/* DATA DESCRIPTION: Citation: März, Christian; Poulton, Simon W; Beckmann, Britta; Küster, Kathrin; Wagner, Thomas; Kasten, Sabine (2008): Geochemical analysis at ODP Site 207-1261 from the Demerara Rise in the western equatorial Atlantic. PANGAEA, https://doi.org/10.1594/PANGAEA.732910, Supplement to: März, C et al. (2008): Redox sensitivity of P cycling during black shale formation: Dynamics of sulfidic and anoxic, non-sulfidic bottom waters. Geochimica et Cosmochimica Acta, 72(15), 3703-3717, https://doi.org/10.1016/j.gca.2008.04.025 Abstract: A high-resolution geochemical record of a 120 cm black shale interval deposited during the Coniacian–Santonian Oceanic Anoxic Event 3 (ODP Leg 207, Site 1261, Demerara Rise) has been constructed to provide detailed insight into rapid changes in deep ocean and sediment paleo-redox conditions. High contents of organic matter, sulfur and redox-sensitive trace metals (Cd, Mo, V, Zn), as well as continuous lamination, point to deposition under consistently oxygen-free and largely sulfidic bottom water conditions. However, rapid and cyclic changes in deep ocean redox are documented by short-term (~15–20 ka) intervals with decreased total organic carbon (TOC), S and redox-sensitive trace metal contents, and in particular pronounced phosphorus peaks (up to 2.5 wt% P) associated with elevated Fe oxide contents. Sequential iron and phosphate extractions confirm that P is dominantly bound to iron oxides and incorporated into authigenic apatite. Preservation of this Fe–P coupling in an otherwise sulfidic depositional environment (as indicated by Fe speciation and high amounts of sulfurized organic matter) may be unexpected, and provides evidence for temporarily non-sulfidic bottom waters. However, there is no evidence for deposition under oxic conditions. Instead, sulfidic conditions were punctuated by periods of anoxic, non-sulfidic bottom waters. During these periods, phosphate was effectively scavenged during precipitation of iron (oxyhydr)oxides in the upper water column, and was subsequently deposited and largely preserved at the sea floor. After ~15–25 ka, sulfidic bottom water conditions were re-established, leading to the initial precipitation of CdS, ZnS and pyrite. Subsequently, increasing concentrations of H2S in the water column led to extensive formation of sulfurized organic matter, which effectively scavenged particle-reactive Mo complexes (thiomolybdates). At Site 1261, sulfidic bottom waters lasted for ?90–100 ka, followed by another period of anoxic, non-sulfidic conditions lasting for ~15–20 ka. The observed cyclicity at the lower end of the redox scale may have been triggered by repeated incursions of more oxygenated surface- to mid-waters from the South Atlantic resulting in a lowering of the oxic–anoxic chemocline in the water column. Alternatively, sea water sulfate might have been stripped by long-lasting high rates of sulfate reduction, removing the ultimate source for HS**- production. Related to: März, Christian; Beckmann, Britta; Franke, Christine; Vogt, Christoph; Wagner, Thomas; Kasten, Sabine (2009): Geochemical environment of the Coniacian-Santonian western tropical Atlantic at Demerara Rise. Palaeogeography, Palaeoclimatology, Palaeoecology, 273(3-4), 286-301, https://doi.org/10.1016/j.palaeo.2008.05.004 