Baker, Earl W; Louda, William (1985): (Table 4) Mass spectra of metal-lophorphyrins isolated from DSDP Hole 71-511 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.763358, In supplement to: Baker, EW; Louda, W (1985): Porphyrin geochemistry of Atlantic Jurassic-Cretaceous black shales. Organic Geochemistry, 10(4-6), 905-914, https://doi.org/10.1016/S0146-6380(86)80028-6
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Project(s):
Deep Sea Drilling Project (DSDP)
Coverage:
Latitude: -51.004700 * Longitude: -46.971700
Date/Time Start: 1980-01-15T00:00:00 * Date/Time End: 1980-01-15T00:00:00
Minimum Elevation: -2589.0 m * Maximum Elevation: -2589.0 m
Event(s):
71-511 * Latitude: -51.004700 * Longitude: -46.971700 * Date/Time: 1980-01-15T00:00:00 * Elevation: -2589.0 m * Penetration: 632 m * Recovery: 384.4 m * Location: South Atlantic/PLATEAU * Campaign: Leg71 * Basis: Glomar Challenger * Method/Device: Drilling/drill rig (DRILL) * Comment: 68 cores; 616.5 m cored; 14.5 m drilled; 62.4 % recovery
Comment:
Low-voltage (14 eV) mass spectra normalized and isotopically corrected.Sample 71-511-37-1 Cu porphyrins also contained C22(24) and C23(74) members in the amounts indicated in parentheses.
Parameter(s):
| # | Name | Short Name | Unit | Principal Investigator | Method/Device | Comment |
|---|---|---|---|---|---|---|
| 1 | Sample code/label | Sample label | Baker, Earl W | DSDP/ODP/IODP sample designation | ||
| 2 | Sample comment | Sample comment | Baker, Earl W | |||
| 3 | C24 carbon number | C24 C n | # | Baker, Earl W | VO = vanadyl; D = DPEP; E = ETIO; BD = benzo-DPEP; TH = tetrahydrobenzo-DPEP; DPEP = 476 +/- 14n; THBD = tetrahydrobenzo-DPEP (Barwise and Roberts, 1984, doi:10.1016/0146-6380(84)90038-X) = 474 +/- 14n; BD = benzo-DPEP (Baker et al., 1967, doi:10.1021/ja00990a050; Barwise and Whitehead, 1980) = 470 + l4n; (n is an integer) | |
| 4 | C25 carbon number | C25 C n | # | Baker, Earl W | ||
| 5 | C26 carbon number | C26 C n | # | Baker, Earl W | ||
| 6 | C27 carbon number | C27 C n | # | Baker, Earl W | ||
| 7 | C28 carbon number | C28 C n | # | Baker, Earl W | ||
| 8 | C29 carbon number | C29 C n | # | Baker, Earl W | ||
| 9 | C30 carbon number | C30 C n | # | Baker, Earl W | ||
| 10 | C31 carbon number | C31 C n | # | Baker, Earl W | ||
| 11 | C32 carbon number | C32 C n | # | Baker, Earl W | ||
| 12 | C33 carbon number | C33 C n | # | Baker, Earl W | ||
| 13 | C34 carbon number | C34 C n | # | Baker, Earl W | ||
| 14 | Average carbon number | Av C n | # | Baker, Earl W | ||
| 15 | Percentage | Perc | % | Baker, Earl W | percent each series is within a metallo-species | |
