<?xml version="1.0" encoding="UTF-8"?><md:MetaData xmlns:md="http://www.pangaea.de/MetaData" version="2026-04-13">
<md:citation id="dataset696416">
<md:author id="dataset.author25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:author>
<md:author id="dataset.author32813">
<md:lastName>Koski</md:lastName>
<md:firstName>Randolph A</md:firstName>
</md:author>
<md:author id="dataset.author32814">
<md:lastName>Morgenson</md:lastName>
<md:firstName>Lisa A</md:firstName>
</md:author>
<md:year>1982</md:year>
<md:title>(Table 1) Chemical and lithological composition of rocks from DSDP Hole 465A</md:title>
<md:type id="dataset.reftype10" includeInCitation="true">dataset</md:type>
<md:URI>https://doi.org/10.1594/PANGAEA.696416</md:URI>
<md:supplementTo id="ref29002">
<md:author id="ref29002.author25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:author>
<md:author id="ref29002.author32813">
<md:lastName>Koski</md:lastName>
<md:firstName>Randolph A</md:firstName>
</md:author>
<md:author id="ref29002.author32814">
<md:lastName>Morgenson</md:lastName>
<md:firstName>Lisa A</md:firstName>
</md:author>
<md:year>1982</md:year>
<md:title>Uranium and thorium enrichment in rocks from the base of DSDP Hole 465A, Hess Rise, Central North Pacific</md:title>
<md:type id="ref29002.reftype1">journal article</md:type>
<md:source id="ref29002.journal3311" relatedTermIds="33971" type="journal">Chemical Geology</md:source>
<md:volume>36(3-4)</md:volume>
<md:URI>https://doi.org/10.1016/0009-2541(82)90050-X</md:URI>
<md:pages>237-251</md:pages>
</md:supplementTo>
</md:citation>
<md:abstract>Uranium and thorium are concentrated in Cretaceous limestone, chert, ash, basalt, and other rock types at Deep Sea Drilling Project Site 465 located on the southern Hess Rise in the central North Pacific. U concentrations, up to 194 ppm on a carbonate-free basis, are among the highest recorded for any deep-sea deposits. U was initially derived from seawater and concentrated by absorption on terrigenous (humic) organic matter in limestone in a shallow marine environment. U and Th were probably concentrated further by low-temperature hydrothermal fluids emanating from the basaltic basement. Mainly montmorillonite, an alteration product of basalt and ash, and organic matter in sedimentary rocks acted as hosts for U and Th.
The unique combination of sediments rich in humic organic matter, abundant smectite in altered ash and basalt, and warm hydrothermal solutions provided the necessary conditions for migration and concentration of U and Th. To better understand the conditions limiting the migrating and concentration of U and Th, other rocks deposited during the ocean-wide Cretaceous anoxic events should be analyzed for these elements.</md:abstract>
<md:extent>
<md:geographic>
<md:westBoundLongitude>178.919</md:westBoundLongitude>
<md:eastBoundLongitude>178.919</md:eastBoundLongitude>
<md:southBoundLatitude>33.8205</md:southBoundLatitude>
<md:northBoundLatitude>33.8205</md:northBoundLatitude>
<md:meanLongitude>178.919</md:meanLongitude>
<md:meanLatitude>33.8205</md:meanLatitude>
</md:geographic>
<md:temporal>
<md:minDateTime>1978-08-23T00:00:00</md:minDateTime>
<md:maxDateTime>1978-08-23T00:00:00</md:maxDateTime>
</md:temporal>
<md:elevation geocodeId="geocode1" name="DEPTH, sediment/rock" unit="m">
<md:min>392.8</md:min>
<md:max>419.5</md:max>
</md:elevation>
<md:topoType id="topotype3">vertical profile</md:topoType>
</md:extent>
<md:project id="project4" type="International">
<md:label>DSDP</md:label>
<md:name>Deep Sea Drilling Project</md:name>
<md:URI>http://www.deepseadrilling.org/</md:URI>
<md:institution id="project4.inst41">
<md:name>Deep Sea Drilling Project</md:name>
<md:optionalName>DSDP</md:optionalName>
</md:institution>
</md:project>
<md:event displayTypeName="Event" id="event12681" typeName="Generic Event">
<md:label>62-465A</md:label>
<md:latitude>33.8205</md:latitude>
<md:longitude>178.919</md:longitude>
<md:location id="event12681.term20691">
<md:name>North Pacific/CONT RISE</md:name>
</md:location>
<md:elevation>-2161.0</md:elevation>
<md:dateTime>1978-08-23T00:00:00</md:dateTime>
<md:campaign displayTypeName="Campaign" id="event12681.campaign3374925" legacyId="event12681.campaign184" typeName="Generic Campaign">
