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März, Christian; Beckmann, Britta; Franke, C; Vogt, Christoph; Wagner, Thomas; Kasten, Sabine (2009): Geochemical analysis at ODP Site 207-1259 from the Demerara Rise in the western equatorial Atlantic. PANGAEA, https://doi.org/10.1594/PANGAEA.732377, Supplement to: März, Christian; Beckmann, Britta; Franke, Christine; Vogt, Christoph; Wagner, Thomas; Kasten, Sabine (2009): Geochemical environment of the Coniacian-Santonian western tropical Atlantic at Demerara Rise. Palaeogeography, Palaeoclimatology, Palaeoecology, 273(3-4), 286-301, https://doi.org/10.1016/j.palaeo.2008.05.004

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Abstract:
Organic carbon-rich shales deposited during the Coniacian–Santonian Oceanic Anoxic Event 3 were drilled during ODP Leg 207 at Demerara Rise. We present integrated high-resolution geochemical records of core intervals from ODP Sites 1259 and 1261 both from nannofossil biozone CC14. Our results reveal systematic variations in marine and detrital sediment contribution, depositional processes, and bottom water redox conditions during black shale formation at two locations on Demerara Rise in different paleo-water depths. A combination of redox proxies (Fe/S, P/Al, C/P, redox-sensitive/sulfide-forming trace metals Mn, Cd, Mo, Ni, V, Zn) and other analytical approaches (bulk sediment composition, P speciation, electron microscopy, X-ray diffraction) evidence anoxic to sulfidic bottom water and sediment conditions throughout the deposition of black shale. These extreme redox conditions persisted and were periodically punctuated by short-termed periods with less reducing bottom waters irrespective of paleo-water depth. Sediment supply at both sites was generally dominated by marine material (carbonate, organic matter, opal) although relationships of detrital proxies as well as glauconitic horizons support some influence of turbidites, winnowing bottom currents and/or variable detritus sources, along with less reducing bottom water at the proposed shallower location (ODP Site 1259). At Site 1261, located at greater paleo-depth, redox fluctuations were more regular, and steady hemipelagic sedimentation sustained the development of mostly undisturbed lamination in the sedimentary record. Strong similarities of the studied deposits exist with the stratigraphic older Cenomanian–Turonian OAE2 black shale sections at Demerara Rise, suggesting that the primary mechanisms controlling continental supply and ocean redox state were time-invariant and kept the western equatorial Atlantic margin widely anoxic over millions of years.
Project(s):
Coverage:
Latitude: 9.300400 * Longitude: -54.199517
Date/Time Start: 2003-02-01T00:00:00 * Date/Time End: 2003-02-16T00:00:00
Minimum DEPTH, sediment/rock: 499.605 m * Maximum DEPTH, sediment/rock: 500.615 m
Event(s):
207-1259 * Latitude: 9.300400 * Longitude: -54.199517 * Date/Time Start: 2003-02-01T00:00:00 * Date/Time End: 2003-02-16T00:00:00 * Elevation: -2354.5 m * Penetration: 1668.7 m * Recovery: 644.9 m * Location: South Atlantic Ocean * Campaign: Leg207 * Basis: Joides Resolution * Method/Device: Composite Core (COMPCORE) * Comment: 104 cores; 929.6 m cored; 739.1 m drilled; 69.4 % recovery
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
DEPTH, sediment/rockDepth sedmGeocode
Depth, referenceDepth refmMärz, ChristianSection depth
Depth, referenceDepth refmMärz, ChristianSection depth, corrected
AluminiumAl%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
BoronBmg/kgMärz, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
BariumBamg/kgMärz, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
CalciumCa%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
ChromiumCr%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
CopperCu%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
10 IronFe%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
11 PotassiumK%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
12 MagnesiumMg%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
13 ManganeseMn%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
14 MolybdenumMomg/kgMärz, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
15 SodiumNa%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
16 PhosphorusP%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
17 Sulfur, totalTS%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
18 StrontiumSr%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
19 TitaniumTi%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
20 VanadiumVmg/kgMärz, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
21 ZincZn%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
22 ZirconiumZrmg/kgMärz, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
23 NickelNi%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
24 Barium/Aluminium ratioBa/AlMärz, ChristianCalculated
25 Chromium/Aluminium ratioCr/AlMärz, ChristianCalculated
26 Copper/Aluminium ratioCu/AlMärz, ChristianCalculated
27 Iron/Aluminium ratioFe/AlMärz, ChristianCalculated
28 Potassium/Aluminium ratioK/AlMärz, ChristianCalculated
29 Magnesium/Aluminium ratioMg/AlMärz, ChristianCalculated
30 Manganese/Aluminium ratioMn/AlMärz, ChristianCalculated
31 Molybdenum/Aluminium ratioMo/AlMärz, ChristianCalculated
32 Nickel/Aluminium ratioNi/AlMärz, ChristianCalculated
33 Phosphorus/Aluminium ratioP/AlMärz, ChristianCalculated
34 Sulfur/Aluminium ratioS/AlMärz, ChristianCalculated
35 Strontium/Aluminium ratioSr/AlMärz, ChristianCalculated
36 Titanium/Aluminium ratioTi/AlMärz, ChristianCalculated
37 Vanadium/Aluminium ratioV/AlMärz, ChristianCalculated
38 Zinc/Aluminium ratioZn/AlMärz, ChristianCalculated
39 Zirconium/Aluminium ratioZr/AlMärz, ChristianCalculated
40 Strontium/Calcium ratioSr/CaMärz, ChristianCalculated
41 Iron/Sulfur ratioFe/SMärz, ChristianCalculated
42 Phosphorus pentoxideP2O5%März, ChristianICP-OES, Inductively coupled plasma - optical emission spectrometry
43 Carbon, organic, totalTOC%März, ChristianElement analyser CS, LECO CS-200
44 CarbonatesCarb%März, ChristianElement analyser CS, LECO CS-200
45 Carbon, organic total/Aluminium ratioTOC/AlMärz, ChristianCalculated
46 Calcium/Aluminium ratioCa/AlMärz, ChristianCalculated
Size:
4590 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Depth sed [m]