Project(s): Ocean Drilling Program (ODP) (URI: http://www-odp.tamu.edu/) Coverage: LATITUDE: 9.048617 * LONGITUDE: -54.317400 DATE/TIME START: 2003-02-16T00:00:00 * DATE/TIME END: 2003-02-23T00:00:00 MINIMUM DEPTH, sediment/rock: 570.210 m * MAXIMUM DEPTH, sediment/rock: 571.360 m Event(s): 207-1261 * LATITUDE: 9.048617 * LONGITUDE: -54.317400 * DATE/TIME START: 2003-02-16T00:00:00 * DATE/TIME END: 2003-02-23T00:00:00 * ELEVATION: -1899.7 m * Penetration: 1343.6 m * Recovery: 447.9 m * LOCATION: South Atlantic Ocean * CAMPAIGN: Leg207 (URI: https://doi.org/10.2973/odp.proc.ir.207.2004) * BASIS: Joides Resolution (URI: http://www-odp.tamu.edu/resolutn.html) * METHOD/DEVICE: Composite Core (COMPCORE) * COMMENT: 67 cores; 632.8 m cored; 710.8 m drilled; 70.8 % recovery Parameter(s): DEPTH, sediment/rock [m] (Depth sed) * GEOCODE Depth, reference [m] (Depth ref) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * COMMENT: Section depth Depth, reference [m] (Depth ref) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * COMMENT: Section depth, corrected Aluminium [%] (Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Boron [mg/kg] (B) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Barium [mg/kg] (Ba) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Calcium [%] (Ca) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Copper [%] (Cu) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Iron [%] (Fe) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Potassium [%] (K) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Magnesium [%] (Mg) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Manganese [%] (Mn) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Sodium [%] (Na) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Phosphorus [%] (P) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Sulfur, total [%] (TS) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Strontium [%] (Sr) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Titanium [%] (Ti) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Vanadium [mg/kg] (V) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Zinc [%] (Zn) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Zirconium [mg/kg] (Zr) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry Barium/Aluminium ratio (Ba/Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Copper/Aluminium ratio (Cu/Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Iron/Aluminium ratio (Fe/Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Potassium/Aluminium ratio (K/Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Magnesium/Aluminium ratio (Mg/Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Manganese/Aluminium ratio (Mn/Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Titanium/Aluminium ratio (Ti/Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Vanadium/Aluminium ratio (V/Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Zinc/Aluminium ratio (Zn/Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Zirconium/Aluminium ratio (Zr/Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Strontium/Calcium ratio (Sr/Ca) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Iron/Sulfur ratio (Fe/S) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Phosphorus/Aluminium ratio (P/Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Carbon, organic, total [%] (TOC) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Element analyser CS, LECO CS-200 Calcium carbonate [%] (CaCO3) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Element analyser CS, LECO CS-200 Sulfur, total [%] (TS) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: ICP-OES, Inductively coupled plasma - optical emission spectrometry * COMMENT: total Carbon, organic total/Aluminium ratio (TOC/Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated Sulfur/Aluminium ratio (S/Al) * PI: März, Christian (C.Maerz@leeds.ac.uk, http://sites.google.com/site/thediljemer/) * METHOD/DEVICE: Calculated License: Creative Commons Attribution 3.0 Unported (CC-BY-3.0) (URI: https://creativecommons.org/licenses/by/3.0/) Size: 4292 data points */ Depth sed [m] Depth ref [m] (Section depth) Depth ref [m] (Section depth, corrected) Al [%] (ICP-OES, Inductively coupled ...) B [mg/kg] (ICP-OES, Inductively coupled ...) Ba [mg/kg] (ICP-OES, Inductively coupled ...) Ca [%] (ICP-OES, Inductively coupled ...) Cu [%] (ICP-OES, Inductively coupled ...) Fe [%] (ICP-OES, Inductively coupled ...) K [%] (ICP-OES, Inductively coupled ...) Mg [%] (ICP-OES, Inductively coupled ...) Mn [%] (ICP-OES, Inductively coupled ...) Na [%] (ICP-OES, Inductively coupled ...) P [%] (ICP-OES, Inductively coupled ...) TS [%] (ICP-OES, Inductively coupled ...) Sr [%] (ICP-OES, Inductively coupled ...) Ti [%] (ICP-OES, Inductively coupled ...) V [mg/kg] (ICP-OES, Inductively coupled ...) Zn [%] (ICP-OES, Inductively coupled ...) Zr [mg/kg] (ICP-OES, Inductively coupled ...) Ba/Al (Calculated) Cu/Al (Calculated) Fe/Al (Calculated) K/Al (Calculated) Mg/Al (Calculated) Mn/Al (Calculated) Ti/Al (Calculated) V/Al (Calculated) Zn/Al (Calculated) Zr/Al (Calculated) Sr/Ca (Calculated) Fe/S (Calculated) P/Al (Calculated) TOC [%] (Element analyser CS, LECO CS-200) CaCO3 [%] (Element analyser CS, LECO CS-200) TS [%] (total, ICP-OES, Inductively c...) TOC/Al (Calculated) S/Al (Calculated) 570.210 1.008 1.008 2.133 44.781 652.673 24.829 0.007 0.952 0.638 0.411 0.006 0.969 0.314 1.801 0.108 0.094 1575.033 0.153 24.016 3060580.351 329816.576 0.447 0.299 0.193 259018.230 4404691.859 7385809.625 7154583.918 112615.992 435061.819 0.529 0.147 7.690 61.226 1.902 3.606 0.844 570.220 1.018 1.018 2.013 43.211 635.916 24.673 0.006 0.905 0.611 0.405 0.005 1.137 0.924 1.714 0.108 0.088 1434.994 0.146 23.917 3158686.250 316710.192 0.449 0.304 0.201 261688.602 4388261.702 7127825.375 7230316.025 118801.314 436971.646 0.528 0.459 7.537 55.836 1.398 3.744 0.851 570.230 1.025 1.025 2.323 49.591 699.442 23.867 0.007 1.095 0.676 0.449 0.006 1.101 0.803 1.787 0.107 0.104 1591.392 0.174 26.938 3011496.274 299176.225 0.472 0.291 0.193 251955.110 4458517.552 6851849.428 7490928.251 115984.535 446944.848 0.613 0.346 7.275 53.937 1.546 3.132 0.769 570.240 1.045 1.045 2.389 50.175 692.173 22.895 0.007 1.131 0.695 0.456 0.006 1.168 0.200 1.933 0.103 0.107 1666.600 0.225 27.239 2896777.809 311723.838 0.473 0.291 0.191 245320.678 4480376.128 6974799.520 9410018.686 113996.456 450762.687 0.585 0.084 7.559 55.653 1.570 3.163 0.809 570.250 1.058 1.058 2.270 47.530 653.750 24.602 0.006 1.030 0.657 0.451 0.006 1.133 0.113 1.781 0.104 0.100 1522.837 0.196 24.655 2879979.246 281973.508 0.454 0.289 0.199 268512.950 4385150.717 6708590.869 