<md:label>Leg62</md:label>
<md:name warning="deprecated">Leg62</md:name>
<md:dateTime>1978-07-29T00:00:00</md:dateTime>
<md:start warning="deprecated">1978-07-29</md:start>
<md:dateTime2>1978-09-07T00:00:00</md:dateTime2>
<md:end warning="deprecated">1978-09-07</md:end>
<md:basis id="event12681.campaign3374925.basis12">
<md:name>Glomar Challenger</md:name>
<md:URI>https://www-odp.tamu.edu:443/glomar.html</md:URI>
</md:basis>
<md:responsible>Thiede, Jörn</md:responsible>
<md:chiefScientist warning="deprecated">Thiede, Jörn</md:chiefScientist>
<md:responsible>Vallier, Tracy L</md:responsible>
<md:chiefScientist warning="deprecated">Vallier, Tracy L</md:chiefScientist>
<md:attribute attid="76863" name="Report">doi:10.2973/dsdp.proc.62.1981</md:attribute>
</md:campaign>
<md:basis id="event12681.basis12">
<md:name>Glomar Challenger</md:name>
<md:URI>https://www-odp.tamu.edu:443/glomar.html</md:URI>
</md:basis>
<md:method id="event12681.method10974">
<md:name>Drilling/drill rig</md:name>
<md:optionalName>DRILL</md:optionalName>
</md:method>
<md:attribute attid="19162" name="Penetration">476 m</md:attribute>
<md:attribute attid="19163" name="Recovery">98.9 m</md:attribute>
<md:comment>43 cores; 408.5 m cored; 9.5 m drilled; 24.2 % recovery</md:comment>
</md:event>
<md:size unit="data points">278</md:size>
<md:license id="license101">
<md:label>CC-BY-3.0</md:label>
<md:name>Creative Commons Attribution 3.0 Unported</md:name>
<md:URI>https://creativecommons.org/licenses/by/3.0/</md:URI>
</md:license>
<md:comment>In the sample 465A-40-1, 145 (calcareous ash / sulfide-rich fraction) contents of major oxides were measured by quantitative emission spectroscopy; in the samples 465A-40-2, 62 (altered ash) and 465A-40-2, 62 (altered ash, &lt;1 µm fraction) contents of major oxides were measured by semi-quantitative emission spectroscopy.</md:comment>
<md:matrixColumn behaviour="1" col="0" format="##0.00" id="col0.ds1357498" source="geocode" type="numeric">
<md:parameter id="col0.ds1357498.geocode1">
<md:name>DEPTH, sediment/rock</md:name>
<md:shortName>Depth sed</md:shortName>
<md:unit>m</md:unit>
<md:term endOffset="5" fragment="1" id="col0.ds1357498.geocode1.term1073131" semanticURI="urn:obo:pato:term:0001595" startOffset="0" terminologyId="14" terminologyLabel="PATO">
<md:name>depth</md:name>
<md:URI>http://purl.obolibrary.org/obo/PATO_0001595</md:URI>
</md:term>
<md:term endOffset="15" fragment="2" id="col0.ds1357498.geocode1.term38263" startOffset="7" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>sediment</md:name>
<md:URI>http://purl.obolibrary.org/obo/ENVO_00002007</md:URI>
</md:term>
<md:term endOffset="20" fragment="3" id="col0.ds1357498.geocode1.term41056" startOffset="16" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>rock</md:name>
</md:term>
<md:term id="col0.ds1357498.geocode1.term43863" semanticURI="http://qudt.org/1.1/vocab/quantity#Length" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Length</md:name>
<md:optionalName>L</md:optionalName>
<md:URI>http://dbpedia.org/resource/Length</md:URI>
</md:term>
</md:parameter>
<md:caption>Depth sed [m]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="1" id="col1.ds10538371" source="data" type="string">
<md:parameter id="col1.ds10538371.param790">
<md:name>Sample code/label</md:name>
<md:shortName>Sample label</md:shortName>
</md:parameter>
<md:method id="col1.ds10538371.method5059">
<md:name>DSDP/ODP/IODP sample designation</md:name>
<md:URI>hdl:10013/epic.27914.d001</md:URI>
</md:method>
<md:PI id="col1.ds10538371.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>Sample label (DSDP/ODP/IODP sample designation)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="2" id="col2.ds10538372" source="data" type="string">
<md:parameter id="col2.ds10538372.param14536">
<md:name>Rock type</md:name>
<md:shortName>Rock</md:shortName>
<md:term endOffset="4" fragment="1" id="col2.ds10538372.param14536.term41056" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>rock</md:name>
</md:term>
</md:parameter>
<md:PI id="col2.ds10538372.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>Rock</md:caption>