Depth ref [m]
(Section depth)

Depth ref [m]
(Section depth, corrected)

Al [%]
(ICP-OES, Inductively coupled ...)

B [mg/kg]
(ICP-OES, Inductively coupled ...)

Ba [mg/kg]
(ICP-OES, Inductively coupled ...)

Ca [%]
(ICP-OES, Inductively coupled ...)

Cr [%]
(ICP-OES, Inductively coupled ...)

Cu [%]
(ICP-OES, Inductively coupled ...)
10 
Fe [%]
(ICP-OES, Inductively coupled ...)
11 
K [%]
(ICP-OES, Inductively coupled ...)
12 
Mg [%]
(ICP-OES, Inductively coupled ...)
13 
Mn [%]
(ICP-OES, Inductively coupled ...)
14 
Mo [mg/kg]
(ICP-OES, Inductively coupled ...)
15 
Na [%]
(ICP-OES, Inductively coupled ...)
16 
P [%]
(ICP-OES, Inductively coupled ...)
17 
TS [%]
(ICP-OES, Inductively coupled ...)
18 
Sr [%]
(ICP-OES, Inductively coupled ...)
19 
Ti [%]
(ICP-OES, Inductively coupled ...)
20 
V [mg/kg]
(ICP-OES, Inductively coupled ...)
21 
Zn [%]
(ICP-OES, Inductively coupled ...)
22 
Zr [mg/kg]
(ICP-OES, Inductively coupled ...)
23 
Ni [%]
(ICP-OES, Inductively coupled ...)
24 
Ba/Al
(Calculated)
25 
Cr/Al
(Calculated)
26 
Cu/Al
(Calculated)
27 
Fe/Al
(Calculated)
28 
K/Al
(Calculated)
29 
Mg/Al
(Calculated)
30 
Mn/Al
(Calculated)
31 
Mo/Al
(Calculated)
32 
Ni/Al
(Calculated)
33 
P/Al
(Calculated)
34 
S/Al
(Calculated)
35 
Sr/Al
(Calculated)
36 
Ti/Al
(Calculated)
37 
V/Al
(Calculated)
38 
Zn/Al
(Calculated)
39 
Zr/Al
(Calculated)
40 
Sr/Ca
(Calculated)
41 
Fe/S
(Calculated)
42 
P2O5 [%]
(ICP-OES, Inductively coupled ...)
43 
TOC [%]
(Element analyser CS, LECO CS-200)
44 
Carb [%]
(Element analyser CS, LECO CS-200)
45 
TOC/Al
(Calculated)
46 
Ca/Al
(Calculated)
499.6051.2051.2052.32169.923408.39624.7790.0130.0051.3140.7050.5230.00640.7131.0191.0921.3480.0920.101945.8650.03730.5230.011175.97857.91720.7470.5660.3040.22627.90017.54347.3530.4710.581398.180437.036407.573158.85613.15237.2930.9745.0035.17252.6292.22910.677
499.6151.2151.2152.20846.873447.43323.6460.0080.0041.1700.6570.4430.00675.5921.1120.0561.8010.0960.1011358.3480.05727.5700.013202.66435.05318.8820.5300.2970.20127.34634.23956.6600.0250.816436.240458.451615.261259.77912.48840.7300.6500.2547.03656.0113.18710.711
499.6251.2251.2252.27454.261467.40423.3900.0070.0051.3130.6670.4470.00676.6211.1350.0832.0090.0980.1031476.8540.05326.8420.013205.50431.66720.0230.5770.2930.19725.88533.68859.1990.0370.883432.821452.655649.329233.83211.80142.0870.6540.3827.51751.0883.30510.284
499.6351.2351.2352.25244.589488.79323.0930.0070.0041.3210.6720.4370.00684.6571.1370.0952.1230.1010.0981474.3300.06125.0040.015217.08030.80218.1950.5870.2980.19427.23837.59767.1690.0420.943449.428437.003654.772268.74211.10543.8220.6220.43710.21031.2384.53410.256
