<?xml version="1.0" encoding="UTF-8"?><md:MetaData xmlns:md="http://www.pangaea.de/MetaData" version="2026-04-13">
<md:citation id="dataset758528">
<md:author id="dataset.author21588">
<md:lastName>Thierstein</md:lastName>
<md:firstName>Hans R</md:firstName>
<md:eMail>thierstein@erdw.ethz.ch</md:eMail>
</md:author>
<md:author id="dataset.author33664">
<md:lastName>Asaro</md:lastName>
<md:firstName>Frank</md:firstName>
</md:author>
<md:author id="dataset.author453">
<md:lastName>Ehrmann</md:lastName>
<md:firstName>Werner</md:firstName>
<md:eMail>ehrmann@rz.uni-leipzig.de</md:eMail>
<md:URI>http://www.uni-leipzig.de/~geologie/Mitarbeiter/Ehrmann/ehrmann.htm</md:URI>
</md:author>
<md:author id="dataset.author556">
<md:lastName>Huber</md:lastName>
<md:firstName>Brian T</md:firstName>
<md:eMail>huberb@si.edu</md:eMail>
<md:URI>https://naturalhistory.si.edu/staff/brian-huber</md:URI>
<md:orcid>0000-0002-0929-3175</md:orcid>
</md:author>
<md:author id="dataset.author37326">
<md:lastName>Michel</md:lastName>
<md:firstName>Helen V</md:firstName>
</md:author>
<md:author id="dataset.author30521">
<md:lastName>Sakai</md:lastName>
<md:firstName>Hideo</md:firstName>
</md:author>
<md:author id="dataset.author31059">
<md:lastName>Schmitz</md:lastName>
<md:firstName>Birger</md:firstName>
</md:author>
<md:year>1991</md:year>
<md:title>Stable isotope ratios, iridium concentrations, and mineralogy of sediments at and around the Cretaceous/Tertiary boundary at ODP Hole 119-738C</md:title>
<md:type id="dataset.reftype10" includeInCitation="true">dataset</md:type>
<md:URI>https://doi.org/10.1594/PANGAEA.758528</md:URI>
<md:supplementTo id="ref33804">
<md:author id="ref33804.author21588">
<md:lastName>Thierstein</md:lastName>
<md:firstName>Hans R</md:firstName>
<md:eMail>thierstein@erdw.ethz.ch</md:eMail>
</md:author>
<md:author id="ref33804.author33664">
<md:lastName>Asaro</md:lastName>
<md:firstName>Frank</md:firstName>
</md:author>
<md:author id="ref33804.author453">
<md:lastName>Ehrmann</md:lastName>
<md:firstName>Werner</md:firstName>
<md:eMail>ehrmann@rz.uni-leipzig.de</md:eMail>
<md:URI>http://www.uni-leipzig.de/~geologie/Mitarbeiter/Ehrmann/ehrmann.htm</md:URI>
</md:author>
<md:author id="ref33804.author556">
<md:lastName>Huber</md:lastName>
<md:firstName>Brian T</md:firstName>
<md:eMail>huberb@si.edu</md:eMail>
<md:URI>https://naturalhistory.si.edu/staff/brian-huber</md:URI>
<md:orcid>0000-0002-0929-3175</md:orcid>
</md:author>
<md:author id="ref33804.author37326">
<md:lastName>Michel</md:lastName>
<md:firstName>Helen V</md:firstName>
</md:author>
<md:author id="ref33804.author30521">
<md:lastName>Sakai</md:lastName>
<md:firstName>Hideo</md:firstName>
</md:author>
<md:author id="ref33804.author31059">
<md:lastName>Schmitz</md:lastName>
<md:firstName>Birger</md:firstName>
</md:author>
<md:year>1991</md:year>
<md:title>The Cretaceous/Tertiary Boundary at Site 738, southern Kerguelen Plateau</md:title>
<md:type id="ref33804.reftype15">book chapter</md:type>
<md:source>In: Barron, J; Larsen, B; et al. (eds.), Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program)</md:source>
<md:volume>119</md:volume>
<md:URI>https://doi.org/10.2973/odp.proc.sr.119.157.1991</md:URI>
<md:pages>849-867</md:pages>
</md:supplementTo>
</md:citation>
