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Hein, James R; Koski, Randolph A; Morgenson, Lisa A (1982): (Table 1) Chemical and lithological composition of rocks from DSDP Hole 465A [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.696416, Supplement to: Hein, JR et al. (1982): Uranium and thorium enrichment in rocks from the base of DSDP Hole 465A, Hess Rise, Central North Pacific. Chemical Geology, 36(3-4), 237-251, https://doi.org/10.1016/0009-2541(82)90050-X

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Published: 1982 (exact date unknown)DOI registered: 2008-08-05

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Abstract:
Uranium and thorium are concentrated in Cretaceous limestone, chert, ash, basalt, and other rock types at Deep Sea Drilling Project Site 465 located on the southern Hess Rise in the central North Pacific. U concentrations, up to 194 ppm on a carbonate-free basis, are among the highest recorded for any deep-sea deposits. U was initially derived from seawater and concentrated by absorption on terrigenous (humic) organic matter in limestone in a shallow marine environment. U and Th were probably concentrated further by low-temperature hydrothermal fluids emanating from the basaltic basement. Mainly montmorillonite, an alteration product of basalt and ash, and organic matter in sedimentary rocks acted as hosts for U and Th.
The unique combination of sediments rich in humic organic matter, abundant smectite in altered ash and basalt, and warm hydrothermal solutions provided the necessary conditions for migration and concentration of U and Th. To better understand the conditions limiting the migrating and concentration of U and Th, other rocks deposited during the ocean-wide Cretaceous anoxic events should be analyzed for these elements.
Project(s):
Coverage:
Latitude: 33.820500 * Longitude: 178.919000
Date/Time Start: 1978-08-23T00:00:00 * Date/Time End: 1978-08-23T00:00:00
Minimum DEPTH, sediment/rock: 392.80 m * Maximum DEPTH, sediment/rock: 419.50 m
Event(s):
62-465A * Latitude: 33.820500 * Longitude: 178.919000 * Date/Time: 1978-08-23T00:00:00 * Elevation: -2161.0 m * Penetration: 476 m * Recovery: 98.9 m * Location: North Pacific/CONT RISE * Campaign: Leg62 * Basis: Glomar Challenger * Method/Device: Drilling/drill rig (DRILL) * Comment: 43 cores; 408.5 m cored; 9.5 m drilled; 24.2 % recovery
Comment:
In the sample 465A-40-1, 145 (calcareous ash / sulfide-rich fraction) contents of major oxides were measured by quantitative emission spectroscopy; in the samples 465A-40-2, 62 (altered ash) and 465A-40-2, 62 (altered ash, <1 µm fraction) contents of major oxides were measured by semi-quantitative emission spectroscopy.
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
DEPTH, sediment/rockDepth sedmGeocode
Sample code/labelSample labelHein, James RDSDP/ODP/IODP sample designation
Rock typeRockHein, James R
Lithology/composition/faciesLithologyHein, James R
MineralsMineralsHein, James Rmajor
MineralsMineralsHein, James Rmoderate
MineralsMineralsHein, James Rminor
MineralsMineralsHein, James Rtrace
Silicon dioxideSiO2%Hein, James RX-ray fluorescence on pressed powder
10 Aluminium oxideAl2O3%Hein, James RX-ray fluorescence on pressed powder
11 Titanium dioxideTiO2%Hein, James RX-ray fluorescence on pressed powder
12 Iron oxide, Fe2O3Fe2O3%Hein, James RX-ray fluorescence on pressed powdertotal Fe as Fe2O3
13 Magnesium oxideMgO%Hein, James RX-ray fluorescence on pressed powder
14 Calcium oxideCaO%Hein, James RX-ray fluorescence on pressed powder
15 Sodium oxideNa2O%Hein, James RX-ray fluorescence on pressed powder
16 Potassium oxideK2O%Hein, James RX-ray fluorescence on pressed powder
17 Phosphorus pentoxideP2O5%Hein, James RX-ray fluorescence on pressed powder
18 Barium oxideBaO%Hein, James RX-ray fluorescence on pressed powder
19 Sulfite[SO3]2-%Hein, James R3 by difference on barite-rich samples
20 ManganeseMnmg/kgHein, James RX-ray fluorescence on pressed powder
21 Loss on ignitionLOI%Hein, James Rat 1050°C
22 SumSum%Hein, James RCalculated
23 Carbon, organic, totalTOC%Hein, James RElement analyser CHN, LECO WR-12
24 Calcium carbonateCaCO3%Hein, James RElement analyser CHN, LECO WR-12
25 UraniumUmg/kgHein, James RElement analysis, neutron activation (NAA)
26 ThoriumThmg/kgHein, James RElement analysis, neutron activation (NAA)differences in detection limits are due to dilutions required to complete the analysis
Size:
278 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Depth sed [m]