</md:matrixColumn>
<md:matrixColumn col="3" id="col3.ds10538373" source="data" type="string">
<md:parameter id="col3.ds10538373.param2834">
<md:name>Lithology/composition/facies</md:name>
<md:shortName>Lithology</md:shortName>
</md:parameter>
<md:PI id="col3.ds10538373.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>Lithology</md:caption>
</md:matrixColumn>
<md:matrixColumn col="4" id="col4.ds10538374" source="data" type="string">
<md:parameter id="col4.ds10538374.param18371">
<md:name>Minerals</md:name>
<md:shortName>Minerals</md:shortName>
</md:parameter>
<md:PI id="col4.ds10538374.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:comment>major</md:comment>
<md:caption>Minerals (major)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="5" id="col5.ds10538375" source="data" type="string">
<md:parameter id="col5.ds10538375.param18371">
<md:name>Minerals</md:name>
<md:shortName>Minerals</md:shortName>
</md:parameter>
<md:PI id="col5.ds10538375.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:comment>moderate</md:comment>
<md:caption>Minerals (moderate)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="6" id="col6.ds10538376" source="data" type="string">
<md:parameter id="col6.ds10538376.param18371">
<md:name>Minerals</md:name>
<md:shortName>Minerals</md:shortName>
</md:parameter>
<md:PI id="col6.ds10538376.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:comment>minor</md:comment>
<md:caption>Minerals (minor)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="7" id="col7.ds10538377" source="data" type="string">
<md:parameter id="col7.ds10538377.param18371">
<md:name>Minerals</md:name>
<md:shortName>Minerals</md:shortName>
</md:parameter>
<md:PI id="col7.ds10538377.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:comment>trace</md:comment>
<md:caption>Minerals (trace)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="8" format="##0.00" id="col8.ds10538379" source="data" type="numeric">
<md:parameter id="col8.ds10538379.param702">
<md:name>Silicon dioxide</md:name>
<md:shortName>SiO2</md:shortName>
<md:unit>%</md:unit>
<md:URI>https://en.wikipedia.org/wiki/Silicon_dioxide</md:URI>
<md:term endOffset="15" fragment="1" id="col8.ds10538379.param702.term1073224" semanticURI="http://purl.obolibrary.org/obo/CHEBI_30563" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>silicon dioxide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_30563</md:URI>
</md:term>
<md:term id="col8.ds10538379.param702.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col8.ds10538379.method4962">
<md:name>X-ray fluorescence on pressed powder</md:name>
</md:method>
<md:PI id="col8.ds10538379.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>SiO2 [%] (X-ray fluorescence on pressed...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="9" format="##0.00" id="col9.ds10538380" source="data" type="numeric">
<md:parameter id="col9.ds10538380.param704">
<md:name>Aluminium oxide</md:name>
<md:shortName>Al2O3</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="15" fragment="1" id="col9.ds10538380.param704.term1074034" semanticURI="http://purl.obolibrary.org/obo/CHEBI_30187" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>aluminium oxide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_30187</md:URI>
</md:term>
<md:term id="col9.ds10538380.param704.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col9.ds10538380.method4962">
<md:name>X-ray fluorescence on pressed powder</md:name>
</md:method>
<md:PI id="col9.ds10538380.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>Al2O3 [%] (X-ray fluorescence on pressed...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="10" format="##0.00" id="col10.ds10538381" source="data" type="numeric">
<md:parameter id="col10.ds10538381.param703">
<md:name>Titanium dioxide</md:name>
<md:shortName>TiO2</md:shortName>
<md:unit>%</md:unit>
<md:URI>https://en.wikipedia.org/wiki/Titanium_dioxide</md:URI>
<md:term endOffset="16" fragment="1" id="col10.ds10538381.param703.term1074190" semanticURI="http://purl.obolibrary.org/obo/CHEBI_32234" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>titanium dioxide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_32234</md:URI>
