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Walter, Hans-Jürgen; Rutgers van der Loeff, Michiel M; Francois, Roger (1999): Compilation of 231Protactinium/230 Thorium excess ratios in various surface sediment samples from the South Atlantic [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.55674, Supplement to: Walter, H-J et al. (1999): Reliability of the 231Pa/230Th Activity Ratio as a Tracer for Bioproductivity of the Ocean. In: Fischer, G & Wefer, G (eds.), Use of Proxies in Paleoceanography - Examples from the South Atlantic, Springer, Berlin, Heidelberg, 393-408

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Abstract:
In large areas of the world's oceans, there is a relationship between the mass flux of particulate matter and the unsupported 231Pa/230Th (xs231Pa/xs230Th) activity ratio of recent sediments. This observation forms the basis for using the xs231Pa/xs230Th ratio as a proxy for past changes in export productivity. However, a simple relationship between xs231Pa/xs 230Th ratio and particle flux requires that the water residence time in an ocean basin is far in excess of the scavenging residence time of 231Pa, and that the composition of sinking particles maintains a strong preference for the adsorption of 230Th over 231Pa with a constant 230Th/231Pa fractionation factor (F). The best correlation between xs231Pa/xs230Th ratio and mass flux is found in the Pacific Ocean. In the Atlantic, the contrast in the xs231Pa/xs230Th ratios between open ocean (low flux regions) and ocean margins (high flux regions) is much less pronounced due to the shorter residence time of deep water, resulting in less effective boundary scavenging of 231Pa. In the Southern Ocean, south of the Polar Front, there is no more a simple relationship between xs231Pa/xs230Th and particle flux. This is a result of a southward decrease in F, probably reflecting the increased opal content of sinking particles. Opal does not fractionate 231Pa and 230Th significantly. This lack of fractionation results in high xs231Pa/xs230Th ratios in opal-dominated regions, even in areas of very low particle fluxes such as the Weddell Sea. The xs231Pa/xs230Th ratio can therefore only be used as a paleoproductivity proxy if, in the time interval of interest, changes in the basin ventilation rate and differential scavenging of both radionuclides due to changes in the chemical composition of particulate matter can be excluded.
Coverage:
Median Latitude: -7.143739 * Median Longitude: -121.539218 * South-bound Latitude: -76.413300 * West-bound Longitude: 0.000000 * North-bound Latitude: 77.460000 * East-bound Longitude: -3.206670
Minimum Elevation: 0.0 m * Maximum Elevation: 0.0 m
Event(s):
SURWalter1999 * Elevation Start: 0.0 m * Elevation End: 0.0 m * Campaign: compiled data * Method/Device: Multiple investigations (MULT) * Comment: This is a virtual site to link a compiled data set from ocean bottom sediments
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Sample code/labelSample labeldata compiled from different sources
LATITUDELatitudeGeocode
LONGITUDELongitudeGeocode
Depth, top/minDepth topmdata compiled from different sources
Depth, bottom/maxDepth botmdata compiled from different sources
Protactinium-231/Thorium-230 excess231Pa/230Th xssee reference(s)data compiled from different sources
Protactinium-231/Thorium-230 excess, standard deviation231Pa/230Th xs std dev±see reference(s)data compiled from different sources
Reference/sourceReferenceWalter, Hans-Jürgen
Size:
1917 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Sample label

Latitude

Longitude

Depth top [m]

Depth bot [m]

231Pa/230Th xs

231Pa/230Th xs std dev [±]