499.6451.2451.2452.25349.768475.69922.7380.0070.0041.1880.6830.4390.00685.4261.1500.0621.9080.0990.1021600.4380.08327.2230.014211.10431.44419.7610.5270.3030.19525.58937.91063.2900.0270.847440.397453.473710.238370.01412.08143.6430.6230.2826.58461.6922.92210.091
499.6551.2551.2552.48858.633546.06721.5780.0080.0061.3620.7620.4700.00688.9121.2190.0502.1140.1020.1131776.6100.11329.3740.016219.48433.28523.0280.5470.3060.18924.25935.73763.6570.0200.850410.575453.408714.086453.56211.80747.3400.6440.2287.64151.3883.0718.673
499.6651.2651.2652.57252.718561.13020.7150.0090.0061.3350.7780.4830.00693.8381.2550.0372.0970.1030.1151880.8580.11633.0560.015218.16633.37522.4830.5190.3020.18821.38836.48459.1890.0140.815399.685448.858731.274451.23612.85249.6260.6360.1678.29949.3223.2278.054
499.6751.2751.2752.74663.418585.01220.0650.0090.0061.4340.8160.5080.00690.2801.2980.0392.1860.1030.1242026.5460.14632.3130.015213.06334.22922.9900.5220.2970.18520.77032.88054.4650.0140.796376.309450.759738.075532.63411.76951.4940.6560.1818.06647.7642.9387.308
499.6851.2851.2853.10768.425635.53118.6770.0120.0071.6620.9010.5750.00685.0131.3330.0202.1960.1030.1402097.9770.15835.2780.014204.51638.15124.1080.5350.2900.18520.39127.35745.5550.0060.707331.222451.666675.135509.33411.35355.1090.7570.0927.45844.9992.4006.010
499.6951.2951.2953.38071.938680.19518.0330.0140.0091.7670.9700.6170.00782.7621.3850.0292.2170.1020.1522279.5690.19937.4880.014201.26841.23926.0260.5230.2870.18320.71824.48940.5640.0090.656300.380450.925674.520588.10211.09356.2930.7970.1327.94941.6582.3525.336
499.7051.3051.3052.94167.517629.02418.9520.0150.0091.3350.8810.5490.00671.3301.3290.0501.9420.1030.1301794.8240.17632.1360.012213.86049.55429.0050.4540.3000.18719.50624.25142.2880.0170.660349.571441.955610.218599.56910.92654.2520.6870.2298.15744.3412.7736.443
499.7151.3151.3153.12975.052596.54118.5540.0220.0091.3790.9050.5940.00663.6451.3090.4671.9050.0980.1381380.9490.13434.6530.013190.64768.74929.8440.4410.2890.19019.43420.34041.6360.1490.609314.203441.313441.333429.12111.07552.9880.7242.1378.41442.3662.6895.930
499.7251.3251.3253.36479.747562.88617.3790.0280.0101.4780.9370.6660.00661.0391.3060.8391.9160.0930.1511048.6000.08239.9960.014167.30782.63629.1330.4390.2780.19819.28618.14342.0460.2490.569277.097449.821311.675242.33911.88853.6430.7713.8449.06535.6942.6945.166
499.7351.3351.3353.55786.662545.88716.3140.0310.0091.5830.9690.7400.00750.0601.3181.8931.8340.0920.160815.4310.04844.1170.014153.44988.48125.9450.4450.2720.20818.80814.07240.2820.5320.516259.319450.854229.217133.97012.40156.5490.8638.6728.78128.0642.4684.586
499.7451.3451.3453.61993.548507.01516.4660.0320.0091.7160.9520.7780.00846.0881.2521.6831.8320.0860.162717.5700.04243.9650.013140.09689.20923.7500.4740.2630.21521.45012.73536.7030.4650.506238.935447.761198.275116.23012.14852.5160.9377.7098.58230.9712.3714.550