</md:term>
<md:term id="col10.ds10538381.param703.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col10.ds10538381.method4962">
<md:name>X-ray fluorescence on pressed powder</md:name>
</md:method>
<md:PI id="col10.ds10538381.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>TiO2 [%] (X-ray fluorescence on pressed...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="11" format="##0.00" id="col11.ds10538382" source="data" type="numeric">
<md:parameter id="col11.ds10538382.param705">
<md:name>Iron oxide, Fe2O3</md:name>
<md:shortName>Fe2O3</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="10" fragment="1" id="col11.ds10538382.param705.term1073388" semanticURI="http://purl.obolibrary.org/obo/CHEBI_50816" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>iron oxide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_50816</md:URI>
</md:term>
<md:term endOffset="17" fragment="2" id="col11.ds10538382.param705.term40802" startOffset="12" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>ferric oxide</md:name>
<md:optionalName>Fe2O3</md:optionalName>
</md:term>
<md:term id="col11.ds10538382.param705.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col11.ds10538382.method4962">
<md:name>X-ray fluorescence on pressed powder</md:name>
</md:method>
<md:PI id="col11.ds10538382.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:comment>total Fe as Fe2O3</md:comment>
<md:caption>Fe2O3 [%] (total Fe as Fe2O3, X-ray fluo...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="12" format="##0.00" id="col12.ds10538383" source="data" type="numeric">
<md:parameter id="col12.ds10538383.param707">
<md:name>Magnesium oxide</md:name>
<md:shortName>MgO</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="15" fragment="1" id="col12.ds10538383.param707.term1074058" semanticURI="http://purl.obolibrary.org/obo/CHEBI_31794" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>magnesium oxide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_31794</md:URI>
</md:term>
<md:term id="col12.ds10538383.param707.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col12.ds10538383.method4962">
<md:name>X-ray fluorescence on pressed powder</md:name>
</md:method>
<md:PI id="col12.ds10538383.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>MgO [%] (X-ray fluorescence on pressed...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="13" format="##0.00" id="col13.ds10538384" source="data" type="numeric">
<md:parameter id="col13.ds10538384.param708">
<md:name>Calcium oxide</md:name>
<md:shortName>CaO</md:shortName>
<md:unit>%</md:unit>
<md:URI>https://en.wikipedia.org/wiki/Calcium_oxide</md:URI>
<md:term endOffset="13" fragment="1" id="col13.ds10538384.param708.term1074050" semanticURI="http://purl.obolibrary.org/obo/CHEBI_31344" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>calcium oxide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_31344</md:URI>
</md:term>
<md:term id="col13.ds10538384.param708.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col13.ds10538384.method4962">
<md:name>X-ray fluorescence on pressed powder</md:name>
</md:method>
<md:PI id="col13.ds10538384.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>CaO [%] (X-ray fluorescence on pressed...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="14" format="###0.00" id="col14.ds10538385" source="data" type="numeric">
<md:parameter id="col14.ds10538385.param1825">
<md:name>Sodium oxide</md:name>
<md:shortName>Na2O</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="12" fragment="1" id="col14.ds10538385.param1825.term49257" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>sodium oxide</md:name>
<md:optionalName>Na2O</md:optionalName>
<md:URI>https://pubchem.ncbi.nlm.nih.gov/compound/73971</md:URI>
</md:term>
<md:term id="col14.ds10538385.param1825.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col14.ds10538385.method4962">
<md:name>X-ray fluorescence on pressed powder</md:name>
</md:method>
<md:PI id="col14.ds10538385.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>Na2O [%] (X-ray fluorescence on pressed...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="15" format="##0.00" id="col15.ds10538386" source="data" type="numeric">