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ktb 1118.5000-21.08330.0000.0100.0700.009Legeleux (1994)
KH-79-4-2220.0450158.60000.0000.0200.0400.003Yang et al. (1986)
ktb 0920.5333-18.60000.0000.0100.1600.037Legeleux (1994)
V21-5920.9167-158.10000.0500.0600.0810.004Lao et al. (1992)
ktb 1021.0500-31.20000.0000.0100.0330.004Legeleux (1994)
ktb 1221.0667-31.15000.0000.0100.0320.004Legeleux (1994)
AII 42-4122.2333-56.65000.0000.0500.0390.004Ku et al. (1972)
VM 23-10022.6833-21.30000.1000.1000.0350.001Yu (1994)
core 1231023.5000-18.71670.0200.0400.1020.013Mangini and Dieter-Haass (1983)
KH-79-4-623.7917147.62300.0000.0150.0220.005Yang et al. (1986)
163-924.2500-115.00000.0000.0100.0970.008Shimmield et al. (1986)
163-1024.6000-114.05000.0000.0200.1310.005Shimmield et al. (1986)
145-724.7000-114.10000.0000.0100.0880.004Shimmield et al. (1986)
163-1424.7000-113.70000.0000.0100.141Shimmield et al. (1986)
145-824.9500-113.50000.0000.0100.1200.005Shimmield et al. (1986)
163-724.9500-113.50000.0000.0200.1450.010Shimmield et al. (1986)
v 10-9526.5167-51.78330.0000.0600.0230.003Ku (1966)
KH-74-4-2126.7617139.70800.0200.0800.1050.015Yang et al. (1986)
V21-7127.9000162.51700.0000.0200.0360.002Ku (1966)
KH-79-4-529.2800144.03300.0000.0150.0580.008Yang et al. (1986)
KH-80-2-930.0000-170.01300.0000.0200.0450.003Yang et al. (1986)
KH-75-3-2-230.0000143.51300.0000.0250.0910.007Yang et al. (1986)
KH-80-3-1631.7250157.44500.0000.0150.1950.032Yang et al. (1986)
SCB QP232.5833-118.16700.0000.1000.1980.011Lao et al. (1992)
M36/2_192-MUC32.9967-21.99170.0000.0000.0420.009Scholten, unpublished
BC3133.7500-118.80000.0000.0100.500Huh etal. (1987)
KH-75-3-14-234.3967145.03000.0000.0300.0760.007Yang et al. (1986)
KH-83-3-D34.8667154.77000.0000.0100.0900.008Yang et al. (1986)
V32-12635.3167174.90000.0700.0800.0640.003Lao et al. (1992)
PS BC15135.6333-121.61700.0000.0100.1570.015Lao et al. (1992)
VM 26-17636.0000-72.00000.0800.1000.0660.004Yu (1994)
PS BC16636.1000-122.60000.0000.0100.1630.019Lao et al. (1992)
PS BC15036.1833-122.36700.0000.0100.1900.047Lao et al. (1992)
PS BC13336.2000-122.26700.0000.0100.9660.058Lao et al. (1992)
V32-12836.4500177.15000.0800.1000.0620.005Lao et al. (1992)
EN 187 BC836.8667-74.57330.0100.0200.0530.015Anderson et al. (1994)
EN 187 BC936.8700-74.56330.0600.0800.0750.014Anderson et al. (1994)
EN 187 BC1036.8750-74.61330.0100.0200.0890.029Anderson et al. (1994)
EN 187 BC1137.0383-74.57170.0200.0300.0620.023Anderson et al. (1994)
en 187-bc637.4000-73.82830.0000.0100.0550.007Anderson et al. (1991)
en 179-bc737.4183-73.82330.0000.0100.0510.006Anderson et al. (1991)
en 179-bc437.5283-74.03830.0100.0200.0710.011Anderson et al. (1991)
EN 187 BC537.6183-74.16670.0400.0500.0690.014Anderson et al. (1994)
EN 187 BC437.6217-74.22170.0300.0400.0630.023Anderson et al. (1994)
EN 179 BC237.6250-74.16670.0400.0500.0500.011Anderson et al. (1994)
EN 179 BC337.6400-74.14330.0200.0300.0750.016Anderson et al. (1994)
V21-14637.6833163.03300.1000.1100.0930.005Lao et al. (1992)
MANOP R38.0000-158.00000.0000.0500.0430.002Lao et al. (1992)
KH-80-2-838.0550-179.76200.0000.0100.0730.005Yang et al. (1986)
KH-84-3-1638.2867135.49200.0000.0150.4130.055Yang et al. (1986)