499.7551.3551.3553.16182.439455.11919.5040.0290.0081.3100.8710.7210.00636.7881.2121.5771.4950.0900.143635.4080.03939.7760.013143.97993.30625.0140.4140.2760.22820.39711.63840.8090.4990.473284.088452.986201.015122.38512.58346.0410.8767.2237.85538.4432.4856.170
499.7651.3651.3653.11579.763431.30418.6910.0290.0081.4600.8530.7110.00738.1821.1711.4771.6270.0850.141645.2930.04040.0480.013138.45192.41726.4930.4690.2740.22822.27212.25741.6970.4740.522272.144454.057207.142127.81312.85545.3580.8976.7677.71638.9342.4776.000
499.7751.3751.3752.72173.956407.98821.3090.0250.0071.1550.7690.6350.00635.2331.1191.8031.3220.0890.124677.2140.03636.3500.012149.94990.65627.2600.4240.2830.23321.76312.94944.1800.6630.486328.625455.605248.899133.90913.36041.9610.8738.2596.90042.4002.5367.832
499.7851.3851.3852.50560.199537.54821.8530.0160.0061.2890.7440.4850.00652.3141.1800.5991.6930.1020.1101156.6020.03828.3120.012214.59362.44825.4840.5150.2970.19423.06820.88448.2540.2390.676408.623439.655461.723152.88911.30246.8400.7622.7457.24549.4392.8928.724
499.7951.3951.3952.29254.964469.69423.6320.0130.0050.9940.6830.4590.00641.9971.0760.6111.3210.0990.1021179.9290.04827.2180.011204.92358.36223.4330.4340.2980.20024.61018.32349.2680.2670.576432.752447.024514.792210.43511.87541.9730.7532.7986.14155.3032.67910.310
499.8051.4051.4052.23246.627547.36822.8030.0100.0051.0700.6850.4030.00660.0341.1550.1161.7130.1040.0971490.8380.11625.8240.014245.25444.42820.7260.4790.3070.18025.20826.89961.7640.0520.768467.099436.221667.984518.91711.57145.7170.6240.5317.21554.8533.23310.217
499.8151.4151.4152.08546.972525.63824.3320.0090.0040.9870.6390.3790.00657.2291.1360.0491.5980.1050.0911528.3590.09224.1220.012252.04843.28320.7650.4730.3060.18226.87527.44256.4290.0230.766502.973435.789732.860441.05211.56743.1090.6180.2226.49659.1763.11511.667
499.8251.4251.4252.21946.533567.88323.1000.0110.0060.9850.6820.3970.00556.1381.1800.1991.7060.1070.0951570.5930.13625.1930.012255.88851.31325.0770.4440.3070.17922.56625.29652.2120.0900.769484.371427.220707.710612.23411.35246.5350.5780.9137.05055.8943.17710.409
499.8351.4351.4352.76856.473653.23020.5780.0160.0081.4540.8300.4720.00664.0371.3250.0622.0630.1100.1221797.6180.20830.2880.013235.96458.34229.3650.5250.3000.17021.75123.13246.2330.0230.745397.500442.088649.347749.54910.94153.4750.7050.2867.48250.2972.7037.433
499.8451.4451.4452.61958.560628.83420.7650.0210.0081.1510.7850.4500.00552.9421.3070.2001.7830.1090.1091165.7070.14728.3350.013240.12178.87330.9190.4400.3000.17218.77120.21649.2610.0760.681417.981417.077445.127559.95010.82052.7140.6460.9157.99850.1633.0547.929
499.8551.4551.4552.82965.903627.32720.0190.0300.0091.2610.7960.5010.00543.3311.2860.7591.7910.1060.121652.2390.05129.9820.014221.765106.63930.7730.4460.2810.17718.08215.31849.7320.2680.633374.821426.614230.572181.54310.59952.9650.7043.4778.24242.2162.9147.077
