Baturin Gleb N Rozanov Alexander G 2003 (Table 2) Chemical composition and sulfur and iron speciations in phosphorites and host sediments from the Namibian-, Peru- and Chile shelves and from the Sea of Japan dataset https://doi.org/10.1594/PANGAEA.762258 Baturin Gleb N Rozanov Alexander G 2003 Sulfur species in oceanic phosphorites journal article Translated from Okeanologiya, 2003, 43(1), 35-43 Oceanology 43(1) 30-39 Sulfur speciation was studied by chemical methods in recent, Pliocene-Pleistocene and Miocene phosphorites from the inner and outer Namibian shef, Late Quaternary phosphorites from the Peru-Chile shelf and Miocene phosphorites from some underwater highs of the Sea of Japan. Following concentrations (%) were measured: 0.25-1.147% of sulfate sulfur (S SO4), 0.012-1.473% pyritic sulfur (S pyr), 0.005-0.141% of organic sulfur (TOS), and <0.0001-0.04% of elemental sulfur (S°). Generally sulfate sulfur was predominant, but in some samples pyritic sufur was more abundant. (S SO4/S pyr) ratio varied from 0.36 to 18 in shelf phosphorites and increased to 37-52 in phosphorites from the Sea of Japan. The most part of sulfate sulfur seemed to be incorporated in apatite mineral of phosphorites. Samples enriched in organic matter were enriched in pyritic sulfur as well, but without direct correlation between them. Similar relation was found between organic matter and organic sulfur. Relative amount of non-pyritic Fe(II) in phosphorites from reducing environment was found to decrease with time along with their lithification owing to continuation of pyritization. -79.65 133.8 -25.2666666666666 41.2333333333333 10.251663333333251 -7.013326666666652 -2130.0 -78.0 vertical profile ARCOD Archive of Ocean Data Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research, Bremerhaven AWI https://www.awi.de/ https://ror.org/032e6b942 AK-1215 -17.416666666667 11.483333333333 Namibian shelf -150.0 Trawl net TRAWL AK4-250 -21.1333 -70.3667 Chile shelf -150.0 AKU4 AKU4 1968-08-01T00:00:00 1968-08-01 1968-12-01T00:00:00 1968-12-01 Akademik Kurchatov Akademik Kurchatov Grab GRAB AK5-412 -25.266666666667 14.05 Namibian shelf -199.0 Grab GRAB DM-1620 41.233333333333 133.8 Sea of Japan -2000.0 Dredge DRG DM8-546 -9.8 -79.4 Peru shelf -560.0 DM8 DM8 1972-05-01T00:00:00 1972-05-01 1972-09-30T00:00:00 1972-09-30 Dmitry Mendeleev https://ocean.ru/index.php/novosti-left/ob-yavleniya/item/1238-polveka-so-dnya-nachala-pervogo-rejsa-nis-dmitrij-mendeleev UILS 6806896 Lisitzin, Alexander P Lisitzin, Alexander P Dmitry Mendeleev https://ocean.ru/index.php/novosti-left/ob-yavleniya/item/1238-polveka-so-dnya-nachala-pervogo-rejsa-nis-dmitrij-mendeleev UILS 6806896 Grab GRAB DM8-553 -9.2333 -79.65 Peru shelf -300.0 DM8 DM8 1972-05-01T00:00:00 1972-05-01 1972-09-30T00:00:00 1972-09-30 Dmitry Mendeleev https://ocean.ru/index.php/novosti-left/ob-yavleniya/item/1238-polveka-so-dnya-nachala-pervogo-rejsa-nis-dmitrij-mendeleev UILS 6806896 Lisitzin, Alexander P Lisitzin, Alexander P Dmitry Mendeleev https://ocean.ru/index.php/novosti-left/ob-yavleniya/item/1238-polveka-so-dnya-nachala-pervogo-rejsa-nis-dmitrij-mendeleev UILS 6806896 Grab GRAB DM24-2046 -22.666666666667 14.25 Namibian shelf -87.0 Grab GRAB DM24-2047 -22.45 14.166666666667 Namibian shelf -78.0 Grab GRAB DM24-2048 -22.133333333333 13.966666666667 Namibian shelf -85.0 