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Oxburgh, Rachel; Pierson-Wickmann, Anne-Catherine; Reisberg, Laurie; Hemming, Sidney R (2007): Osmium concentration and isotope composition of ODP Hole 165-1002C (Table 1) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.725507, Supplement to: Oxburgh, R et al. (2007): Climate-correlated variations in seawater 187Os/188Os over the past 200,000 yr: Evidence from the Cariaco Basin, Venezuela. Earth and Planetary Science Letters, 263(3-4), 246-258, https://doi.org/10.1016/j.epsl.2007.08.033

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Abstract:
A high resolution record of seawater osmium isotopic composition (35 samples over the past 191,000 yr) has been obtained from sediments from Ocean Drilling Program (ODP) Leg 165 Site 1002 in the Cariaco Basin, Venezuela. Strong correlations are observed between 187Os/188Os and both the local and global oxygen isotopic records, with less radiogenic values observed during glacial intervals. In conjunction with previous analyses of sediments from the East Pacific Rise, the Santa Barbara Basin, and the Japan Sea, the data demonstrate conclusively that there have been ocean-wide changes in seawater 187Os/188Os over the Pleistocene. Global seawater excursions to relatively unradiogenic 187Os/188Os, indicating decreased continental inputs, occur during cold intervals, times of increased aridity and increased ice cover of old (radiogenic) continental masses. The data thus indicate a direct climatic control on chemical weathering rates and/or composition of weathering products on a glacial-interglacial timescale.
Project(s):
Coverage:
Latitude: 10.706100 * Longitude: -65.169400
Date/Time Start: 1996-02-18T16:30:00 * Date/Time End: 1996-02-19T04:30:00
Minimum DEPTH, sediment/rock: 0.3 m * Maximum DEPTH, sediment/rock: 64.9 m
Event(s):
165-1002C * Latitude: 10.706100 * Longitude: -65.169400 * Date/Time Start: 1996-02-18T16:30:00 * Date/Time End: 1996-02-19T04:30:00 * Elevation: -892.6 m * Penetration: 170.1 m * Recovery: 186 m * Location: Cayman Rise, Caribbean Sea * Campaign: Leg165 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 19 cores; 170.1 m cored; 0 m drilled; 109.3 % recovery
Comment:
Ages before 65 ka based on correlation of G. ruber delta18O record with SPECMAP stack (Peterson et al., 2000 doi:10.2973/odp.proc.sr.165.017.2000), followed by age conversion to the Lisiecki and Raymo (2005 doi:10.1029/2004PA001071) age model. Ages after 65 ka based on linear regression of high resolution ODP Site 1002 14C age record calibrated to the GISP2 Greenland ice core ((Hughen et al., 2004a doi:10.1126/science.1092995) and (Hughen et al., 2004b doi:10.1126/science.1090300))
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Sample code/labelSample labelOxburgh, RachelDSDP/ODP/IODP sample designation
DEPTH, sediment/rockDepth sedmGeocode
AGEAgeka BPGeocode
Osmium-187/Osmium-188 ratio187Os/188OsOxburgh, RachelNegative-thermal ionization mass spectrometry (N-TIMS)in-run precision for all data is better than 4 per mil (external standard reproducibility) and often better than 2 per mil
OsmiumOsng/kgOxburgh, Rachel
Accumulation rate, OsmiumAcc rate Ospg/cm2/kaOxburgh, RachelCalculatedmultiplying the linear sedimentation rate (obtained from the ages and depths of the overlying and underlying samples) by the Os concentration and by a dry bulk density of 0.85 g/ccm (representative value suggested by Yarcinik et al., 2000, doi:10.1029/1999PA900048)
CommentCommentOxburgh, Rachel
Size:
162 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Sample label

Depth sed [m]

Age [ka BP]

187Os/188Os

Os [ng/kg]

Acc rate Os [pg/cm2/ka]

Comment
165-1002C-1H-1,32-340.30.71.0458252
165-1002C-1H-2,82-842.35.01.04532549900
165-1002C-1H-3,132-1344.39.31.04481656500
165-1002C-1H-5,32-346.313.71.02002479700
165-1002C-1H-6,61-638.117.60.97731395400
165-1002C-2H-2,42-4410.322.40.98231264900
165-1002C-2H-3,93-9512.326.70.98061335200
165-1002C-2H-4,142-14414.331.10.98811244900
165-1002C-2H-6,42-4416.335.40.99061275000
165-1002C-3H-1,42-4418.339.71.01271495800
165-1002C-3H-2,92-9420.344.10.98321084200
165-1002C-3H-2,92-9420.344.10.9772111duplicate
165-1002C-3H-3,142-14422.348.40.9425993900
165-1002C-3H-5,42-4424.352.80.95461194700
165-1002C-3H-5,42-4424.352.80.9448114duplicate
165-1002C-3H-5,42-4424.352.80.9487Leachate L1 solution: 0.2 N HNO3 and 5% H2O2 for 15 min
165-1002C-3H-6,91-9326.357.10.95191174600
165-1002C-4H-1,92-9428.361.50.9147933600
165-1002C-4H-1,92-9428.361.50.9052106duplicate
165-1002C-4H-1,92-9428.361.50.9062solution: 0.5N HNO3 and 5% H2O2 for 15 min
165-1002C-4H-1,92-9428.361.50.9181Leachate L3 solution: 1.2N H2SO4 and 5% H2O2 for 24 h
165-1002C-4H-2,141-14330.365.80.96891415500
165-1002C-4H-2,141-14330.365.80.9861144duplicate
165-1002C-4H-4,41-4332.470.31.03261032700
165-1002C-4H-6,140-14236.586.21.0326901800
165-1002C-5H-1,140-14238.396.41.04571412500
165-1002C-5H-3,41-4340.3105.51.04721422800
165-1002C-5H-4,91-9342.3114.61.05461783500
165-1002C-5H-5,140-14244.3123.61.06081903800
165-1002C-5H-7,41-4346.3132.81.0471941500
165-1002C-6H-2,41-4347.1136.20.96541392200
165-1002C-6H-3,92-9450.3151.40.98421653300
165-1002C-6H-4,140-14251.1153.00.98231063000
165-1002C-6H-6,40-4253.1159.90.98911673800
165-1002C-7H-1,42-4456.3172.61.0045952300
165-1002C-7H-2,82-8457.6175.91.0472902900
165-1002C-7H-3,142-14459.7181.51.01841224100
165-1002C-7H-4,92-9460.7183.70.96501184500
165-1002C-7H-5,42-4461.8186.10.9688894300
165-1002C-7H-5,142-14462.8187.41.01861209200
165-1002C-7H-6,91-9363.8188.31.02081427100
165-1002C-7H-7,42-4464.9191.01.0313