<md:abstract>High-resolution stratigraphic evidence of an apparently complete carbonate-rich Cretaceous/Tertiary boundary interval in Section 119-738C-20R-5 from the southern Kerguelen Plateau is summarized and interpreted. The change of the calcareous nannoflora and of the planktonic foraminifers is spread over a laminated interval of about 15 cm thickness. The base of this laminated interval lies in uppermost Maestrichtian chalks, 2 cm below a distinct 2-mm-thick "gray clay" layer, which shows the highest iridium enrichment (18 ppb) measured in this section. No shocked quartz or microspherules, characteristic of an impact, were found. No change in the clay mineralogy, which could be expected for a large volcanic or impact event, could be identified. Elevated metal and iridium concentrations (&gt; 1.6 ppb) occur already in the bioturbated uppermost Maestrichtian chalks several centimeters below the "gray clay" and decrease above the iridium peak gradually over a laminated 12-cm-thick interval to background values of 0.1-0.3 ppb Ir. Application of bio- and magnetochronology shows that the accumulation rates of carbonates and clays, but not of the metals, decreased dramatically at the Cretaceous/Tertiary boundary and thus, the lack of dilution may have led to the observed metal concentrations.</md:abstract>
<md:extent>
<md:geographic>
<md:westBoundLongitude>82.7878</md:westBoundLongitude>
<md:eastBoundLongitude>82.7878</md:eastBoundLongitude>
<md:southBoundLatitude>-62.709</md:southBoundLatitude>
<md:northBoundLatitude>-62.709</md:northBoundLatitude>
<md:meanLongitude>82.7878</md:meanLongitude>
<md:meanLatitude>-62.709</md:meanLatitude>
</md:geographic>
<md:temporal>
<md:minDateTime>1988-01-11T18:45:00</md:minDateTime>
<md:maxDateTime>1988-01-17T05:00:00</md:maxDateTime>
</md:temporal>
<md:elevation geocodeId="geocode1" name="DEPTH, sediment/rock" unit="m">
<md:min>376.0</md:min>
<md:max>389.6</md:max>
</md:elevation>
</md:extent>
<md:project id="project3" type="International">
<md:label>ODP</md:label>
<md:name>Ocean Drilling Program</md:name>
<md:URI>https://www-odp.tamu.edu:443/</md:URI>
<md:institution id="project3.inst34">
<md:name>Ocean Drilling Program, Texas A&amp;M University</md:name>
<md:optionalName>ODP</md:optionalName>
<md:URI>http://www-odp.tamu.edu/</md:URI>
<md:ROR>https://ror.org/01f5ytq51</md:ROR>
</md:institution>
</md:project>
<md:event displayTypeName="Event" id="event13515" typeName="Generic Event">
<md:label>119-738C</md:label>
<md:latitude>-62.709</md:latitude>
<md:longitude>82.7878</md:longitude>
<md:location id="event13515.term20611">
<md:name>Indian Ocean</md:name>
</md:location>
<md:elevation>-2263.0</md:elevation>
<md:dateTime>1988-01-11T18:45:00</md:dateTime>
<md:dateTime2>1988-01-17T05:00:00</md:dateTime2>
<md:campaign displayTypeName="Campaign" id="event13515.campaign3397808" legacyId="event13515.campaign91" typeName="Generic Campaign">
<md:label>Leg119</md:label>
<md:name warning="deprecated">Leg119</md:name>
<md:dateTime>1987-12-14T00:00:00</md:dateTime>
<md:start warning="deprecated">1987-12-14</md:start>
<md:dateTime2>1988-02-20T00:00:00</md:dateTime2>
<md:end warning="deprecated">1988-02-20</md:end>
<md:basis id="event13515.campaign3397808.basis5">
<md:name>Joides Resolution</md:name>
<md:URI>https://www-odp.tamu.edu:443/resolutn.html</md:URI>
</md:basis>
<md:responsible>Barron, John A</md:responsible>
<md:chiefScientist warning="deprecated">Barron, John A</md:chiefScientist>
<md:responsible>Larsen, Birger</md:responsible>
<md:chiefScientist warning="deprecated">Larsen, Birger</md:chiefScientist>
<md:attribute attid="76863" name="Report">doi:10.2973/odp.proc.ir.119.1989</md:attribute>
</md:campaign>
