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Experimental calibration and implications of olivine-melt vanadium oxybarometry for hydrous basaltic arc magmas

  • Tatiana A. Shishkina EMAIL logo , Maxim V. Portnyagin , Roman E. Botcharnikov , Renat R. Almeev , Anna V. Simonyan , Dieter Garbe-Schönberg , Stephan Schuth , Martin Oeser and Francois Holtz
From the journal American Mineralogist

Abstract

The strong dependence of vanadium partitioning between olivine and silicate melt (DVO1-M) on redox conditions (fO2) can be used as sensitive oxybarometer in magmatic systems. Here we extend the experimental database on DVO1-M, obtained so far at high temperatures (mainly above 1250 °C), to lower temperatures that are typical for island-arc basalts. Crystallization experiments were performed using a composition from Mutnovsky volcano (Kamchatka), and the investigated temperature, pressure, and oxygen fugacity ranges were 1025–1150 °C, 0.1 and 0.3 GPa, and ΔQFM of –0.5 to +3.2, respectively. The water content in melts ranged from 0.6 to ~6.5 wt% H2O. The data demonstrate a strong negative correlation between DVO1-M and oxygen fugacity, similar to the behavior observed previously at higher temperatures and in MgO-rich compositions. The correlation between DVO1-M and ΔQFM in the range from –0.5 to +3.2 is described for melts with MgO < 12 wt% and Na2O < 4 wt% at temperatures ≤1250 °C by the empirical equation: ΔQFM = 3.070.29+0.26logDVO1-M3.340.49+0.40 with the standard error (SE) as a function of log DVO1-M: 2SE(ΔQFM) = –0.275log DVO1-M + 0.4.

We suggest that this equation can be used as an oxybarometer, which is particularly well applicable to the hydrous island-arc magmas at relatively low temperature. Application of the equation to the composition of melt inclusions and their host olivine phenocrysts from basalts of Mutnovsky volcano, containing vanadium concentrations in the range of 250–370 and 4–6 ppm, respectively, reveals an oxygen fugacity in the range ΔQFM +1.9 to +2.3. The estimates are in a good agreement with olivine-spinel oxybarometry for Mutnovsky basalts and may be typical for moderately evolved island-arc magmas.

Acknowledgments

This research has been supported by the Russian Foundation for Basic Research (project no. 16-35-60123), the Russian Science Foundation (grant 14-17-000582) and the German Science Foundation (DFG projects Ho1337/21, Ho1337/19, and Bo2941/3-1). We thank C. Godeck for the help with performing the experiments, U. Westernströer for help with the LA-ICP-MS at CAU Kiel, I. Horn for help with the LA-ICP-MS at LU Hannover. Also we thank M. Brounce and an anonymous reviewer whose critical comments helped to improve the original manuscript. The editorial work of S. Straub is greatly appreciated.

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Received: 2017-6-11
Accepted: 2017-12-1
Published Online: 2018-2-28
Published in Print: 2018-3-26

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