499.8651.4651.4652.79665.431594.97620.4310.0300.0081.1420.7750.5040.00535.6541.2670.8201.4900.1040.119532.6510.04030.7580.012212.781108.63727.7380.4080.2770.18018.14412.75143.9850.2930.533372.020424.444190.492141.88411.00050.9140.7663.7557.73045.3982.7647.307
499.8751.4751.4752.36061.701457.75924.7750.0260.0071.2390.6420.4800.00525.3121.0803.1931.4060.1060.105438.8170.02928.7940.009193.978109.38427.8840.5250.2720.20322.00510.72636.8851.3530.596447.995445.494185.952122.06512.20242.6720.88114.6254.89742.5912.07510.499
499.8851.4851.4853.01481.968429.07021.0880.0350.0081.3010.7620.7010.00528.2211.1364.3721.3410.0970.144552.6080.03641.7380.011142.357116.17125.6250.4310.2530.23318.1339.36338.0241.4500.445320.226478.007183.344120.14813.84845.7700.97020.0256.25527.9972.0756.996
499.8951.4951.4953.18880.468524.47419.7270.0320.0081.6910.8460.6570.00633.7861.1893.0321.6420.1000.143550.3370.03938.3930.012164.490100.15726.1100.5300.2650.20619.28510.59638.9660.9510.515315.098450.022172.601122.97312.04150.9301.03013.8877.01831.0882.2016.187
499.9051.5051.5053.12786.559559.62421.3240.0310.0081.4080.8610.6310.00633.5911.2621.3681.4430.1070.139578.4640.03934.6510.012178.98399.89224.8970.4500.2750.20220.03310.74337.7520.4380.462343.316444.100185.008125.48311.08250.3400.9766.2677.38440.8672.3626.820
499.9151.5151.5152.85576.812550.54921.0850.0290.0081.2310.8080.5570.00632.8491.2700.7991.5240.1080.123628.0720.04030.6380.012192.857100.75827.3530.4310.2830.19519.97711.50743.3570.2800.534379.567432.244220.013140.36210.73351.3900.8073.6618.31544.1072.9137.386
499.9250.0051.5252.40160.593508.95022.5540.0220.0070.9960.6940.4460.00540.8451.1340.9851.3480.1040.102795.9830.08226.4960.010211.95791.49830.9720.4150.2890.18620.94017.01041.9390.4100.562432.274426.657331.495340.32711.03446.0220.7384.5137.68849.4973.2029.393
499.9350.0151.5352.30255.079508.60022.5000.0210.0071.0100.6700.4320.00541.1511.1030.4091.3710.1010.098806.0450.10224.7550.010220.89492.27632.3650.4390.2910.18822.52417.87343.8130.1770.596437.667424.545350.079442.59810.75144.7860.7371.8727.31954.6533.1799.772
499.9450.0251.5452.50857.921527.45821.6470.0220.0081.0970.7330.4600.00546.6621.2090.1671.5300.1030.107910.5200.09427.2370.011210.28087.73833.2640.4370.2920.18321.68518.60344.1250.0670.610410.117426.402362.994373.51710.85947.5230.7170.7658.30049.5643.3098.630
499.9550.0351.5552.67862.156635.48820.9940.0220.0081.1440.7690.4790.00540.2101.2550.3911.5590.1090.113886.0620.09229.1180.011237.25983.99631.2160.4270.2870.17920.03715.01242.5500.1460.582406.735422.732330.811343.42010.87151.8920.7341.7937.99349.1222.9847.838
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