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Delaney, Margaret Lois (1989): Mg/Ca and Sr/Ca in calcites and estimated distribution coefficients in marine sediments (Table 2) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.723370, Supplement to: Delaney, ML (1989): Temporal changes in interstitial water chemistry and calcite recrystallization in marine sediments. Earth and Planetary Science Letters, 95(1-2), 23-37, https://doi.org/10.1016/0012-821X(89)90165-9

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Abstract:
Recrystallization processes in marine sediments can alter the extent to which biogenic calcite composition serves as a proxy of oceanic chemical and isotopic history. Models of calcite recrystallization developed to date have resulted in significant insights into these processes, but are not completely adequate to describe the conditions of recrystallization. Marine sediments frequently have concentration gradients in interstitial dissolved calcium, magnesium, and strontium which have probably evolved during sediment accumulation. Realistic, albeit simplified, models of the temporal evolution of interstitial water profiles of Ca, Mg, and Sr were used with several patterns of recrystallization rate variation to predict the composition of recrystallized inorganic calcite. Comparison of predictions with measured Mg/Ca and Sr/Ca ratios in severely altered calcite samples from several Deep Sea Drilling Project sites demonstrates that models incorporating temporal variation in interstitial water composition more successfully predict observed calcite compositions than do models which rely solely on present-day interstitial water chemistry. Temporal changes in interstitial composition are particularly important in interpreting Mg/Ca ratios in conjunction with Sr/Ca ratios. Estimates of Mg distribution coefficients from previous observations in marine sediments, much lower than those in laboratory studies of inorganic calcite, are confirmed by these results. Evaluation of the effects of diagenetic alteration of biogenic calcium carbonate sediment must be a site-specific process, taking into account accumulation history, present interstitial chemistry and its variation in the past, and sample depths and ages.
Project(s):
Deep Sea Drilling Project (DSDP)
Coverage:
Median Latitude: -0.864680 * Median Longitude: 57.725000 * South-bound Latitude: -30.122700 * West-bound Longitude: -19.851300 * North-bound Latitude: 26.592500 * East-bound Longitude: 161.825500
Date/Time Start: 1973-05-21T00:00:00 * Date/Time End: 1980-07-14T00:00:00
Minimum DEPTH, sediment/rock: 225 m * Maximum DEPTH, sediment/rock: 1168 m
Event(s):
30-288_Site  * Latitude: -5.972500 * Longitude: 161.825500 * Date/Time: 1973-05-21T00:00:00 * Elevation: -3000.0 m * Penetration: 14.935 m * Recovery: 1.185 m * Location: South Pacific * Campaign: Leg30 * Basis: Glomar Challenger * Method/Device: Composite Core (COMPCORE) * Comment: 42 cores; 380.5 m cored; 9.5 m drilled; 31.1% recovery
30-289  * Latitude: -0.498700 * Longitude: 158.511500 * Date/Time: 1973-05-31T00:00:00 * Elevation: -2206.0 m * Penetration: 1271 m * Recovery: 709.1 m * Location: South Pacific/PLATEAU * Campaign: Leg30 * Basis: Glomar Challenger * Method/Device: Drilling/drill rig (DRILL) * Comment: 133 cores; 1270.8 m cored; 0 m drilled; 55.8 % recovery
41-366_Site  * Latitude: 5.678000 * Longitude: -19.851300 * Date/Time: 1975-02-22T00:00:00 * Elevation: -2853.0 m * Penetration: 12.175 m * Recovery: 5.799 m * Location: North Atlantic/CONT RISE * Campaign: Leg41 * Basis: Glomar Challenger * Method/Device: Composite Core (COMPCORE) * Comment: 91 cores; 856.5 m cored; 28.5 m drilled; 67.7% recovery
Comment:
Distribution coefficients are calculated from calcite compositions and solution compositions. Interstitial water results include those based on present-day interstitial water composition ("present") and three based on time-averaged interstitial water compositions (“uniform”, “age-dependent”, and “Sr-maximum”). Model parameters for each site were defined as follows (with gradients in mM/m and Sr concentrations in mM): Site 288, accumulation = 1000 m at 10 m/m.y., Ca gradient = 0.023, Mg gradient = -0.025, Sr maximum of 0.7 at 340 m; Site 289, accumulation = 1300 m at 10 m/m.y., Ca = 0.028, Mg = -0.033, Sr maximum of 0.9 at 200 m; Site 366, accumulation = 1000 m at 10 m/m.y., Ca = 0.056, Mg = -0.051, Sr maximum of 1.2 at 500 m; Site 369, accumulation = 600 m at 5 m/m.y., Ca = 0.037, Mg = -0.029, Sr maximum of 1.1 at 460 m. For these sites, model runs used accumulations of 300 and 500 m before Ca and Mg gradients developed; Sr concentrations were constant below the Sr maximum. Site 526, accumulation = 500 m at 5 m/m.y., no Ca or Mg gradient, Sr maximum of 0.24 at 100 m, Sr decreases to 0.08 at depth; results in parentheses for Site 526 use a Ca gradient = 0.050. Distribution coefficients are also calculated based on present-day seawater composition (“seawater”). Depth, sediment for average calculation is given as the deepest depth (mbsf)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1 Event labelEvent
2 DEPTH, sediment/rockDepth sedmGeocode
3 Sample commentSample commentDelaney, Margaret Lois
4 Temperature, calculatedT cal°CDelaney, Margaret LoisCalculatedEstimated from a geothermal gradient of 35 deg C/km and a temperature of 2 deg C at the sediment-water interface
5 Magnesium/Calcium ratioMg/CaDelaney, Margaret LoisCalcite composition (mmol/mol)
6 Strontium/Calcium ratioSr/CaDelaney, Margaret LoisCalcite composition (mmol/mol)
7 Magnesium distribution coefficientMg dist coef10-3Delaney, Margaret LoisCalculatedinterstitial water, present
8 Magnesium distribution coefficientMg dist coef10-3Delaney, Margaret LoisCalculatedinterstitial water, uniform
9 Magnesium distribution coefficientMg dist coef10-3Delaney, Margaret LoisCalculatedinterstitial water, age-dependent
10 Magnesium distribution coefficientMg dist coef10-3Delaney, Margaret LoisCalculatedinterstitial water, Sr-maximum
11 Magnesium distribution coefficientMg dist coef10-3Delaney, Margaret LoisCalculatedseawater
12 Strontium distribution coefficientSr dist coef10-3Delaney, Margaret LoisCalculatedinterstitial water, present
13 Strontium distribution coefficientSr dist coef10-3Delaney, Margaret LoisCalculatedinterstitial water, uniform
14 Strontium distribution coefficientSr dist coef10-3Delaney, Margaret LoisCalculatedinterstitial water, age-dependent
15 Strontium distribution coefficientSr dist coef10-3Delaney, Margaret LoisCalculatedinterstitial water, Sr-maximum
16 Strontium distribution coefficientSr dist coef10-3Delaney, Margaret LoisCalculatedseawater
License:
Creative Commons Attribution 3.0 Unported (CC-BY-3.0)
Size:
111 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 
Event		2 
Depth sed [m]		3 
Sample comment		4 
T cal [°C]
(Estimated from a geothermal g...)		5 
Mg/Ca
(Calcite composition (mmol/mol))		6 
Sr/Ca
(Calcite composition (mmol/mol))		7 
Mg dist coef [10-3]
(interstitial water, present)		8 
Mg dist coef [10-3]
(interstitial water, uniform)		9 
Mg dist coef [10-3]
(interstitial water, age-depen...)		10 
Mg dist coef [10-3]
(interstitial water, Sr-maximum)		11 
Mg dist coef [10-3]
(seawater)		12 
Sr dist coef [10-3]
(interstitial water, present)		13 
Sr dist coef [10-3]
(interstitial water, uniform)		14 
Sr dist coef [10-3]
(interstitial water, age-depen...)		15 
Sr dist coef [10-3]
(interstitial water, Sr-maximum)		16 
Sr dist coef [10-3]
(seawater)
30-288_Site 743Bulk CaCO3302.560.63
30-288_Site849Bulk CaCO31.820.84
30-288_Site878Bulk CaCO32.870.58
30-288_Site878Average2.420.682.10.700.560.630.462827412481
30-289 1168Bulk CaCO3372.320.42
30-2891140Dilute acid leach of CaCO30.51
30-2891168Dilute acid leach of CaCO30.64
30-2891168Average2.320.524.60.700.510.540.442621292062
41-366_Site 783Mixed planktonic foraminifera303.700.65
41-366_Site793Mixed planktonic foraminifera3.520.63
41-366_Site793Average3.610.645.60.470.340.600.692118261577
41-369_Site 447Mixed planktonic foraminifera187.530.70
41-369_Site466Mixed planktonic foraminifera9.930.63
41-369_Site476Mixed planktonic foraminifera8.660.54
41-369_Site486Mixed planktonic foraminifera9.910.76
41-369_Site486Average9.010.665.3<1.70<1.50<2.401.701620281579
74-526_Site 225Bulk CaCO3, chalk layer1012.900.342.82.802.802.802.504958775141
74-526_Site225Bulk CaCO3, chalk layer1.601.301.40364431