (main sample, ICP, Inductively...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="24" format="#0.00" id="col24.ds12289786" source="data" type="numeric">
<md:parameter id="col24.ds12289786.param64">
<md:name>Manganese</md:name>
<md:shortName>Mn</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col24.ds12289786.param64.term38521" semanticURI="http://purl.obolibrary.org/obo/CHEBI_18291" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>manganese</md:name>
<md:optionalName>Mn</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:18291</md:URI>
</md:term>
<md:term id="col24.ds12289786.param64.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col24.ds12289786.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col24.ds12289786.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col24.ds12289786.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col24.ds12289786.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>sampled with rhizones</md:comment>
<md:caption>Mn [µmol/l] (sampled with rhizones, ICP, I...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="25" format="##0" id="col25.ds12289788" source="data" type="numeric">
<md:parameter id="col25.ds12289788.param58">
<md:name>Sodium</md:name>
<md:shortName>Na</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="6" fragment="1" id="col25.ds12289788.param58.term41048" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>sodium</md:name>
</md:term>
<md:term id="col25.ds12289788.param58.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col25.ds12289788.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col25.ds12289788.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col25.ds12289788.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col25.ds12289788.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Na [mmol/l] (main sample, ICP, Inductively...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="26" format="##0" id="col26.ds12289789" source="data" type="numeric">
<md:parameter id="col26.ds12289789.param58">
<md:name>Sodium</md:name>
<md:shortName>Na</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="6" fragment="1" id="col26.ds12289789.param58.term41048" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>sodium</md:name>
</md:term>
<md:term id="col26.ds12289789.param58.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col26.ds12289789.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col26.ds12289789.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col26.ds12289789.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col26.ds12289789.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>sampled with rhizones</md:comment>
<md:caption>Na [mmol/l] (sampled with rhizones, ICP, I...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="27" format="###0.000" id="col27.ds12289790" source="data" type="numeric">
<md:parameter id="col27.ds12289790.param52">
<md:name>Ammonium</md:name>
<md:shortName>[NH4]+</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="8" fragment="1" id="col27.ds12289790.param52.term1073173" semanticURI="http://purl.obolibrary.org/obo/CHEBI_28938" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>ammonium</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_28938</md:URI>
</md:term>
<md:term id="col27.ds12289790.param52.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col27.ds12289790.method72">
<md:name>Photometry</md:name>
</md:method>
<md:PI id="col27.ds12289790.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>[NH4]+ [µmol/l] (main sample, Photometry)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="28" format="##0.000" id="col28.ds12289805" source="data" type="numeric">
<md:parameter id="col28.ds12289805.param52">
<md:name>Ammonium</md:name>
<md:shortName>[NH4]+</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="8" fragment="1" id="col28.ds12289805.param52.term1073173" semanticURI="http://purl.obolibrary.org/obo/CHEBI_28938" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>ammonium</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_28938</md:URI>
</md:term>
<md:term id="col28.ds12289805.param52.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col28.ds12289805.method72">
<md:name>Photometry</md:name>
</md:method>
<md:PI id="col28.ds12289805.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>sampled with rhizones</md:comment>
<md:caption>[NH4]+ [µmol/l] (sampled with rhizones, Photom...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="29" format="#0.000" id="col29.ds12289791" source="data" type="numeric">
<md:parameter id="col29.ds12289791.param757">
<md:name>Nitrite</md:name>
<md:shortName>[NO2]-</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col29.ds12289791.param757.term1073483" semanticURI="http://purl.obolibrary.org/obo/CHEBI_16301" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>nitrite</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_16301</md:URI>
</md:term>
<md:term id="col29.ds12289791.param757.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col29.ds12289791.method72">
<md:name>Photometry</md:name>
</md:method>
<md:PI id="col29.ds12289791.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>[NO2]- [µmol/l] (main sample, Photometry)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="30" format="#0.0000" id="col30.ds12289792" source="data" type="numeric">
<md:parameter id="col30.ds12289792.param756">
<md:name>Nitrate</md:name>
<md:shortName>[NO3]-</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col30.ds12289792.param756.term1073482" semanticURI="http://purl.obolibrary.org/obo/CHEBI_17632" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>nitrate</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_17632</md:URI>
</md:term>
<md:term id="col30.ds12289792.param756.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col30.ds12289792.method72">
<md:name>Photometry</md:name>
</md:method>
<md:PI id="col30.ds12289792.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>[NO3]- [µmol/l] (main sample, Photometry)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="31" format="##0.000" id="col31.ds12289793" source="data" type="numeric">
<md:parameter id="col31.ds12289793.param758">
<md:name>Phosphate</md:name>
<md:shortName>[PO4]3-</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col31.ds12289793.param758.term1073484" semanticURI="http://purl.obolibrary.org/obo/CHEBI_26020" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>phosphate</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_26020</md:URI>
</md:term>
<md:term id="col31.ds12289793.param758.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col31.ds12289793.method72">
<md:name>Photometry</md:name>
</md:method>
<md:PI id="col31.ds12289793.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>[PO4]3- [µmol/l] (main sample, Photometry)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="32" format="#0.000" id="col32.ds12289794" source="data" type="numeric">
<md:parameter id="col32.ds12289794.param758">
<md:name>Phosphate</md:name>
<md:shortName>[PO4]3-</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col32.ds12289794.param758.term1073484" semanticURI="http://purl.obolibrary.org/obo/CHEBI_26020" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>phosphate</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_26020</md:URI>