Sample label
(DSDP/ODP/IODP sample designation)

Rock

Lithology

Minerals
(major)

Minerals
(moderate)

Minerals
(minor)

Minerals
(trace)

SiO2 [%]
(X-ray fluorescence on pressed...)
10 
Al2O3 [%]
(X-ray fluorescence on pressed...)
11 
TiO2 [%]
(X-ray fluorescence on pressed...)
12 
Fe2O3 [%]
(total Fe as Fe2O3, X-ray fluo...)
13 
MgO [%]
(X-ray fluorescence on pressed...)
14 
CaO [%]
(X-ray fluorescence on pressed...)
15 
Na2O [%]
(X-ray fluorescence on pressed...)
16 
K2O [%]
(X-ray fluorescence on pressed...)
17 
P2O5 [%]
(X-ray fluorescence on pressed...)
18 
BaO [%]
(X-ray fluorescence on pressed...)
19 
[SO3]2- [%]
(3 by difference on barite-ric...)
20 
Mn [mg/kg]
(X-ray fluorescence on pressed...)
21 
LOI [%]
(at 1050°C)
22 
Sum [%]
(Calculated)
23 
TOC [%]
(Element analyser CHN, LECO WR-12)
24 
CaCO3 [%]
(Element analyser CHN, LECO WR-12)
25 
U [mg/kg]
(Element analysis, neutron act...)
26 
Th [mg/kg]
(differences in detection limi...)
392.80465A-38-2, 80chertblack chertquartzpyroxene, smectite90.104.36<0.020.070.130.45<0.150.050.06<2003.1598.370.962.06.21<5.0
392.85465A-38-2, 85limestonegray limestonecalcitequartz3.011.09<0.020.160.7449.200.460.220.19<20042.4097.472.9488.720.80<8.8
400.91465A-39-1, 91limestonegray limestonecalciteplumbo-jarosite?, quartz2.3393.512.60<7.1
410.00465A-40-1, 50limestonegray-green limestonecalcitedolomitequartz, plumbo-jarosite?4.441.51<0.020.151.0348.300.500.240.3690039.9096.432.4189.020.80<7.5
410.95465A-40-1, 145ashdolomiteplagioclasehigh-Mg calcite pyrite, barite, quartzsmectite1.7832.79.8315.6
410.95465A-40-1, 145ashcalcareous ash / barite-rich fraction16.535.220.271.955.719.761.420.970.1029.813.9140014.3199.95
410.95465A-40-1, 145ashcalcareous ash / sulfide-rich fraction<21.403.020.10>28.593.987.000.961.18<0.05340
410.95465A-40-1, 145ashcalcareous ash / dolomite-rich fraction
411.10465A-40-2, 10pyritedark-gray pyrite layerpyritequartz, plagioclasedolomite, calcite, barite21.905.750.1041.060.692.711.792.02<0.053.2124020.97100.200.167.63.738.1
411.29465A-40-2, 29dolomitegray-green clastic dolomitebaritecalciteK-feldspar, quartz, pyrite7.892.770.091.734.9714.200.660.24<0.0533.715.15100018.4599.850.9329.20.785.9
411.62465A-40-2, 62ashaltered ashmicroclinesmectite, quartz, plagioclasepyrite, pyroxene, barite, opal-CTapatite, illite59.9014.550.332.572.980.483.773.610.123700.010.47.6535.6
411.62465A-40-2, 62ashaltered ash, <1 µm fractionmontmorillonite59.9015.120.321.724.970.133.640.600.09<2004.7929.9
411.64465A-40-2, 64ashgray laminated ashplagioclase, smectitequartz, pyroxene6.8430.1
411.94465A-40-2, 94ashyellow-to-gray altered ashplagioclasejarosite, pyrite, smectitequartzillite?42.2413.780.768.391.981.222.702.830.158.02.90<20015.09100.040.000.65.2314.3
412.36465A-40-2, 136volcanic brecciagray m-b basalt brecciaplagioclasecalcite, smectite, pyroxenepyriteapatite?54.5017.600.984.073.252.293.522.860.18<20010.0099.250.001.64.5413.3
419.50465A-41-1, 50volcanic brecciagray m- b basalt brecciaplagioclasepyroxenesmectite, pyrite, quartzapatite?56.7018.300.973.532.432.064.613.010.27<2007.2999.17<0.010.74.0710.9