<md:parameter id="col15.ds10538386.param811">
<md:name>Potassium oxide</md:name>
<md:shortName>K2O</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="15" fragment="1" id="col15.ds10538386.param811.term2632269" semanticURI="http://purl.obolibrary.org/obo/CHEBI_88321" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>potassium oxide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_88321</md:URI>
</md:term>
<md:term id="col15.ds10538386.param811.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col15.ds10538386.method4962">
<md:name>X-ray fluorescence on pressed powder</md:name>
</md:method>
<md:PI id="col15.ds10538386.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>K2O [%] (X-ray fluorescence on pressed...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="16" format="##0.00" id="col16.ds10538387" source="data" type="numeric">
<md:parameter id="col16.ds10538387.param709">
<md:name>Phosphorus pentoxide</md:name>
<md:shortName>P2O5</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="16" fragment="1" id="col16.ds10538387.param709.term1074191" semanticURI="http://purl.obolibrary.org/obo/CHEBI_37349" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>phosphorus oxide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_37349</md:URI>
</md:term>
<md:term id="col16.ds10538387.param709.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col16.ds10538387.method4962">
<md:name>X-ray fluorescence on pressed powder</md:name>
</md:method>
<md:PI id="col16.ds10538387.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>P2O5 [%] (X-ray fluorescence on pressed...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="17" format="####0.0" id="col17.ds10538388" source="data" type="numeric">
<md:parameter id="col17.ds10538388.param27315">
<md:name>Barium oxide</md:name>
<md:shortName>BaO</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="12" fragment="1" id="col17.ds10538388.param27315.term49339" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>barium oxide</md:name>
<md:URI>https://pubchem.ncbi.nlm.nih.gov/compound/62392</md:URI>
</md:term>
<md:term id="col17.ds10538388.param27315.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col17.ds10538388.method4962">
<md:name>X-ray fluorescence on pressed powder</md:name>
</md:method>
<md:PI id="col17.ds10538388.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>BaO [%] (X-ray fluorescence on pressed...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="18" format="#0.00" id="col18.ds10538389" source="data" type="numeric">
<md:parameter id="col18.ds10538389.param2842">
<md:name>Sulfite</md:name>
<md:shortName>[SO3]2-</md:shortName>
<md:unit>%</md:unit>
<md:URI>https://en.wikipedia.org/wiki/Sulfite</md:URI>
<md:term endOffset="7" fragment="1" id="col18.ds10538389.param2842.term1073626" semanticURI="http://purl.obolibrary.org/obo/CHEBI_17359" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>sulfite</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_17359</md:URI>
</md:term>
<md:term id="col18.ds10538389.param2842.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:PI id="col18.ds10538389.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:comment>3 by difference on barite-rich samples</md:comment>
<md:caption>[SO3]2- [%] (3 by difference on barite-ric...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="19" format="####0" id="col19.ds10538390" source="data" type="numeric">
<md:parameter id="col19.ds10538390.param24619">
<md:name>Manganese</md:name>
<md:shortName>Mn</md:shortName>
<md:unit>mg/kg</md:unit>
<md:term endOffset="9" fragment="1" id="col19.ds10538390.param24619.term38521" semanticURI="http://purl.obolibrary.org/obo/CHEBI_18291" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>manganese</md:name>
<md:optionalName>Mn</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:18291</md:URI>
</md:term>
</md:parameter>
<md:method id="col19.ds10538390.method4962">
<md:name>X-ray fluorescence on pressed powder</md:name>
</md:method>
<md:PI id="col19.ds10538390.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>Mn [mg/kg] (X-ray fluorescence on pressed...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="20" format="#0.00" id="col20.ds10538391" source="data" type="numeric">