</md:term>
<md:term id="col32.ds12289794.param758.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col32.ds12289794.method72">
<md:name>Photometry</md:name>
</md:method>
<md:PI id="col32.ds12289794.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>sampled with rhizones</md:comment>
<md:caption>[PO4]3- [µmol/l] (sampled with rhizones, Photom...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="33" format="###0" id="col33.ds12289795" source="data" type="numeric">
<md:parameter id="col33.ds12289795.param24303">
<md:name>Number</md:name>
<md:shortName>No</md:shortName>
<md:term endOffset="6" fragment="1" id="col33.ds12289795.param24303.term2663481" semanticURI="urn:pangaea:obo:pato:syn:5_0001555" startOffset="0" terminologyId="14" terminologyLabel="PATO">
<md:name>number</md:name>
</md:term>
</md:parameter>
<md:PI id="col33.ds12289795.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>No (main sample)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="34" format="#0.00" id="col34.ds12289796" source="data" type="numeric">
<md:parameter id="col34.ds12289796.param26">
<md:name>Porosity</md:name>
<md:shortName>Poros</md:shortName>
<md:unit>% vol</md:unit>
<md:URI>http://en.wikipedia.org/wiki/Porosity</md:URI>
<md:term endOffset="8" fragment="1" id="col34.ds12289796.param26.term1073159" semanticURI="urn:obo:pato:term:0000973" startOffset="0" terminologyId="14" terminologyLabel="PATO">
<md:name>porosity</md:name>
<md:URI>http://purl.obolibrary.org/obo/PATO_0000973</md:URI>
</md:term>
</md:parameter>
<md:PI id="col34.ds12289796.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Poros [% vol] (main sample)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="35" format="#0.000" id="col35.ds12289798" source="data" type="numeric">
<md:parameter id="col35.ds12289798.param50">
<md:name>Sulfate</md:name>
<md:shortName>[SO4]2-</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col35.ds12289798.param50.term1073219" semanticURI="http://purl.obolibrary.org/obo/CHEBI_16189" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>sulfate</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_16189</md:URI>
</md:term>
<md:term id="col35.ds12289798.param50.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col35.ds12289798.method68">
<md:name>Ion chromatography</md:name>
<md:term id="col35.ds12289798.method68.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col35.ds12289798.method68.term2299500" semanticURI="SDN:L22::TOOL0884" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>Scripps Institution of Oceanography Hydrographic Doppler Sonar System</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L22/current/TOOL0884/</md:URI>
</md:term>
</md:method>
<md:PI id="col35.ds12289798.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>[SO4]2- [mmol/l] (main sample, Ion chromatography)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="36" format="#0.00" id="col36.ds12289799" source="data" type="numeric">
<md:parameter id="col36.ds12289799.param83981">
<md:name>Silicon</md:name>
<md:shortName>Si</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col36.ds12289799.param83981.term38478" semanticURI="http://purl.obolibrary.org/obo/CHEBI_27573" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>silicon</md:name>
<md:optionalName>Si</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:27573</md:URI>
</md:term>
<md:term id="col36.ds12289799.param83981.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col36.ds12289799.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col36.ds12289799.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col36.ds12289799.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col36.ds12289799.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Si [mmol/l] (main sample, ICP, Inductively...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="37" format="#0.00" id="col37.ds12289800" source="data" type="numeric">
<md:parameter id="col37.ds12289800.param83981">
<md:name>Silicon</md:name>
<md:shortName>Si</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col37.ds12289800.param83981.term38478" semanticURI="http://purl.obolibrary.org/obo/CHEBI_27573" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>silicon</md:name>
<md:optionalName>Si</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:27573</md:URI>
</md:term>
<md:term id="col37.ds12289800.param83981.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col37.ds12289800.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col37.ds12289800.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col37.ds12289800.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col37.ds12289800.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>sampled with rhizones</md:comment>
<md:caption>Si [mmol/l] (sampled with rhizones, ICP, I...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="38" format="##0.000" id="col38.ds12289801" source="data" type="numeric">
<md:parameter id="col38.ds12289801.param755">
<md:name>Silicate</md:name>
<md:shortName>Si(OH)4</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term id="col38.ds12289801.param755.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col38.ds12289801.method72">
<md:name>Photometry</md:name>
</md:method>
<md:PI id="col38.ds12289801.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Si(OH)4 [µmol/l] (main sample, Photometry)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="39" format="#0.0" id="col39.ds12289802" source="data" type="numeric">
<md:parameter id="col39.ds12289802.param62">
<md:name>Strontium</md:name>
<md:shortName>Sr</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col39.ds12289802.param62.term40663" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>strontium</md:name>
</md:term>
<md:term id="col39.ds12289802.param62.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col39.ds12289802.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col39.ds12289802.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
<md:term id="col39.ds12289802.method538.term2299496" semanticURI="SDN:L05::LAB15" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>inductively-coupled plasma mass spectrometers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB15/</md:URI>
</md:term>
</md:method>
<md:PI id="col39.ds12289802.pi482">
<md:lastName>Pfannkuche</md:lastName>
<md:firstName>Olaf</md:firstName>
</md:PI>
<md:comment>main sample</md:comment>
<md:caption>Sr [µmol/l] (main sample, ICP, Inductively...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="40" format="#0.0" id="col40.ds12289803" source="data" type="numeric">
<md:parameter id="col40.ds12289803.param62">
<md:name>Strontium</md:name>
<md:shortName>Sr</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col40.ds12289803.param62.term40663" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>strontium</md:name>
</md:term>
<md:term id="col40.ds12289803.param62.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col40.ds12289803.method538">
<md:name>ICP, Inductively coupled plasma</md:name>
<md:term id="col40.ds12289803.method538.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
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