Grab GRAB DM35-3150 38.733333333333 130.21666666667 Sea of Japan -2130.0 Dredge DRG 389 CC-BY-3.0 Creative Commons Attribution 3.0 Unported https://creativecommons.org/licenses/by/3.0/ Event label Event Event Latitude of event Latitude Latitude Longitude of event Longitude Longitude Elevation of event Elevation m Elevation [m] Location of event Location Location Sample code/label Sample label Baturin Gleb N Sample label Sample type Samp type Baturin Gleb N Samp type Phosphorus pentoxide P2O5 % phosphorus oxide http://purl.obolibrary.org/obo/CHEBI_37349 Dimensionless Ratio ψ Wet chemistry Baturin Gleb N P2O5 [%] (Wet chemistry) Aluminium Al % aluminium Al Dimensionless Ratio ψ Wet chemistry Baturin Gleb N Al [%] (Wet chemistry) Carbon dioxide CO2 % carbon dioxide http://purl.obolibrary.org/obo/CHEBI_16526 Dimensionless Ratio ψ Wet chemistry Baturin Gleb N CO2 [%] (Wet chemistry) Carbon, organic, total TOC % carbon C https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:27594 organic total https://www.oxforddictionaries.com/definition/american_english/total Dimensionless Ratio ψ Wet chemistry Baturin Gleb N TOC [%] (Wet chemistry) Sulfur in sulfate S SO4 mg/kg sulfur sulfate http://purl.obolibrary.org/obo/CHEBI_16189 Wet chemistry Baturin Gleb N S SO4 [mg/kg] (Wet chemistry) Sulfur of pyrite S Py mg/kg sulfur pyrite http://purl.obolibrary.org/obo/CHEBI_86471 Wet chemistry Baturin Gleb N S Py [mg/kg] (Wet chemistry) Sulfur, organic S org % sulfur organic Dimensionless Ratio ψ Wet chemistry Baturin Gleb N total S org [%] (total, Wet chemistry) Sulfur, elemental S° % sulfur Dimensionless Ratio ψ Wet chemistry Baturin Gleb N S° [%] (Wet chemistry) Sulfur, total TS % sulfur total https://www.oxforddictionaries.com/definition/american_english/total Dimensionless Ratio ψ Wet chemistry Baturin Gleb N TS [%] (Wet chemistry) Barium Ba mg/kg barium Wet chemistry Baturin Gleb N Ba [mg/kg] (Wet chemistry) Iron Fe % Dimensionless Ratio ψ Wet chemistry Baturin Gleb N Fe [%] (Wet chemistry) Iron in pyrite Fe Py % pyrite http://purl.obolibrary.org/obo/CHEBI_86471 Dimensionless Ratio ψ Calculated Baturin Gleb N calculated from S pyr Fe Py [%] (calculated from S pyr, Calcul...) Iron Fe % Dimensionless Ratio ψ Calculated Baturin Gleb N excessive (Fe ex = Fe - Fe pyr) Fe [%] (excessive (Fe ex = Fe - Fe py...) Iron/Aluminium ratio Fe/Al aluminium Al ratio Calculated Baturin Gleb N Fe/Al (Calculated) Ratio Ratio ratio Calculated Baturin Gleb N S SO4 / S pyr Ratio (S SO4 / S pyr, Calculated) Ratio Ratio ratio Calculated Baturin Gleb N Fe ex / Fe pyr Ratio (Fe ex / Fe pyr, Calculated) supplement citable author35002 author36194 basis126 basis15 campaign25593 campaign3378694 campaign3379018 campaign34255 event2108956 event2108961 event2109079 event2633133 event2633134 event2633135 event2633136 event2633137 event2633138 event2633139 geocode1599 geocode1600 geocode1601 geocode8128 inst32 journal12199 license101 method10654 method11098 method11731 method50 method6629 param18479 param49318 param50534 param53118 param6246 param67 param6846 param7059 param709 param72 param75 param77 param790 param82 param97866 param97867 pi35002 project4026 ref34556 term1073219 term1073490 term1074191 term22033 term2630673 term2663825 term28582 term28863 term28874 term38253 term38477 term40136 term40685 term40966 term43794 term44419 topotype3