<md:parameter id="col20.ds10538391.param2208">
<md:name>Loss on ignition</md:name>
<md:shortName>LOI</md:shortName>
<md:unit>%</md:unit>
<md:URI>http://en.wikipedia.org/wiki/Loss_on_ignition</md:URI>
<md:term endOffset="4" fragment="1" id="col20.ds10538391.param2208.term41092" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>loss</md:name>
</md:term>
<md:term id="col20.ds10538391.param2208.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:PI id="col20.ds10538391.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:comment>at 1050°C</md:comment>
<md:caption>LOI [%] (at 1050°C)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="21" format="###0.00" id="col21.ds10538392" source="data" type="numeric">
<md:parameter id="col21.ds10538392.param6166">
<md:name>Sum</md:name>
<md:shortName>Sum</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="3" fragment="1" id="col21.ds10538392.param6166.term38380" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>sum</md:name>
<md:URI>http://www.oxforddictionaries.com/definition/american_english/sum</md:URI>
</md:term>
<md:term id="col21.ds10538392.param6166.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col21.ds10538392.method50">
<md:name>Calculated</md:name>
</md:method>
<md:PI id="col21.ds10538392.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>Sum [%] (Calculated)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="22" format="#0.00" id="col22.ds10538393" source="data" type="numeric">
<md:parameter id="col22.ds10538393.param67">
<md:name>Carbon, organic, total</md:name>
<md:shortName>TOC</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="6" fragment="1" id="col22.ds10538393.param67.term38477" semanticURI="http://purl.obolibrary.org/obo/CHEBI_27594" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>carbon</md:name>
<md:optionalName>C</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:27594</md:URI>
</md:term>
<md:term endOffset="15" fragment="2" id="col22.ds10538393.param67.term44419" startOffset="8" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>organic</md:name>
</md:term>
<md:term endOffset="22" fragment="3" id="col22.ds10538393.param67.term38253" startOffset="17" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>total</md:name>
<md:URI>https://www.oxforddictionaries.com/definition/american_english/total</md:URI>
</md:term>
<md:term id="col22.ds10538393.param67.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col22.ds10538393.method5004">
<md:name>Element analyser CHN, LECO WR-12</md:name>
<md:term id="col22.ds10538393.method5004.term67625" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chemical property sensors</md:name>
</md:term>
<md:term id="col22.ds10538393.method5004.term2299833" semanticURI="SDN:L22::TOOL0631" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>CHN elemental analyser</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L22/current/TOOL0631/</md:URI>
</md:term>
</md:method>
<md:PI id="col22.ds10538393.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>TOC [%] (Element analyser CHN, LECO WR-12)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="23" format="#0.0" id="col23.ds10538394" source="data" type="numeric">
<md:parameter id="col23.ds10538394.param70">
<md:name>Calcium carbonate</md:name>
<md:shortName>CaCO3</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="17" fragment="1" id="col23.ds10538394.param70.term1074204" semanticURI="http://purl.obolibrary.org/obo/CHEBI_3311" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>calcium carbonate</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_3311</md:URI>
</md:term>
<md:term id="col23.ds10538394.param70.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col23.ds10538394.method5004">
<md:name>Element analyser CHN, LECO WR-12</md:name>
<md:term id="col23.ds10538394.method5004.term67625" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chemical property sensors</md:name>
</md:term>
<md:term id="col23.ds10538394.method5004.term2299833" semanticURI="SDN:L22::TOOL0631" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>CHN elemental analyser</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L22/current/TOOL0631/</md:URI>
