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Dalai, Tarun K; Ravizza, Gregory E (2006): (Table 1) Concentrations of Os, Ir, Pt and 187Os/188Os ratio in ODP Hole 130-806C samples [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.710862

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Abstract:
New osmium (Os) isotope and platinum group element (PGE) concentration data are used in conjunction with published 3He and Th isotope data to determine the relative proportions of lithogenic, extraterrestrial and hydrogenous iridium (Ir) in a Pacific pelagic carbonate sequence from the Ocean Drilling Program (ODP) Site 806 on the Ontong Java Plateau (OJP). These calculations demonstrate that lithogenic and extraterrestrial contributions to sedimentary Ir budget are minor, while hydrogenous Ir accounts for roughly 85% of the total Ir. Application of analogous partitioning calculations to previously reported data from a North Pacific red clay sequence (LL44-GPC3) yields very similar results. Total Ir burial fluxes at Site 806 and LL44-GPC3 are also similar, 45 and 30 pg/cm**2/kyr, respectively. Average Ir/3He and Ir/xs230Th_initial ratios calculated from the entire Site 806 data set are similar to those reported earlier for Pacific sites. In general, down-core profiles of Ir, 3He and xs230Th_initial, are not well correlated with one another. However, all three data sets show similar variance and yield sediment mass accumulation rate estimates that agree within a factor of two. While these results indicate that Ir concentration has potential as a point-paleoflux tracer in pelagic carbonates, Ir-based paleoflux estimates are likely subject to uncertainties that are similar to those associated with Co-based paleoflux estimates. Consequently, local calibration of Ir flux in space and time will be required to fully assess the potential of Ir as a point paleoflux tracer. Measured 187Os/188Os of the OJP sediments are systematically lower than the inferred 187Os/188Os of contemporaneous seawater and a clear glacial-interglacial 187Os/188Os variation is lacking. Mixing calculations suggest Os contributions from lithogenic sources are insufficient to explain the observed 187Os/188Os variations. The difference between the 187Os/188Os of bulk sediment and that of seawater is interpreted in terms of subtle contributions of unradiogenic Os carried by particulate extraterrestrial material. Down-core variations of 187Os/188Os with Pt/Ir and Os/Ir also point to contributions from extraterrestrial particles. Mixing calculations for each set of several triplicate analyses suggest that the unradiogenic Os end member cannot be characterized by primary extraterrestrial particles of chondritic composition. It is noteworthy that in efforts aimed at determining the effect of extraterrestrial contributions, 187Os/188Os of pelagic carbonates has greater potential compared to abundances of PGE. An attempt has been made for the first time to estimate sediment mass accumulation rates based on amount of extraterrestrial Os in the OJP samples and previously reported extraterrestrial Os flux. Throughout most of the OJP record, Os isotope-based paleoflux estimates are within a factor of two of those derived using other constant flux tracers. Meaningful flux estimates cannot be made during glacial maxima because the OJP sediments do not record the low 187Os/188Os reported previously. We speculate that this discrepancy may be related to focusing of extraterrestrial particles at the OJP, as has been suggested to explain down-core 3He variations.
Related to:
Dalai, Tarun K; Ravizza, Gregory E (2006): Evaluation of osmium isotopes and iridium as paleoflux tracers in pelagic carbonates. Geochimica et Cosmochimica Acta, 70(15), 3928-3942, https://doi.org/10.1016/j.gca.2006.06.002
Project(s):
Coverage:
Latitude: 0.318500 * Longitude: 159.361000
Date/Time Start: 1990-02-23T01:30:00 * Date/Time End: 1990-02-25T19:00:00
Minimum DEPTH, sediment/rock: 29 m * Maximum DEPTH, sediment/rock: 421 m
Event(s):
130-806C * Latitude: 0.318500 * Longitude: 159.361000 * Date/Time Start: 1990-02-23T01:30:00 * Date/Time End: 1990-02-25T19:00:00 * Elevation: -2520.8 m * Penetration: 776.4 m * Recovery: 523.62 m * Location: North Pacific Ocean * Campaign: Leg130 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 62 cores; 587.6 m cored; 0 m drilled; 89.1 % recovery
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
DEPTH, sediment/rockDepth sedmGeocode
Sample code/labelSample labelDalai, Tarun KDSDP/ODP/IODP sample designation
Sample commentSample commentDalai, Tarun K
Osmium-187/Osmium-188 ratio187Os/188OsDalai, Tarun KInductively coupled plasma - mass spectrometry (ICP-MS)
Osmium-187/Osmium-188, error187Os/188Os e±Dalai, Tarun KCalculated2SD
OsmiumOsng/kgDalai, Tarun KInductively coupled plasma - mass spectrometry (ICP-MS)
IridiumIrng/kgDalai, Tarun KInductively coupled plasma - mass spectrometry (ICP-MS)
PlatinumPtng/kgDalai, Tarun KInductively coupled plasma - mass spectrometry (ICP-MS)
Osmium/Iridium ratioOs/IrDalai, Tarun KCalculated
10 Platinum/Iridium ratioPt/IrDalai, Tarun KCalculated
Size:
441 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Depth sed [m]