<md:basis id="event13515.basis5">
<md:name>Joides Resolution</md:name>
<md:URI>https://www-odp.tamu.edu:443/resolutn.html</md:URI>
</md:basis>
<md:method id="event13515.method10974">
<md:name>Drilling/drill rig</md:name>
<md:optionalName>DRILL</md:optionalName>
</md:method>
<md:attribute attid="19162" name="Penetration">533.8 m</md:attribute>
<md:attribute attid="19163" name="Recovery">146.03 m</md:attribute>
<md:comment>35 cores; 337.2 m cored; 0 m drilled; 43.3 % recovery</md:comment>
</md:event>
<md:size unit="data points">260</md:size>
<md:license id="license101">
<md:label>CC-BY-3.0</md:label>
<md:name>Creative Commons Attribution 3.0 Unported</md:name>
<md:URI>https://creativecommons.org/licenses/by/3.0/</md:URI>
</md:license>
<md:comment>The Cretaceous/Tertiary boundary clay is at Section 119-738C-20R-5, 96.0-96.2 cm. The samples for the nannofossil counts and microcarbonate estimates were taken at specific millimeter intervals. The samples for carbonate, clay mineralogical, and geochemical analyses were homogenized over 1-cm intervals and are listed at the corresponding centimeter levels.</md:comment>
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<md:name>Sample code/label</md:name>
<md:shortName>Sample label</md:shortName>
</md:parameter>
<md:method id="col0.ds11426316.method5059">
<md:name>DSDP/ODP/IODP sample designation</md:name>
<md:URI>hdl:10013/epic.27914.d001</md:URI>
</md:method>
<md:PI id="col0.ds11426316.pi21588">
<md:lastName>Thierstein</md:lastName>
<md:firstName>Hans R</md:firstName>
<md:eMail>thierstein@erdw.ethz.ch</md:eMail>
</md:PI>
<md:caption>Sample label</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="1" col="1" format="##0.000" id="col1.ds1415161" source="geocode" type="numeric">
<md:parameter id="col1.ds1415161.geocode1">
<md:name>DEPTH, sediment/rock</md:name>
<md:shortName>Depth sed</md:shortName>
<md:unit>m</md:unit>
<md:term endOffset="5" fragment="1" id="col1.ds1415161.geocode1.term1073131" semanticURI="urn:obo:pato:term:0001595" startOffset="0" terminologyId="14" terminologyLabel="PATO">
<md:name>depth</md:name>
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<md:term endOffset="15" fragment="2" id="col1.ds1415161.geocode1.term38263" startOffset="7" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>sediment</md:name>
<md:URI>http://purl.obolibrary.org/obo/ENVO_00002007</md:URI>
</md:term>
<md:term endOffset="20" fragment="3" id="col1.ds1415161.geocode1.term41056" startOffset="16" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>rock</md:name>
</md:term>
<md:term id="col1.ds1415161.geocode1.term43863" semanticURI="http://qudt.org/1.1/vocab/quantity#Length" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Length</md:name>
<md:optionalName>L</md:optionalName>
<md:URI>http://dbpedia.org/resource/Length</md:URI>
</md:term>
</md:parameter>
<md:caption>Depth sed [m]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="2" format="#0.00" id="col2.ds11426318" source="data" type="numeric">
<md:parameter id="col2.ds11426318.param2094">
<md:name>δ18O, carbonate</md:name>
<md:shortName>δ18O carb</md:shortName>
<md:unit>‰ PDB</md:unit>
<md:term endOffset="4" fragment="1" id="col2.ds11426318.param2094.term1073093" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>δ18O</md:name>
<md:URI>http://en.wikipedia.org/wiki/List_of_elements_by_stability_of_isotopes</md:URI>
</md:term>
<md:term endOffset="15" fragment="2" id="col2.ds11426318.param2094.term1073143" semanticURI="http://purl.obolibrary.org/obo/CHEBI_41609" startOffset="6" terminologyId="16" terminologyLabel="ChEBI">