</md:term>
</md:method>
<md:PI id="col23.ds10538394.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>CaCO3 [%] (Element analyser CHN, LECO WR-12)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="24" format="#####0.00" id="col24.ds10538395" source="data" type="numeric">
<md:parameter id="col24.ds10538395.param701">
<md:name>Uranium</md:name>
<md:shortName>U</md:shortName>
<md:unit>mg/kg</md:unit>
<md:term endOffset="7" fragment="1" id="col24.ds10538395.param701.term40550" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>uranium</md:name>
</md:term>
</md:parameter>
<md:method id="col24.ds10538395.method190">
<md:name>Element analysis, neutron activation (NAA)</md:name>
<md:term id="col24.ds10538395.method190.term67625" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chemical property sensors</md:name>
</md:term>
<md:term id="col24.ds10538395.method190.term2299468" semanticURI="SDN:L05::LAB01" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>elemental analysers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB01/</md:URI>
</md:term>
</md:method>
<md:PI id="col24.ds10538395.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:caption>U [mg/kg] (Element analysis, neutron act...)</md:caption>
</md:matrixColumn>
<md:matrixColumn col="25" format="#0.0" id="col25.ds10538396" source="data" type="numeric">
<md:parameter id="col25.ds10538396.param1546">
<md:name>Thorium</md:name>
<md:shortName>Th</md:shortName>
<md:unit>mg/kg</md:unit>
<md:term endOffset="7" fragment="1" id="col25.ds10538396.param1546.term1073193" semanticURI="http://purl.obolibrary.org/obo/CHEBI_33385" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>thorium</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_33385</md:URI>
</md:term>
</md:parameter>
<md:method id="col25.ds10538396.method190">
<md:name>Element analysis, neutron activation (NAA)</md:name>
<md:term id="col25.ds10538396.method190.term67625" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chemical property sensors</md:name>
</md:term>
<md:term id="col25.ds10538396.method190.term2299468" semanticURI="SDN:L05::LAB01" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>elemental analysers</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/LAB01/</md:URI>
</md:term>
</md:method>
<md:PI id="col25.ds10538396.pi25771">
<md:lastName>Hein</md:lastName>
<md:firstName>James R</md:firstName>
<md:eMail>jhein@usgs.gov</md:eMail>
</md:PI>
<md:comment>differences in detection limits are due to dilutions required to complete the analysis</md:comment>
<md:caption>Th [mg/kg] (differences in detection limi...)</md:caption>
</md:matrixColumn>
<md:keywords>
<md:techKeyword type="autoGenerated">supplement</md:techKeyword>
<md:techKeyword type="autoGenerated">citable</md:techKeyword>
<md:techKeyword type="autoGenerated">author25771</md:techKeyword>
<md:techKeyword type="autoGenerated">author32813</md:techKeyword>
<md:techKeyword type="autoGenerated">author32814</md:techKeyword>
<md:techKeyword type="autoGenerated">basis12</md:techKeyword>
<md:techKeyword type="autoGenerated">campaign184</md:techKeyword>
<md:techKeyword type="autoGenerated">campaign3374925</md:techKeyword>
<md:techKeyword type="autoGenerated">event12681</md:techKeyword>
<md:techKeyword type="autoGenerated">geocode1</md:techKeyword>
<md:techKeyword type="autoGenerated">geocode1599</md:techKeyword>
<md:techKeyword type="autoGenerated">geocode1600</md:techKeyword>
<md:techKeyword type="autoGenerated">geocode1601</md:techKeyword>
<md:techKeyword type="autoGenerated">geocode8128</md:techKeyword>
<md:techKeyword type="autoGenerated">inst41</md:techKeyword>
<md:techKeyword type="autoGenerated">journal3311</md:techKeyword>
<md:techKeyword type="autoGenerated">license101</md:techKeyword>
<md:techKeyword type="autoGenerated">method10974</md:techKeyword>
<md:techKeyword type="autoGenerated">method190</md:techKeyword>
<md:techKeyword type="autoGenerated">method4962</md:techKeyword>
<md:techKeyword type="autoGenerated">method50</md:techKeyword>
<md:techKeyword type="autoGenerated">method5004</md:techKeyword>
<md:techKeyword type="autoGenerated">method5059</md:techKeyword>
<md:techKeyword type="autoGenerated">param14536</md:techKeyword>