8625543.942 108614.701 423190.840 0.578 0.050 6.513 60.951 1.752 2.869 0.784 570.260 1.075 1.075 2.617 55.853 734.137 22.226 0.007 1.165 0.719 0.488 0.006 1.164 2.077 1.831 0.108 0.115 936.979 0.080 34.074 2805126.990 273764.912 0.445 0.275 0.187 224022.000 4384050.834 3580181.424 3066095.549 130195.268 485653.663 0.637 0.794 8.000 41.567 1.541 3.057 0.699 570.270 1.085 1.085 3.732 78.150 903.698 15.264 0.008 1.736 0.982 0.670 0.007 1.384 2.367 2.395 0.101 0.174 917.128 0.063 50.367 2421281.664 219856.352 0.465 0.263 0.180 189926.243 4648916.791 2457265.005 1690738.739 134948.665 660697.062 0.725 0.634 10.030 22.741 2.008 2.687 0.642 570.280 1.095 1.095 3.031 63.358 779.888 19.449 0.006 1.400 0.808 0.553 0.007 1.198 2.052 2.009 0.104 0.138 725.174 0.043 39.955 2573293.978 205175.912 0.462 0.267 0.183 217668.274 4547115.831 2392760.954 1413767.807 131834.216 533977.508 0.697 0.677 8.134 36.036 1.829 2.684 0.663 570.290 1.108 1.108 2.719 56.780 697.412 20.105 0.005 1.248 0.731 0.512 0.006 1.183 1.647 1.883 0.099 0.123 695.135 0.040 35.056 2564921.151 198883.110 0.459 0.269 0.188 229434.658 4517986.779 2556547.623 1485871.953 128927.700 490049.600 0.663 0.606 7.556 45.848 1.992 2.779 0.693 570.300 1.118 1.118 1.959 41.297 584.315 25.139 0.004 0.996 0.558 0.399 0.006 0.990 0.760 1.892 0.095 0.087 632.181 0.030 24.135 2983318.212 203744.920 0.509 0.285 0.204 325939.245 4428492.607 3227704.581 1519062.035 123226.517 377376.732 0.527 0.388 7.648 59.160 1.627 3.905 0.966 570.310 1.125 1.125 1.498 34.650 469.809 27.306 0.003 0.865 0.451 0.333 0.006 0.873 0.140 1.937 0.090 0.064 574.298 0.029 16.439 3135712.181 191094.890 0.577 0.301 0.222 424348.188 4247174.417 3833119.464 1946656.128 109719.817 329353.709 0.447 0.094 7.680 71.638 1.698 5.126 1.293 570.320 1.135 1.135 1.652 36.634 499.743 26.335 0.003 0.908 0.487 0.358 0.006 0.912 0.226 1.863 0.090 0.071 671.469 0.039 18.036 3024603.497 181590.584 0.550 0.295 0.217 376920.097 4283547.790 4063947.280 2337509.091 109161.968 341598.785 0.488 0.136 7.540 66.140 1.687 4.563 1.127 570.330 1.145 1.145 1.830 43.519 567.953 24.979 0.003 1.040 0.546 0.369 0.006 1.008 0.138 2.170 0.093 0.079 722.682 0.030 21.235 3103590.414 162065.694 0.568 0.298 0.202 333470.103 4289658.231 3949110.030 1662007.794 116037.232 373766.676 0.479 0.075 8.641 61.134 2.020 4.722 1.186 570.340 1.158 1.158 2.072 47.377 662.799 23.901 0.003 1.056 0.623 0.397 0.006 1.139 0.076 2.343 0.098 0.089 796.005 0.046 23.363 3198614.745 154095.540 0.510 0.301 0.192 310584.369 4300061.739 3841456.263 2221914.702 112746.413 410675.472 0.451 0.037 8.927 60.667 2.311 4.308 1.131 570.350 1.168 1.168 1.959 43.330 588.036 24.176 0.003 0.987 0.583 0.379 0.006 1.073 0.100 2.255 0.095 0.084 757.708 0.036 21.003 3002442.978 148583.191 0.504 0.298 0.193 324584.577 4311744.781 3868771.863 1844455.671 107238.481 394060.982 0.438 0.051 8.647 61.001 1.972 4.415 1.151 570.360 1.175 1.175 2.075 47.926 657.689 23.389 0.004 1.014 0.614 0.394 0.006 1.125 0.080 2.279 0.098 0.089 810.783 0.039 22.322 3169911.910 181330.054 0.489 0.296 0.190 292776.828 4275106.238 3907790.515 1858651.178 107586.338 420107.808 0.445 0.038 9.688 57.827 2.089 4.669 1.098 570.370 1.205 1.205 2.181 64.242 692.961 21.804 0.004 1.058 0.651 0.398 0.006 1.147 0.079 2.136 0.090 0.091 879.142 0.039 26.648 3176580.673 176904.462 