| 16 | Ratio | Ratio | Baker, Earl W | DPEP to ETIO ratio calculated excluding BD and TH series |
License:
Creative Commons Attribution 3.0 Unported (CC-BY-3.0)
Size:
306 data points
Data
| 1 Sample label | 2 Sample comment | 3 C24 C n [#] | 4 C25 C n [#] | 5 C26 C n [#] | 6 C27 C n [#] | 7 C28 C n [#] | 8 C29 C n [#] | 9 C30 C n [#] | 10 C31 C n [#] | 11 C32 C n [#] | 12 C33 C n [#] | 13 C34 C n [#] | 14 Av C n [#] | 15 Perc [%] | 16 Ratio |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 71-511-37-1 | Cu E | 83 | 83 | 100 | 69 | 83 | 41 | 41 | 9 | 3 | 26.3 | 100 | |||
| 71-511-60-5 | Ni D | 3 | 43 | 67 | 100 | 64 | 68 | 6 | 30.2 | 58 | 1.59 | ||||
| 71-511-60-5 | Ni E | 9 | 23 | 48 | 47 | 55 | 30 | 8 | 27.1 | 37 | |||||
| 71-511-60-5 | Ni BD | 3 | 6 | 20 | 1 | 32.6 | 5 | ||||||||
| 71-511-62-5 | Ni D | 5 | 31 | 62 | 100 | 66 | 79 | 30.2 | 60 | 1.81 | |||||
| 71-511-62-5 | Ni E | 3 | 13 | 40 | 39 | 66 | 19 | 8 | 27.3 | 33 | |||||
| 71-511-62-5 | Ni ED | 4 | 5 | 18 | 1 | 32.4 | 6 | ||||||||
| 71-511-62-5 | Ni TH | 1 | 16 | 33.0 | 2 | ||||||||||
| 71-511-64-4 | Ni D | 1 | 12 | 27 | 52 | 63 | 100 | 30.8 | 65 | 2.54 | |||||
| 71-511-64-4 | Ni E | 2 | 8 | 17 | 16 | 26 | 15 | 16 | 1 | 27.1 | 26 | ||||
| 71-511-64-4 | Ni BD | 3 | 4 | 13 | 1 | 32.6 | 5 | ||||||||
| 71-511-64-4 | Ni TH | 1 | 13 | 1 | 33.0 | 4 | |||||||||
| 71-511-64-4 | VO D | 2 | 22 | 51 | 100 | 92 | 2 | 1 | 31.0 | 73 | |||||
| 71-511-64-4 | VO BD | 8 | 18 | 39 | 2 | 32.5 | 18 | ||||||||
| 71-511-64-4 | VO TH | 1 | 16 | 18 | 1 | 32.5 | 9 | ||||||||
| 71-511-66-4 | Ni D | 1 | 11 | 31 | 68 | 84 | 100 | 30.9 | 63 | 2.49 | |||||
| 71-511-66-4 | Ni E | 1 | 7 | 21 | 23 | 36 | 20 | 14 | 1 | 27.7 | 25 | ||||
| 71-511-66-4 | Ni BD | 3 | 7 | 17 | 1 | 32.5 | 6 | ||||||||
| 71-511-66-4 | Ni TH | 2 | 9 | 18 | 1 | 32.6 | 6 | ||||||||
| 71-511-66-4 | VO D | 4 | 20 | 47 | 100 | 76 | 14 | 1 | 31.0 | 70 | |||||
| 71-511-66-4 | VO BD | 1 | 5 | 22 | 67 | 8 | 32.9 | 27 | |||||||
| 71-511-66-4 | VO TH | 1 | 8 | 31.9 | 3 | ||||||||||
| 71-511-68-2 | Ni D | 1 | 10 | 32 | 63 | 79 | 100 | 5 | 30.8 | 72 | 2.91 | ||||
| 71-511-68-2 | Ni E | 2 | 4 | 11 | 18 | 23 | 23 | 17 | 3 | 28.0 | 25 | ||||
| 71-511-68-2 | Ni BD | 1 | 2 | 6 | 32.5 | 2 | |||||||||
| 71-511-68-2 | Ni TH | 5 | 34.0 | 1 | |||||||||||
| 71-511-70-3 | Ni D | 4 | 18 | 45 | 100 | 72 | 84 | 6 | 1 | 30.5 | 66 | 2.56 | |||
| 71-511-70-3 | Ni E | 4 | 11 | 22 | 24 | 40 | 18 | 10 | 27.4 | 36 | |||||
| 71-511-70-3 | Ni BD | 2 | 4 | 12 | 32.5 | 3 | |||||||||
| 71-511-70-3 | Ni TH | 10 | 15 | 32.5 | 5 | ||||||||||
| 71-511-70-3 | VO D | 1 | 11 | 21 | 51 | 100 | 98 | 18 | 31.0 | 91 | |||||
| 71-511-70-3 | VO BD | 4 | 5 | 18 | 32.5 | 8 | |||||||||
| 71-511-70-3 | VO TH | 3 | 32.0 | 1 |