<md:techKeyword type="autoGenerated">param1546</md:techKeyword>
<md:techKeyword type="autoGenerated">param1825</md:techKeyword>
<md:techKeyword type="autoGenerated">param18371</md:techKeyword>
<md:techKeyword type="autoGenerated">param2208</md:techKeyword>
<md:techKeyword type="autoGenerated">param24619</md:techKeyword>
<md:techKeyword type="autoGenerated">param27315</md:techKeyword>
<md:techKeyword type="autoGenerated">param2834</md:techKeyword>
<md:techKeyword type="autoGenerated">param2842</md:techKeyword>
<md:techKeyword type="autoGenerated">param6166</md:techKeyword>
<md:techKeyword type="autoGenerated">param67</md:techKeyword>
<md:techKeyword type="autoGenerated">param70</md:techKeyword>
<md:techKeyword type="autoGenerated">param701</md:techKeyword>
<md:techKeyword type="autoGenerated">param702</md:techKeyword>
<md:techKeyword type="autoGenerated">param703</md:techKeyword>
<md:techKeyword type="autoGenerated">param704</md:techKeyword>
<md:techKeyword type="autoGenerated">param705</md:techKeyword>
<md:techKeyword type="autoGenerated">param707</md:techKeyword>
<md:techKeyword type="autoGenerated">param708</md:techKeyword>
<md:techKeyword type="autoGenerated">param709</md:techKeyword>
<md:techKeyword type="autoGenerated">param790</md:techKeyword>
<md:techKeyword type="autoGenerated">param811</md:techKeyword>
<md:techKeyword type="autoGenerated">pi25771</md:techKeyword>
<md:techKeyword type="autoGenerated">project4</md:techKeyword>
<md:techKeyword type="autoGenerated">ref29002</md:techKeyword>
<md:techKeyword type="autoGenerated">term1073131</md:techKeyword>
<md:techKeyword type="autoGenerated">term1073193</md:techKeyword>
<md:techKeyword type="autoGenerated">term1073224</md:techKeyword>
<md:techKeyword type="autoGenerated">term1073388</md:techKeyword>
<md:techKeyword type="autoGenerated">term1073626</md:techKeyword>
<md:techKeyword type="autoGenerated">term1074034</md:techKeyword>
<md:techKeyword type="autoGenerated">term1074050</md:techKeyword>
<md:techKeyword type="autoGenerated">term1074058</md:techKeyword>
<md:techKeyword type="autoGenerated">term1074190</md:techKeyword>
<md:techKeyword type="autoGenerated">term1074191</md:techKeyword>
<md:techKeyword type="autoGenerated">term1074204</md:techKeyword>
<md:techKeyword type="autoGenerated">term20691</md:techKeyword>
<md:techKeyword type="autoGenerated">term2299468</md:techKeyword>
<md:techKeyword type="autoGenerated">term2299833</md:techKeyword>
<md:techKeyword type="autoGenerated">term2632269</md:techKeyword>
<md:techKeyword type="autoGenerated">term38253</md:techKeyword>
<md:techKeyword type="autoGenerated">term38263</md:techKeyword>
<md:techKeyword type="autoGenerated">term38380</md:techKeyword>
<md:techKeyword type="autoGenerated">term38477</md:techKeyword>
<md:techKeyword type="autoGenerated">term38521</md:techKeyword>
<md:techKeyword type="autoGenerated">term40550</md:techKeyword>
<md:techKeyword type="autoGenerated">term40802</md:techKeyword>
<md:techKeyword type="autoGenerated">term41056</md:techKeyword>
<md:techKeyword type="autoGenerated">term41092</md:techKeyword>
<md:techKeyword type="autoGenerated">term43794</md:techKeyword>
<md:techKeyword type="autoGenerated">term43863</md:techKeyword>
<md:techKeyword type="autoGenerated">term44419</md:techKeyword>
<md:techKeyword type="autoGenerated">term49257</md:techKeyword>
<md:techKeyword type="autoGenerated">term49339</md:techKeyword>
<md:techKeyword type="autoGenerated">term67625</md:techKeyword>
<md:techKeyword type="autoGenerated">topotype3</md:techKeyword>
</md:keywords>
<md:technicalInfo>
<md:entry key="xmlLastModified" value="2026-05-01T04:32:11Z"/>
<md:entry key="lastModified" value="2015-04-12T19:44:42"/>
<md:entry key="filename" value="DSDP465A-chem"/>
<md:entry key="mimeType" value="text/tab-separated-values"/>
<md:entry key="status" value="published"/>
<md:entry key="status_num" value="4"/>
<md:entry key="DOIRegistryStatus" value="registered"/>
<md:entry key="DOIRegistryStatus_num" value="4"/>
<md:entry key="DOIRegistrationDate" value="2008-08-05T01:07:09"/>
<md:entry key="loginOption" value="unrestricted"/>
<md:entry key="loginOption_num" value="1"/>
</md:technicalInfo>
</md:MetaData>