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Aycard, Mylène; Derenne, Sylvie; Largeau, Claude; Mongenot, Thierry; Tribovillard, Nicolas; Baudin, Francois (2003): (Table 2) Composition nd atomic ratios of the proto-kerogen concentrates in ODP Hole 165-1002C samples [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.757601, In supplement to: Aycard, M et al. (2003): Formation pathways of proto-kerogens in Holocene sediments of the upwelling influenced Cariaco Trench, Venezuela. Organic Geochemistry, 34(6), 701-718, https://doi.org/10.1016/S0146-6380(03)00058-5

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Project(s):
Coverage:
Latitude: 10.706100 * Longitude: -65.169400
Date/Time Start: 1996-02-18T16:30:00 * Date/Time End: 1996-02-19T04:30:00
Minimum DEPTH, sediment/rock: 0.275 m * Maximum DEPTH, sediment/rock: 2.535 m
Event(s):
165-1002C * Latitude: 10.706100 * Longitude: -65.169400 * Date/Time Start: 1996-02-18T16:30:00 * Date/Time End: 1996-02-19T04:30:00 * Elevation: -892.6 m * Penetration: 170.1 m * Recovery: 186 m * Location: Cayman Rise, Caribbean Sea * Campaign: Leg165 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 19 cores; 170.1 m cored; 0 m drilled; 109.3 % recovery
Comment:
Sorg was obtained by subtracting pyritic S (calculated from Fe content assuming that Fe exclusively occurs as pyrite) from total S (measured by elemental analysis). Accordingly, these values, and hence the Sorg/C ratios, are not obtained with high precision and rounded numbers are reported. However, (i) these Sorg/C values point to a low level of sulfurisation for the proto-kerogen of the shallowest sample (in agreement with S measurements from Were et al., 2003, doi:10.1016/S0009-2541(02)00393-5) and to an increasing trend with depth and (ii) these two features are supported by light microscopy and pyrolysis observations.
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Sample code/labelSample labelAycard, MylèneDSDP/ODP/IODP sample designation
DEPTH, sediment/rockDepth sedmGeocode
Depth, top/minDepth topmAycard, Mylène
Depth, bottom/maxDepth botmAycard, Mylène
AGEAgeka BPGeocode
CarbonC%Aycard, Mylènewt. %
HydrogenH%Aycard, Mylènewt. %
Nitrogen, totalTN%Aycard, Mylènewt. %
OxygenO%Aycard, Mylènewt. %
10 IronFe%Aycard, Mylènewt. %
11 Sulfur, totalTS%Aycard, Mylènewt. %
12 Ash, volcanicVolc ash%Aycard, MylènePyrite is not eliminated by HF/HC1 treatment. In agreement with Fe content, microscopic observations and FTIR data, ash in these proto-kerogen concentrates almost entirely corresponds to pyrite.
13 Hydrogen/Carbon ratioH/CAycard, Mylèneatomic
14 Oxygen/Carbon ratioO/CAycard, Mylèneatomic
15 Carbon/Nitrogen ratioC/NAycard, Mylèneatomic
16 Sulfur/Carbon ratioS/CAycard, MylèneSorg/C, atomic
Size:
42 data points

Data

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Sample label

Depth sed [m]

Depth top [m]

Depth bot [m]

Age [ka BP]

C [%]

H [%]

TN [%]

O [%]
10 
Fe [%]
11 
TS [%]
12 
Volc ash [%]
13 
H/C
14 
O/C
15 
C/N
16 
S/C
165-1002C-1H-1,26-290.2750.260.290.9047.74.73.718.47.611.016.401.20.2915.00.02
165-1002C-1H-1,102-1051.0351.021.052.8546.35.04.420.55.69.811.901.30.3312.30.03
165-1002C-1H-2,102-1052.5352.522.556.0042.14.73.618.18.916.121.101.30.3213.60.05