Kohnen, Math E L; Sinninghe Damsté, Jaap S; Kock-van Dalen, A C; ten Haven, H Lo; Rullkötter, Jürgen; de Leeuw, Jan W (1990): (Table 1) Organic carbon contents and vitrinite reflection in sediments from DSDP Holes 63-467, 63-471, and 64-481A [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.707468
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Abstract:
A number of C25 and C30 highly branched isoprenoid (HBI) sulphur compounds (E.G., thiolanes, 1-oxo-thiolanes, thiophenes, and benzo[b]thiophenes) with 2,6,10,14-tetramethyl-7-(3-methylpentyl)pentadecane and 2,6,10,14,18-pentamethyl-7-(3-methylpentyl)nonadecane carbon skeletons were identified in sediments, ranging from Holocene to Upper Cretaceous. These identifications are based on mass spectral characterisation, desulphurisation, and, in some cases, by comparison of mass spectral and relative retention time data with those of authentic standards. The presence of unsaturated C25 and C30 HBI thiolanes in a Recent sediment from the Black Sea (age 3-6 ka) strongly supports their formation during early diagenesis. The co-occurrence of HBI polyenes (C25 and C30) and unsaturated HBI thiolanes (C25 and C30) possessing two double bonds less than the corresponding HBI polyenes, in this Recent sediment, testifies to the formation of unsaturated HBI thiolanes by a reaction of inorganic sulphur species with double bonds of the HBI polyenes. Furthermore, a diagenetic scheme for HBI sulphur compounds is proposed based on the identification of HBI sulphur compounds in sediment samples with different maturity levels.
Related to:
Kohnen, Math E L; Sinninghe Damsté, Jaap S; Kock-van Dalen, A C; ten Haven, H Lo; Rullkötter, Jürgen; de Leeuw, Jan W (1990): Origin and diagenetic transformations of C25 and C30 highly branched isoprenoid sulphur compounds: Further evidence for the formation of organically bound sulphur during early diagenesis. Geochimica et Cosmochimica Acta, 54(11), 3053-3063, https://doi.org/10.1016/0016-7037(90)90121-Z
Project(s):
Deep Sea Drilling Project (DSDP)
Coverage:
Median Latitude: 28.194900 * Median Longitude: -114.920600 * South-bound Latitude: 23.482200 * West-bound Longitude: -120.757800 * North-bound Latitude: 33.849500 * East-bound Longitude: -111.507700
Date/Time Start: 1978-10-10T00:00:00 * Date/Time End: 1979-01-03T00:00:00
Minimum DEPTH, sediment/rock: 130.18 m * Maximum DEPTH, sediment/rock: 911.07 m
Event(s):
63-467 * Latitude: 33.849500 * Longitude: -120.757800 * Date/Time: 1978-10-10T00:00:00 * Elevation: -2128.0 m * Penetration: 1041.5 m * Recovery: 399.1 m * Location: North Pacific/GAP * Campaign: Leg63 * Basis: Glomar Challenger * Method/Device: Drilling/drill rig (DRILL) * Comment: 100 cores; 946.5 m cored; 38 m drilled; 42.2 % recovery
63-471 * Latitude: 23.482200 * Longitude: -112.496300 * Date/Time: 1978-11-08T00:00:00 * Elevation: -3101.0 m * Penetration: 823 m * Recovery: 348.8 m * Location: North Pacific/FAN * Campaign: Leg63 * Basis: Glomar Challenger * Method/Device: Drilling/drill rig (DRILL) * Comment: 83 cores; 776 m cored; 28.5 m drilled; 45 % recovery
64-481A * Latitude: 27.253000 * Longitude: -111.507700 * Date/Time: 1979-01-03T00:00:00 * Elevation: -1998.0 m * Penetration: 374.5 m * Recovery: 159 m * Location: North Pacific/Gulf of California/BASIN * Campaign: Leg64 * Basis: Glomar Challenger * Method/Device: Drilling/drill rig (DRILL) * Comment: 31 cores; 293.5 m cored; 39 m drilled; 54.2 % recovery
Parameter(s):
| # | Name | Short Name | Unit | Principal Investigator | Method/Device | Comment |
|---|---|---|---|---|---|---|
| 1 | Event label | Event | ||||
| 2 | Latitude of event | Latitude | ||||
| 3 | Longitude of event | Longitude | ||||
| 4 | Elevation of event | Elevation | m | |||
| 5 | DEPTH, sediment/rock | Depth sed | m | Geocode | ||
| 6 | Sample code/label | Sample label | Kohnen, Math E L | DSDP/ODP/IODP sample designation | ||
| 7 | Epoch | Epoch | Kohnen, Math E L | |||
| 8 | Rock type | Rock | Kohnen, Math E L | |||
| 9 | Carbon, organic, total | TOC | % | Kohnen, Math E L | ||
| 10 | Vitrinite reflection | Vitr refl | % | Kohnen, Math E L |
License:
Creative Commons Attribution 3.0 Unported (CC-BY-3.0)
Size:
25 data points
Data
| 1 Event | 2 Latitude | 3 Longitude | 4 Elevation [m] | 5 Depth sed [m] | 6 Sample label | 7 Epoch | 8 Rock | 9 TOC [%] | 10 Vitr refl [%] |
|---|---|---|---|---|---|---|---|---|---|
| 63-467 | 33.8495 | -120.7578 | -2128.0 | 502.58 | 63-467-54-2,100-115 | Late Miocene | silty claystone | 4.37 | 0.4 |
| 63-467 | 33.8495 | -120.7578 | -2128.0 | 911.07 | 63-467-97-2,105-109 | Middle Miocene | calcareous claystone | 1.63 | 0.4 |
| 63-471 | 23.4822 | -112.4963 | -3101.0 | 316.05 | 63-471-34-2,103-107 | Late Miocene | silty claystone | 0.81 | 0.3 |
| 63-471 | 23.4822 | -112.4963 | -3101.0 | 409.59 | 63-471-44-1,100-118 | Middle Miocene | silty claystone | 1.12 | 0.4 |
| 64-481A | 27.2530 | -111.5077 | -1998.0 | 130.18 | 64-481A-10-2,110-125 | Late Pleistocene | diatomaceous mud | 5.76 | 0.3 |