<md:name>carbonate</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_41609</md:URI>
</md:term>
</md:parameter>
<md:PI id="col2.ds11426318.pi21588">
<md:lastName>Thierstein</md:lastName>
<md:firstName>Hans R</md:firstName>
<md:eMail>thierstein@erdw.ethz.ch</md:eMail>
</md:PI>
<md:comment>fine fraction &lt;38 µm</md:comment>
<md:caption>δ18O carb [‰ PDB]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="3" format="#0.00" id="col3.ds11426319" source="data" type="numeric">
<md:parameter id="col3.ds11426319.param2095">
<md:name>δ13C, carbonate</md:name>
<md:shortName>δ13C carb</md:shortName>
<md:unit>‰ PDB</md:unit>
<md:term endOffset="4" fragment="1" id="col3.ds11426319.param2095.term1073089" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>δ13C</md:name>
<md:URI>http://en.wikipedia.org/wiki/List_of_elements_by_stability_of_isotopes</md:URI>
</md:term>
<md:term endOffset="15" fragment="2" id="col3.ds11426319.param2095.term1073143" semanticURI="http://purl.obolibrary.org/obo/CHEBI_41609" startOffset="6" terminologyId="16" terminologyLabel="ChEBI">
<md:name>carbonate</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_41609</md:URI>
</md:term>
</md:parameter>
<md:PI id="col3.ds11426319.pi21588">
<md:lastName>Thierstein</md:lastName>
<md:firstName>Hans R</md:firstName>
<md:eMail>thierstein@erdw.ethz.ch</md:eMail>
</md:PI>
<md:comment>fine fraction &lt;38 µm</md:comment>
<md:caption>δ13C carb [‰ PDB]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="4" format="####0" id="col4.ds11426320" source="data" type="numeric">
<md:parameter id="col4.ds11426320.param2204">
<md:name>Iridium</md:name>
<md:shortName>Ir</md:shortName>
<md:unit>ng/kg</md:unit>
<md:term endOffset="7" fragment="1" id="col4.ds11426320.param2204.term44258" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>iridium</md:name>
</md:term>
</md:parameter>
<md:PI id="col4.ds11426320.pi21588">
<md:lastName>Thierstein</md:lastName>
<md:firstName>Hans R</md:firstName>
<md:eMail>thierstein@erdw.ethz.ch</md:eMail>
</md:PI>
<md:caption>Ir [ng/kg]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="5" format="#0.0" id="col5.ds11426321" source="data" type="numeric">
<md:parameter id="col5.ds11426321.param295">
<md:name>Smectite</md:name>
<md:shortName>Sme</md:shortName>
<md:unit>%</md:unit>
<md:URI>http://www.mindat.org/min-11116.html</md:URI>
<md:term id="col5.ds11426321.param295.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:PI id="col5.ds11426321.pi21588">
<md:lastName>Thierstein</md:lastName>
<md:firstName>Hans R</md:firstName>
<md:eMail>thierstein@erdw.ethz.ch</md:eMail>
</md:PI>
<md:caption>Sme [%]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="6" format="#0.0" id="col6.ds11426322" source="data" type="numeric">
<md:parameter id="col6.ds11426322.param296">
<md:name>Illite</md:name>
<md:shortName>Ill</md:shortName>
<md:unit>%</md:unit>
<md:URI>http://www.mindat.org/min-2011.html</md:URI>
<md:term endOffset="6" fragment="1" id="col6.ds11426322.param296.term40831" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>illite</md:name>
<md:URI>https://www.mindat.org/min-2011.html</md:URI>
</md:term>
<md:term id="col6.ds11426322.param296.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:PI id="col6.ds11426322.pi21588">
<md:lastName>Thierstein</md:lastName>
<md:firstName>Hans R</md:firstName>
<md:eMail>thierstein@erdw.ethz.ch</md:eMail>
</md:PI>