KH-80-2-639.0417166.00500.0200.0300.1130.011Yang et al. (1986)
oce 152 bc539.1333-70.93330.0000.0050.0630.003Anderson et al. (1991)
EN 123 BC139.1367-70.92500.0100.0150.0530.003Anderson et al. (1994)
EN 123 BC339.5817-70.92000.0000.0100.0610.005Anderson et al. (1994)
RC14-10539.6833157.55000.1000.1200.0900.005Lao et al. (1992)
OCE 152-BC939.6983-70.91330.0000.0050.0910.007Anderson et al. (1994)
oce 152 bc839.7750-70.96500.0000.0050.0710.007Anderson et al. (1991)
EN 123 BC439.8033-70.92830.0100.0150.0760.008Anderson et al. (1994)
OCE 152-BC139.8117-70.94330.0000.0200.0820.008Anderson et al. (1994)
EN 123 BC639.8133-70.92330.0000.0100.0660.006Anderson et al. (1994)
KH-84-3-539.9583145.43800.0000.0150.1440.021Yang et al. (1986)
KH-80-2-540.0033156.00000.0000.0100.1280.014Yang et al. (1986)
V20-8840.1833-151.65000.0000.0000.0440.002Lao et al. (1992)
VM 30-09741.0000-33.93330.0500.1600.2720.010Yu (1994)
W8709A-141.5500-131.95000.0100.0300.0810.003Lao et al. (1992)
chn 82-2341.6333-27.33330.0000.0500.0570.003Ku et al. (1972)
chn 82-2441.7167-32.85000.0000.0500.0470.002Ku et al. (1972)
CHN 82-00441.7167-32.85000.0200.0400.0650.005Yu (1994)
chn 82-3041.8500-26.46670.0000.1000.0650.004Ku et al. (1972)
chn 82-2842.0000-29.90000.0000.1000.0550.004Ku et al. (1972)
W8709A-1342.1167-125.75000.0400.0500.2170.036Lao et al. (1992)
chn 82-2642.1667-31.63330.0000.1000.0570.003Ku et al. (1972)
W8709A-842.2667-127.68300.0900.1000.1800.011Lao et al. (1992)
chn 82-2542.3167-28.58330.0000.0600.0410.003Ku et al. (1972)
chn 82-3142.3833-31.80000.0000.1000.0500.003Ku et al. (1972)
CHN 82-01142.3833-31.80000.0350.0500.0530.004Yu (1994)
chn 82-3342.4833-28.66670.0000.1000.0700.007Ku et al. (1972)
KH-83-3-BC43.3000154.70700.0000.0100.2900.034Yang et al. (1986)
chn 82-4243.3333-28.08330.0000.1000.0610.004Ku et al. (1972)
chn 82-4143.3667-28.23330.0000.1000.0930.005Ku et al. (1972)
CHN 82-01543.3667-28.23330.0300.0400.0690.006Yu (1994)
CHN 82-02043.5000-29.86670.0400.0600.0520.003Yu (1994)
chn 82-3243.7500-27.78330.0000.1000.0580.004Ku et al. (1972)
VM 29-17944.0000-24.53330.1600.1600.0440.002Yu (1994)
V20-8544.9000-143.61700.0000.0100.0440.002Lao et al. (1992)
KH-83-3-C45.0250159.99500.0000.0100.1610.012Yang et al. (1986)
V20-12246.5667161.68300.0800.1000.1450.007Lao et al. (1992)
KH-78-3-453.5000177.25800.0000.0250.2190.027Yang et al. (1986)
M36/2_MC43554.6117-21.15000.0000.0000.0730.013Scholten, unpublished
RC14-12154.8500-170.68300.2500.2700.1540.016Lao et al. (1992)
VM 28-01464.7833-29.56670.1300.1300.1080.004Yu (1994)
VM 27-08666.60001.11670.0900.0900.0870.005Yu (1994)
HM-79-2666.9000-5.93330.0000.0000.0710.004Yu (1994)
HM-71-1969.4833-9.51670.0000.0000.0770.006Yu (1994)
GIK17730-272.11177.38830.0000.0100.1450.010Scholten et al. (1995)
2329372.6217-6.59170.0000.0100.0790.011Scholten et al. (1995)
HM-94-18/373.50005.68330.0000.0000.0450.003Yu (1994)
2189374.8683-10.11000.0000.0100.1010.009Scholten et al. (1995)
1772975.00000.00000.0000.0100.0780.006Scholten et al. (1995)
2189575.4133-7.31000.0000.0100.0760.008Scholten et al. (1995)
GIK17726-175.49833.56170.0000.0100.0720.006Scholten et al. (1995)
GIK17728-176.52003.62500.0000.0100.1050.009Scholten et al. (1995)
GIK17725-177.46004.58000.0000.0100.0770.005Scholten et al. (1995)