Sample label

Sample comment

187Os/188Os

187Os/188Os e [±]

Os [ng/kg]

Ir [ng/kg]

Pt [ng/kg]

Os/Ir
10 
Pt/Ir
29130-806C-1H-1,28-300.9890.0066424.95142.5620.6
48130-806C-1H-1,47-490.9960.0077125.25352.8321.2
54130-806C-1H-1,53-550.9950.0046320.74903.0423.6
76130-806C-1H-1,75-770.9990.0047521.85013.4522.9
99130-806C-1H-1,98-1000.9790.0056324.04412.6518.4
99130-806C-1H-1,98-100replicate 10.9750.0056321.24552.9921.5
119130-806C-1H-1,118-1200.9580.0037537.47182.0019.2
119130-806C-1H-1,118-120replicate 10.9930.0047126.75502.6520.6
119130-806C-1H-1,118-120replicate 20.9950.0037121.05393.3925.6
162130-806C-1H-2,15-170.9350.0075921.23352.8015.8
162130-806C-1H-2,15-17replicate 10.9790.0035417.92953.0416.5
162130-806C-1H-2,15-17replicate 20.9670.0035618.83063.0016.3
179130-806C-1H-2,32-340.9810.0047321.94423.3520.2
193130-806C-1H-3,46-480.9860.0067019.74113.5420.9
204130-806C-1H-2,58-600.9730.0074920.82662.3512.8
204130-806C-1H-2,58-60replicate 10.9680.0055218.12782.8715.4
226130-806C-1H-2,79-810.9840.0065122.23102.3114.0
226130-806C-1H-2,79-81replicate 10.9500.0095127.83361.8512.1
226130-806C-1H-2,79-81replicate 20.9870.0035321.03042.5214.5
240130-806C-1H-2,93-950.9820.0054319.62882.2114.7
250130-806C-1H-2,103-1050.9850.0094219.12832.1814.8
269130-806C-1H-2,122-1240.9980.0058726.66533.2924.5
280130-806C-1H-2,133-1350.9910.0057019.36363.6333.0
298130-806C-1H-3,1-30.9810.0046528.65682.2619.9
309130-806C-1H-3,16-180.9800.0057023.85742.9424.1
309130-806C-1H-3,16-18replicate 10.9680.0047425.96052.8623.4
309130-806C-1H-3,16-18replicate 20.9840.0027026.45462.6520.7
327130-806C-1H-3,34-360.9430.0057321.74663.3521.5
327130-806C-1H-3,34-36replicate 10.9910.0036718.04733.7226.3
327130-806C-1H-3,34-36replicate 20.9920.0046720.44713.2923.1
346130-806C-1H-3,53-550.9870.0067420.16033.6630.0
353130-806C-1H-3,60-620.9660.0076323.85842.6424.6
370130-806C-1H-3,73-750.9720.0076825.15972.7123.8
370130-806C-1H-3,73-75replicate 10.9430.0087124.96252.8525.1
370130-806C-1H-3,73-75replicate 20.9750.0037525.96172.8823.8
373130-806C-1H-3,76-780.9880.0047825.07843.1431.4
373130-806C-1H-3,76-78replicate 10.9620.0038027.77322.8926.4
373130-806C-1H-3,76-78replicate 20.9790.0047927.57582.8727.6
385130-806C-1H-3,88-900.9150.0056123.34072.6217.5
385130-806C-1H-3,88-90replicate 10.9840.0046019.74183.0621.2
385130-806C-1H-3,88-90replicate 20.9430.0036022.24152.6818.7
391130-806C-1H-3,94-960.9310.0065521.53572.5716.6
391130-806C-1H-3,94-96replicate 10.9440.0035523.33512.3515.0
391130-806C-1H-3,94-96replicate 20.9790.0045421.23372.5415.9
400130-806C-1H-3,103-1050.9530.0085018.23412.7618.7
400130-806C-1H-3,103-105replicate 10.9720.0024820.13272.4016.3
400130-806C-1H-3,103-105replicate 20.9490.0044919.63212.5216.4
415130-806C-1H-3,118-1200.9900.0058122.96853.5229.9
415130-806C-1H-3,118-120replicate 10.9770.0058324.26943.4128.7
415130-806C-1H-3,118-120replicate 20.9540.0028627.26853.1725.2
421130-806C-1H-3,124-1260.9570.0065425.43792.1414.9
421130-806C-1H-3,124-126replicate 10.9560.0035624.03892.3216.2