<md:caption>Ill [%]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="7" format="#0.0" id="col7.ds11426323" source="data" type="numeric">
<md:parameter id="col7.ds11426323.param297">
<md:name>Chlorite</md:name>
<md:shortName>Chl</md:shortName>
<md:unit>%</md:unit>
<md:URI>http://www.mindat.org/min-11468.html</md:URI>
<md:term endOffset="8" fragment="1" id="col7.ds11426323.param297.term1073285" semanticURI="http://purl.obolibrary.org/obo/CHEBI_17441" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>chlorite</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_17441</md:URI>
</md:term>
<md:term id="col7.ds11426323.param297.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:PI id="col7.ds11426323.pi21588">
<md:lastName>Thierstein</md:lastName>
<md:firstName>Hans R</md:firstName>
<md:eMail>thierstein@erdw.ethz.ch</md:eMail>
</md:PI>
<md:caption>Chl [%]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="8" format="#0.0" id="col8.ds11426324" source="data" type="numeric">
<md:parameter id="col8.ds11426324.param70">
<md:name>Calcium carbonate</md:name>
<md:shortName>CaCO3</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="17" fragment="1" id="col8.ds11426324.param70.term1074204" semanticURI="http://purl.obolibrary.org/obo/CHEBI_3311" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>calcium carbonate</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_3311</md:URI>
</md:term>
<md:term id="col8.ds11426324.param70.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:PI id="col8.ds11426324.pi21588">
<md:lastName>Thierstein</md:lastName>
<md:firstName>Hans R</md:firstName>
<md:eMail>thierstein@erdw.ethz.ch</md:eMail>
</md:PI>
<md:caption>CaCO3 [%]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="9" format="#0" id="col9.ds11426325" source="data" type="numeric">
<md:parameter id="col9.ds11426325.param98938">
<md:name>Microcarbonate</md:name>
<md:shortName>Microcarbonate</md:shortName>
<md:unit>%</md:unit>
<md:term id="col9.ds11426325.param98938.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:PI id="col9.ds11426325.pi21588">
<md:lastName>Thierstein</md:lastName>
<md:firstName>Hans R</md:firstName>
<md:eMail>thierstein@erdw.ethz.ch</md:eMail>
</md:PI>
<md:caption>Microcarbonate [%]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="10" format="#0" id="col10.ds11426326" source="data" type="numeric">
<md:parameter id="col10.ds11426326.param98939">
<md:name>Nannofossils, tertiary</md:name>
<md:shortName>Nannos tertiary</md:shortName>
<md:unit>%</md:unit>
<md:term id="col10.ds11426326.param98939.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:PI id="col10.ds11426326.pi21588">
<md:lastName>Thierstein</md:lastName>
<md:firstName>Hans R</md:firstName>
<md:eMail>thierstein@erdw.ethz.ch</md:eMail>
</md:PI>
<md:caption>Nannos tertiary [%]</md:caption>
</md:matrixColumn>
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<md:entry key="xmlLastModified" value="2026-05-01T03:42:22Z"/>
<md:entry key="lastModified" value="2016-03-21T21:25:31"/>
<md:entry key="filename" value="119-738C_iridium"/>
<md:entry key="mimeType" value="text/tab-separated-values"/>
<md:entry key="status" value="published"/>
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<md:entry key="DOIRegistryStatus" value="registered"/>
<md:entry key="DOIRegistryStatus_num" value="4"/>
<md:entry key="DOIRegistrationDate" value="2011-04-20T01:11:38"/>
<md:entry key="loginOption" value="unrestricted"/>
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