0.485 0.298 0.183 271925.484 4148764.274 4030043.676 1771848.772 122157.890 413807.834 0.495 0.036 9.008 57.327 2.345 4.129 0.979 570.380 1.215 1.215 2.157 59.111 685.485 23.543 0.004 1.031 0.650 0.396 0.006 1.143 0.093 2.020 0.092 0.089 913.540 0.045 27.324 3178152.130 183896.297 0.478 0.301 0.184 284470.543 4146235.315 4235496.408 2074720.092 126681.545 392574.716 0.510 0.043 8.599 57.569 1.772 3.987 0.937 570.390 1.225 1.225 2.017 58.443 647.574 24.599 0.004 0.960 0.617 0.374 0.006 1.018 0.058 1.885 0.091 0.083 864.956 0.046 25.482 3210872.100 187998.290 0.476 0.306 0.185 302793.184 4126340.449 4288721.907 2290868.872 126346.659 370795.870 0.509 0.029 8.264 59.609 1.823 4.098 0.935 570.400 1.235 1.235 1.972 57.864 621.542 24.851 0.004 0.947 0.590 0.379 0.006 1.080 0.066 1.881 0.091 0.083 886.537 0.048 24.901 3151511.110 194491.116 0.480 0.299 0.192 310516.625 4191922.876 4495161.328 2432383.565 126258.342 365117.765 0.503 0.033 7.872 61.625 1.715 3.991 0.954 570.410 1.245 1.245 2.204 64.889 715.623 23.439 0.004 1.070 0.650 0.407 0.006 1.137 0.074 2.046 0.092 0.092 968.126 0.054 27.991 3246845.738 189403.546 0.485 0.295 0.185 284351.856 4168924.321 4392476.486 2444392.535 126996.313 392637.712 0.523 0.034 8.301 57.635 1.891 3.766 0.928 570.420 1.255 1.255 1.971 59.833 628.575 24.340 0.004 0.952 0.591 0.393 0.006 1.197 0.055 1.819 0.087 0.082 911.454 0.052 25.529 3189021.535 191765.053 0.483 0.300 0.199 323637.226 4184669.752 4624185.914 2636050.784 129521.360 358439.631 0.523 0.028 6.777 65.915 1.883 3.438 0.923 570.430 1.265 1.265 2.082 61.596 628.858 22.984 0.004 0.976 0.610 0.406 0.006 1.051 0.059 1.812 0.087 0.089 1041.157 0.058 27.190 3020434.755 212769.159 0.469 0.293 0.195 293749.132 4255326.179 5000724.381 2783674.613 130594.439 377152.866 0.539 0.028 7.501 57.802 1.800 3.603 0.870 570.440 1.275 1.275 2.104 62.434 676.413 23.227 0.004 1.000 0.626 0.384 0.006 1.096 0.067 1.984 0.094 0.089 1105.356 0.062 25.968 3215313.230 207147.218 0.475 0.297 0.182 271706.659 4245193.903 5254283.726 2954260.975 123439.459 403661.848 0.504 0.032 8.724 58.027 1.914 4.147 0.943 570.450 1.285 1.285 2.098 60.021 653.411 24.106 0.004 0.955 0.622 0.390 0.006 1.155 0.062 1.886 0.094 0.088 1148.306 0.066 25.710 3115097.976 199708.225 0.455 0.296 0.186 271682.549 4177601.270 5474478.860 3132720.683 122572.296 391924.382 0.506 0.030 8.166 59.926 1.771 3.893 0.899 570.460 1.295 1.295 2.155 63.279 654.229 24.002 0.005 1.037 0.632 0.402 0.006 1.107 0.048 1.824 0.092 0.091 1253.988 0.064 26.715 3035237.261 214688.644 0.481 0.293 0.187 289963.661 4220314.890 5817761.898 2978764.313 123940.175 384006.117 0.568 0.022 7.572 59.460 1.699 3.513 0.846 570.470 1.305 1.305 2.113 60.384 675.759 24.469 0.004 0.992 0.617 0.380 0.006 0.938 0.043 1.791 0.095 0.089 1244.929 0.069 25.584 3197639.477 204809.051 0.470 0.292 0.180 276333.284 4217577.255 5890902.672 3283342.962 121062.269 387393.941 0.554 0.020 7.364 62.692 1.918 3.485 0.847 570.480 1.315 1.315 1.779 51.301 566.303 26.292 0.004 0.830 0.525 0.355 0.006 0.993 0.068 1.587 0.089 0.074 1123.834 0.067 21.815 3183896.709 221005.965 0.467 0.295 0.200 333420.550 4185073.928 6318473.883 3794932.606 122647.667 340020.920 0.523 0.038 6.796 65.257 1.550 3.821 0.892 570.490 1.325 1.325 1.686 47.752 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